Immobilization of AIEgens into metal‐organic frameworks: Ligand design,emission behavior,and applications

Aggregation‐induced emission (AIE), in which the luminophores are highly emissive in aggregate state, is one of the most unique photophysical phenomena and has shown interesting applications in many areas. The immobilization of AIE luminogens (AIEgens) into metal‐organic frameworks (MOFs), which are inorganic‐organic hybrid porous materials with tunable and predictable structures, has been investigated over the past few years. These well‐defined porous frameworks cannot only provide an ideal platform for studying the mechanism of AIE phenomenon in solid state, but also show potential applications from sensing to white light‐emitting diodes. In this highlight, we will summarize the recent progress of AIEgens‐based MOFs, including ligand design, emission behavior, and applications. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 1809–1817     

A formula of solution to the integral of rational functions

ＡＦＯＲＭＵＬＡＯＦＳＯＬＵＴＩＯＮＴＯＴＨＥＩＮＴＥＧＲＡＬＯＦＲＡＴＩＯＮＡＬＦＵＮＣＴＩＯＮＳＧｕｉＺｕ－ｈｕａ（桂祖华）（ＴｈｅＤｅｐａｒｔｍｅｎｔｏｆＡｐｐｌｉｅｄＭａｔｈｅｍａｔｉｃｓ,ＳｈａｎｇｈａｉＪｉａｏ－ｔｏｎｇＵｎｉｖｅｒｓｉｔ...     

LBE simulation of coherent vortex motion and heat transfer in jets of cross flow

Lattice Boltzmann equation method is used to simulate the coherent vortex motions and interactions and the heat transfer characteristics of jets in cross flow (JICFs) via TD2G9 model. After validation, the characteristics of cross flow under different Reynolds numbers are illustrated, including the mean profiles, the Reynolds stress tensor, the vortex and temperature fields, the temperature gradients near the walls, and the coherent correlation of vortex motions. The results show that the velocity profiles in JICF can be characterized by three basic regions, which are mainly caused by the mergence of JICF with the main flow. The temperature gradient near the walls can also be categorized by four basic regions, which are caused mainly by the impulse of JICFs too. Coherent vortex motions are found in JICF for Re = 3000, which are proved by strong periodic correlation of flow variables over a fixed area.     

Synthesis of Pyrazolines Used as Blue Organic Electroluminescence Materials

SinceTangetaldevelopedanoveltWo-layerorganicelectr0luminescentdevice(OELD)inl987successfully',OELDhasattractedmuchinterestall0verthew0rId.ltisregardedas"havingbr0ughtthethirdrev0luti0ntoflatpaneldisplay"',becauseithass0manyadvantagessuperiort0CathodeRayTube(CRT)andLiquidCrystalDevice(LCD).Ithasl0wdrivenvoltage(lO0,000cd/m=),highluminescentefficiency(l5lIn/w),goodstability(50,000h),andithassimplestructureandiseasytofabricate'.ComparedtoinorganicELD,OELDiseasie…     

Existence and stability of periodic solutions of high-order Hopfield neural networks with impulses and delays

By using the continuation theorem of coincidence degree theory and constructing suitable Lyapunov functions, the global exponential stability and periodicity are investigated for a class of delayed high-order Hopfield neural networks (HHNNs) with impulses, which are new and complement previously known results. Finally, an example with numerical simulation is given to show the effectiveness of the proposed method and results. The numerical simulation shows that our models can occur in many forms of complexities including periodic oscillation and the Gui chaotic strange attractor.     

Terpenoids from Roots of Chloranthus spicatus

Five new terpenoids, including four eudesmane‐type sesquiterpenoids, 1 – 4 , and one labdane‐type diterpenoid, 6 , together with ten known compounds, were isolated from the roots of Chloranthus spicatus. The structures and their relative configurations were mainly established by 1D‐ and 2D‐NMR spectra, and MS experiments.     

Neolignans and Caffeoyl Derivatives from Selaginella moellendorffii

Ten new phenolic compounds including the six neolignans 1 – 3 and 6 – 8 and four caffeoyl derivatives, i.e., myo‐inositol 1‐caffeate ( 9 ), myo‐inositol 6‐caffeate ( 10 ), myo‐inositol 5‐caffeate ( 11 ), and paucine 3′‐β‐D ‐glucopyranoside ( 12 ) were isolated from the whole plants of Selaginella moellendorffii (caffeic acid=3‐(3,4‐dihydroxyphenyl)prop‐2‐enoic acid). Their structures were established by spectroscopic and chemical methods.