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151.
Eleven triazolyl substituted tetrahydrobenzofuran derivatives were synthesized in high yields as novel H+/K+‐ATPase inhibitor via one‐pot CuI‐catalyzed three‐component click reaction of azide, secondary amine and 3‐bromopropyne under mild conditions in water. Their structures were characterized by NMR, IR, ESI‐MS, elemental analysis and single‐crystal X‐ray diffraction analysis. Most of the target compounds exhibited better H+/K+‐ATPase inhibitory activity than commercial omeprazole with IC50 values less than 15 µmol·L?1. The initial structure‐activity analysis suggested that the triazole substituted by cycloalkyl, aromatic ring or O‐containing side‐chain seemed to be beneficial for enhancing the activity. 相似文献
152.
Zirui Song Kangyu Zou Xuhuan Xiao Xinglan Deng Shuo Li Prof. Dr. Hongshuai Hou Prof. Dr. Xiaoming Lou Prof. Dr. Guoqiang Zou Prof. Dr. Xiaobo Ji 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(65):16082-16092
Nowadays sodium-based energy storage systems (Na-based ESSs) have been widely researched as it possesses the possibility to replace traditional energy storage media to become next generation energy storage system. However, due to the irreversible loss of sodium ions in the first cycle, development of Na-based ESSs is limited. Presodiation, as a strategy of adding excess sodium ions to the system in advance, accomplishes the enhancement of electrochemical performance. In this minireview, different presodiation strategies applied in sodium-based energy storage systems will be summarized in detail, their functions and corresponding mechanisms will be discussed as well. Furthermore, the current novel application of presodiation method in other aspects of Na-based ESSs will be mentioned additionally. At last, in the view of present research status of presodiation, issues that can be mitigated are put forward and guidelines are given on how to deliberate in-depth presodiation technology in the future, dedicating to promote the further development of Na-based ESSs. 相似文献
153.
Quanfei Zou Yuan Gu Rong Lu Tiejun Zhang Guang‐Rong Zhao Changxiao Liu Duanyun Si 《Biomedical chromatography : BMC》2013,27(9):1123-1128
In this study, a simple and sensitive LC/MS/MS method was developed and validated for the determination of arctigenin in rat plasma. The MS detection was performed using multiple reaction monitoring at the transitions of m/z 373.2 → 137.3 for arctigenin and m/z 187.1 → 131.0 for psoralen (internal standard) with a Turbo IonSpray electrospray in positive mode. The calibration curves fitted a good linear relationship over the concentration range of 0.2–500 ng/mL. It was found that arctigenin is not stable enough at both room temperature and ?80 °C unless mixed with methanol before storage. The validated LC/MS/MS method was successfully applied for the pharmacokinetic study of arctigenin in rats. After intravenous injection of 0.3 mg/kg arctigenin injection to rats, the maximum concentration, half‐life and area under the concentration–time curve were 323 ± 65.2 ng/mL, 0.830 ± 0.166 and 81.0 ± 22.1 h ng/mL, respectively. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
154.
Dinuclear ytterbium and erbium based bifunction complexes Ln2L2(depma2)Cl2 (1-Ln, Ln = Yb and Er, H2L = N1,N3-bis(salicylideneimino)diethylenetriamine, depma2 = dimerized 9-diethyl-phosphonomethylanthracene) are reported. They undergo thermo-induced consecutive phase transitions, first the dissociation of depma2 ligand forming LnL(depma)Cl (2-Ln) and then the release of chloroethane forming LnL(epma) (3-Ln, epma = 9-ethylphosphonomethylanthrancene). The structural transformations are accompanied with synergetic switch of the luminescence in visible and NIR regions and also magnetic dynamics. 相似文献
155.
156.
Flexible conductive polymer hydrogels are unique material that synergize the features of conductive polymers and hydrogels. They are excellent candidates for the flexible supercapacitor electrodes. In this paper, flexible conductive polymer hydrogels were prepared with poly(vinyl alcohol) as soft skeleton through cyclic freezing-thawing method. Firstly, phytic acid-doped polyaniline with crosslinked network was prepared using phytic acid as the dopant and crosslinking agents. Hydrogels with interpenetrating binary network nanostructure were then formed by freezing-thawing method. The interpenetrating binary network structure endowed the hydrogel reliable mechanical properties with decent flexibility and compressive strength of 3.64 MPa. More importantly, this unique structure enable them to maintain highly specific capacitance (314 F/g at the current density of 0.5 A/g). 相似文献
157.
Zou Fan Zuo Jing Geng Chao Li Feng Huang Guan Liu Jiaying Jiang Jiali Fan Zhihua Li Xinyang 《Journal of Russian Laser Research》2021,42(4):462-467
Journal of Russian Laser Research - Laser aiming is one of the key technologies of laser atmospheric transmission. The beam actually is affected by atmospheric turbulence and mechanical vibration;... 相似文献
158.
Cheng‐Xiong Liu Zhi‐yong Guo Yan‐Hong Xue Hong‐Yan Zhang Hong‐Qi Zhang Kun Zou Nian‐Yu Huang 《Magnetic resonance in chemistry : MRC》2012,50(4):320-324
Three new steroidal compounds with polyhydroxy groups, tupisteroide A–C (1–3), were obtained from the roots of Tupistra chinensis, together with one known compound (4) that was isolated from this plant for the first time. The structures of tupisteroide A–C were determined on the basis of one‐ and two‐dimensional NMR spectroscopy, including 1H–1H Correlation Spectroscopy, Heteronuclear Multiple Bond Correlation, and Heteronuclear Single Quantum Coherence experiments. The isolated compounds were evaluated for their cytotoxic activities against A549, HepG2, and CaSki cancer cell lines in vitro. Among them, compounds 1, 2, and 4 did not show significant inhibitory activity, but compound 3 showed cytotoxicity against A549 cancer cell lines with IC50 values of 25.0 μM. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
159.
In this paper, compressive imaging based on spatial correlation (CISC), which uses second-order correlation with the measurement matrix, is introduced to improve the signal-to-noise ratio performance of compressive imaging (CI). Numerical simulations and experiments are performed as well. Referred to the results, it can be seen that CISC performs much better than CI in three common noise environments. This provides the great opportunity to pave the way for real applications. 相似文献