全文获取类型
收费全文 | 16225篇 |
免费 | 2907篇 |
国内免费 | 1881篇 |
专业分类
化学 | 11570篇 |
晶体学 | 164篇 |
力学 | 1159篇 |
综合类 | 68篇 |
数学 | 1710篇 |
物理学 | 6342篇 |
出版年
2024年 | 56篇 |
2023年 | 356篇 |
2022年 | 613篇 |
2021年 | 597篇 |
2020年 | 648篇 |
2019年 | 610篇 |
2018年 | 571篇 |
2017年 | 507篇 |
2016年 | 867篇 |
2015年 | 764篇 |
2014年 | 974篇 |
2013年 | 1171篇 |
2012年 | 1505篇 |
2011年 | 1460篇 |
2010年 | 995篇 |
2009年 | 933篇 |
2008年 | 1085篇 |
2007年 | 966篇 |
2006年 | 870篇 |
2005年 | 768篇 |
2004年 | 535篇 |
2003年 | 436篇 |
2002年 | 433篇 |
2001年 | 355篇 |
2000年 | 307篇 |
1999年 | 337篇 |
1998年 | 275篇 |
1997年 | 246篇 |
1996年 | 277篇 |
1995年 | 276篇 |
1994年 | 192篇 |
1993年 | 153篇 |
1992年 | 153篇 |
1991年 | 145篇 |
1990年 | 125篇 |
1989年 | 102篇 |
1988年 | 87篇 |
1987年 | 67篇 |
1986年 | 51篇 |
1985年 | 41篇 |
1984年 | 30篇 |
1983年 | 25篇 |
1982年 | 15篇 |
1981年 | 16篇 |
1980年 | 9篇 |
1978年 | 2篇 |
1972年 | 1篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
X. Y. Yang H. C. Gao X. L. Tan H. Z. Yuan G. Z. Cheng S. Z. Mao S. Zhao L. Zhang J. Y. An J. Y. Yu Y. R. Du 《Colloid and polymer science》2004,282(3):280-286
1H chemical shift changes of sodium 4-decyl naphthalene sulfonate (SDNS) at 313 K show that its critical micellar concentration lies between 0.82 and 0.92 mmol/dm3, which is in the same range as that of the previous study at 298 K. The spin–lattice relaxation time, spin–spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy experiments give information about the structure of the SDNS micelle and the dynamics of the molecules in the micelle. The size of the SDNS micelle remains almost unchanged in the temperature range from 298 to 313 K as deduced by analyzing the self-diffusion coefficient. Special arrangement of the naphthyl rings of SDNS in the micelles affects the packing of these hydrophobic chains. The methylene groups of the alkyl chain nearest the naphthalene groups penetrate into the aromatic region, which results in a more tightly packed hydrophobic micellar core than that of sodium dodecyl sulfonate. 相似文献
92.
A method has been described for the determination of arsenic species (arsenite and arsenate) by hydride generation-atomic fluorescence spectrometry (HG-AFS). The experimental conditions that influence the fluorescence intensity and the reduction of arsenic were investigated and optimized, and the influences from foreign ions and their elimination were studied. The detection limit was found to be 79.7 ng L(-1). The proposed method was applied to the determination of arsenic species in water leachate of traditional Chinese medicines with a recovery range of 91.1-109.5%. 相似文献
93.
Fengping Yu Junpo He Xiaojun Wang Guangzheng Gao Yuliang Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(17):4013-4025
A combination of nitroxide‐mediated radical polymerization and living anionic polymerization was used to synthesize a series of well‐defined graft (co)polymers with “V‐shaped” and “Y‐shaped” branches. The polymer main chain is a copolymer of styrene and p‐chloromethylstyrene (PS‐co‐PCMS) prepared via nitroxide‐mediated radical polymerization. The V‐shaped branches were prepared through coupling reaction of polystyrene macromonomer, carrying 1,1‐diphenylethylene terminus, with polystyryllithium or polyisoprenyllithium. The Y‐shaped branches were prepared throughfurther polymerization initiated by the V‐shaped anions. The obtained branches, carrying a living anion at the middle (V‐shaped) or at the end of the third segment (Y‐shaped), were coupled in situ with pendent benzyl chloride of PS‐co‐PCMS to form the target graft (co)polymers. The purified graft (co)polymers were analyzed by size exclusion chromatography equipped with a multiangle light scattering detector and a viscometer. The result shows that the viscosities and radii of gyration of the branched polymers are remarkably smaller than those of linear polystyrene. In addition, V‐shaped product adopts a more compact conformation in dilute solution than the Y‐shaped analogy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4013–4025, 2007 相似文献
94.
研究了非相干辐照对LiNbO3:Fe晶体中从自散焦到自聚焦的动态转换过程的影响和控制作用.无论是从前向还是从背向加入非相干辐照,都能加快自散焦、自聚焦过程以及从自散焦到自聚焦的转换过程,增大折射率的变化值.当非相干辐照以一定的时间间隔重复辐照在晶体上时,透射功率能迅速地上升和下降,具有明显的开关效应.这种在非相干辐照控制下折射率的迅速改变有望应用于全光学开关器件.
关键词:
非相干辐照
光伏效应
自散焦
自聚焦 相似文献
95.
96.
97.
98.
Wenping Deng Gang Xu Lei Wan Anwen Liu Bo Gao Junhe Du Shuiming Hu Yang Chen 《Acta Physico》2008,24(8):1329-1334
Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (ν=0←0, J=6←0) line around 2410 cm−1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-helium temperature was studied. 相似文献
99.
100.
光照与彩陶俑表面色变关系的实验研究 总被引:1,自引:0,他引:1
本文以秦彩俑表面色彩为研究对象,通过光照实验与色彩变化的色度测量,分析了光照引起彩俑颜料色变的规律,为秦彩俑这一大型重点文物的色彩保护提供了科学理论依据. 相似文献