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991.
Palladium-catalyzed asymmetric ring opening of oxabenzonorbornadienes with readily available organozinc halides under mild conditions in the presence of (S)-Pr(i)-PHOX produces the corresponding 1,2-dihydronaphth-1-ols in good yield and high enantioselectivity. [reaction: see text] 相似文献
992.
A new simple and sensitive fluorimetric method for the determination of carbohydrates is described. The method is based on the reaction between carbohydrates and Ce(IV) in the presence of sulfuric acid. All the reductive carbohydrates can be detected indirectly by the fluorescence of Ce(III) produced. The addition of sodium triphate enhances the sensitivity of the method by more than 10-folds. Under optimum conditions, an excellent linear relationship was obtained between the fluorescence intensity and the concentration of carbohydrates. The limits of detection lie in the range of 9.3 x 10(-10) - 1.3 x 10(-9) mol/L. As compared to the normal fluorimetric method, the proposed method is faster and more sensitive. 相似文献
993.
Xun?Gu Selcuk?Akturk Aparna?Shreenath Qiang?Cao Rick?TrebinoEmail author 《Optical Review》2004,11(3):141-152
We review the state of the art of ultrashort-light-pulse measurement using frequency-resolved-optical-gating (FROG). Recent developments have extended the state of the art considerably. FROG devices for measuring the intensity and phase of ultrashort laser pulses have become so simple that almost no alignment is required. In addition, such devices not only operate single shot, but they also yield the two most important spatio-temporal distortions, spatial chirp and pulse-front tilt. With other FROG variations, it is now possible to measure more general ultrashort light pulses (i.e., pulses much more complex than common laser pulses), with time-bandwidth products as large as several thousand and as weak as a few hundred photons, and despite other difficulties such as random absolute phase and poor spatial coherence. 相似文献
994.
J. Cao Z. Xiong J. M. Yang 《The European Physical Journal C - Particles and Fields》2004,32(2):245-252
In the supersymmetric seesaw model, large flavor mixings of sleptons induce the lepton flavor violating (LFV) interactions
(
), which give rise to various LFV processes. In this work we examine the LFV decays
. Subject to the constraints from the existing neutrino oscillation data and the experimental bounds on the decays
, these LFV Z-decays are found to be sizable, and among them the largest-rate channel
can occur with a branching ratio of 10-8 and may be accessible at the LHC or GigaZ experiment.Received: 1 September 2003, Published online: 20 November 2003 相似文献
995.
The evolution of 2-D disturbances in hypersonic boundary layer with Mach number 6,8, and 10 was investigated numerically by
three different numerical schemes. At the entrance, second mode T-S waves with different amplitudes were introduced, and the
relation between the Mach number and the amplitude of the disturbance when shocklets started to appear was investigated. By
comparing the disturbance velocity profiles with those provided by linear stability theory, the effects of shocklets on flow
structures were also investigated. 相似文献
996.
Titanium pyrrolyl complexes are effective catalysts for the synthesis of alpha,beta-unsaturated imines, which can be further functionalized using Rh-catalyzed alkene or alkyne insertion into the beta-C-H bond. 相似文献
997.
In this paper we have demonstrated that the crystallization method of amorphous colloids is convenient and feasible in the large-scale production of one-dimensional (1D) nanostructures. For the crystals with highly anisotropic structures, such as orthorhombic, trigonal, and hexagonal crystals, the crystallization generally tends to occur along the (001) axis. The preparation of orthorhombic bismuth sulfide (Bi2S3) nanorods and trigonal selenium ( t-Se) nanowires by the crystallization route was used as typical examples to illustrate the process and mechanism of crystallization. The as-prepared products were characterized with transmission electron microscopy, field-emission scanning electron microscopy, X-ray diffraction, and selected area electron diffraction. Additionally, the detailed crystal growth processes involved in the crystallization of amorphous Bi2S3 colloid were investigated by studying the morphology and structure of intermediates. It demonstrates that the growth of the nanorods is through two key steps: (1) the formation of multiple activated sites on the surface of spherical Bi2S3 colloid and (2) the subsequent preferential growth along these sites. 相似文献
998.
Cao XY Liu XH Zhou XH Zhang Y Jiang Y Cao Y Cui YX Pei J 《The Journal of organic chemistry》2004,69(18):6050-6058
This paper reports the facile synthetic strategy of a series of novel pi-conjugated dendrimers (G0 and G1) based on 10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) in which the benzene cores are generated "in-situ" from acetyl aromatics by the acid-promoted cyclotrimerizations. The unique NMR behaviors, physical properties, and electroluminescence device applications are also presented. Besides the purity, the structure, and the confirmation of the successful formation and isolation of desired compounds by clear assignments of every molecule by (1)H and (13)C and 2D NMR characterizations, several astonishing NMR behaviors have been observed in various solvents. For 1, chemical shift values belonging to H-2' of hexyl substituents move to the most upfield; however, such chemical shift values move from 0.48 to 0.85 ppm when pyridine-d(5) or benzene-d(6) is used as solvent. Our dendrimers as the emissive layers in organic light-emitting diodes gave blue-green light with an external quantum efficiency up to 0.16% both for G0 and for G1 in nitrogen, respectively, which exhibit unique electroluminescence spectra in comparison with their corresponding photoluminescence ones. 相似文献
999.
The Markov moment problem is to characterize sequences admitting the representation sn=01xnf(x)dx, where f(x) is a probability density on [0,1] and 0f(x)c for almost all x. There are well-known characterizations through complex systems of non-linear inequalities on {sn}. Necessary and sufficient linear conditions are the following: s0=1, and for all and . Here, is the forward difference operator. This result is due to Hausdorff. We give a new proof with some ancillary results, for example, characterizing monotone densities. Then we make the connection to de Finettis theorem, with characterizations of the mixing measure.in final form: 18 June 2003 相似文献
1000.
Magnetic-field- and temperature-dependent Raman scattering studies of Ca3Ru2O7 reveal dramatic field-dependent properties arising from transitions between various complex orbital and magnetic phases, including a field-induced orbital-ordered to orbital-disordered transition (H(o) // hard axis), and a reentrant orbital-ordered to orbital-disordered to orbital-ordered transition (H(o) // easy axis). We find that the dramatic magnetic-field properties are most prevalent in a "mixed"-magnetic and -orbital phase regime, providing evidence for a strong connection between orbital phase inhomogeneity and "colossal" field effects in the ruthenates. 相似文献