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81.
利用离子速度成像方法,研究CH2I2分子在277—305nm范围内若干波长处的光解离动力学.通过同一束激光经(2+1)共振多光子电离(REMPI)过程探测光解碎片I(2P32)和I(2P12),得到了不同激发波长处的离子速度分布图像,从而获得CH2I2光解产物的能量分配和角分布.实验发现,碎片CH2I自由基有很高的内能激发,约占总可资用能的80%,该能量分配可以较好地用冲击模型来解释.实验还发现,产物I(2P32)和I(2P12)具有很不相同的平动能分布,结合所得到的碎片能量分配和角分布,我们对碎片I(2P32)和I(2P12)生成机理进行了分析,指出CH2I2分子电子激发态的绝热和非绝热解离决定了碎片的平动能分布.
关键词:
CH2I2
离子速度成像
绝热和非绝热解离 相似文献
82.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
83.
Yah ZHAO Xiao Qing LIU Hong You ZHU Zi Ming YANG Rong HUANG 《中国化学快报》2006,17(12):1543-1546
Bridged bis(β-cyclodextrin)s (CDs), as a very important family of CD derivatives, have been known that they can significantly alter the molecular binding ability and selectivity toward a variety of guests in comparison with parent cyclodextrin. Their two… 相似文献
84.
Yong LU Hong WANG Ye LIU Ming Yuan HE 《中国化学快报》2006,17(10):1397-1400
Recently, miniature H2 generator to power fuel cells for portable/micro electronic devices and passenger propulsion has been the focus of intense research activities1-3. One of the strategies is to find simple CO-free H2 production with novel microreactor… 相似文献
85.
以己二酸酐和邻羟基苯甲酸为原料,制备了己二酸单(2-羧苯酚)酯,并以它为单体聚合得到了相应的聚酯酸酐.研究了温度、真空度对聚合物分子量的影响,得到了最佳的聚合条件:真空度66.66Pa,聚合温度200℃.在此条件下聚合2.5h,得到的聚己二酸单(2-羧苯酚)酯重均分子量达6498.另外,还对聚合物在不同pH值条件下的体外降解行为进行了研究. 相似文献
86.
D. Fong J. H. Hamilton A. V. Ramayya J. K. Hwang C. Goodin K. Li J. Kormicki J. O. Rasmussen Y. X. Luo S. C. Wu I. Y. Lee A. V. Daniel G. M. Ter-Akopian G. S. Popeko A. S. Fomichev A. M. Rodin Yu. Ts. Oganessian M. Jandel J. Kliman L. Krupa J. D. Cole M. A. Stoyer R. Donangelo W. C. Ma 《Physics of Atomic Nuclei》2006,69(7):1161-1167
The hot bimodal fission of 252Cf is reexamined with new high-statistics data. We constructed a γ-γ-γ coincidence cube for binary fission and LCP-gated γ-γ matrix for ternary fission. By identifying the secondary fission fragments from their γ-ray transitions, we measured the yields for various fission splits. The normal neutron yield distribution is found to be
Gaussian for Xe-Ru. However, the binary fission split of Ba-Mo is found to exhibit a bimodal neutron distribution with the
“hot mode” corresponding to ≈3.1% of the total yield. In α ternary fission, the first measurements of yields for specific fission splits are presented. The Te-α-Ru and Xe-α-Mo neutron yields fit well with a single mode, but the Ba-α-Zr split shows evidence for an enhanced hot mode with an intensity of ≈13.8% of the normal mode.
The text was submitted by the authors in English. 相似文献
87.
88.
Jian Ming ZHAN Bijan DAVVAZ K. P. SHUM 《数学学报(英文版)》2007,23(8):1345-1356
We describe the relationship between the fuzzy sets and the algebraic hyperstructures. In fact, this paper is a continuation of the ideas presented by Davvaz in (Fuzzy Sets Syst., 117: 477- 484, 2001) and Bhakat and Das in (Fuzzy Sets Syst., 80: 359-368, 1996). The concept of the quasicoincidence of a fuzzy interval value with an interval-valued fuzzy set is introduced and this is a natural generalization of the quasi-coincidence of a fuzzy point in fuzzy sets. By using this new idea, the concept of interval-valued (α,β)-fuzzy sub-hypermodules of a hypermodule is defined. This newly defined interval-valued (α,β)-fuzzy sub-hypermodule is a We shall study such fuzzy sub-hypermodules and sub-hypermodules of a hypermodule. generalization of the usual fuzzy sub-hypermodule. consider the implication-based interval-valued fuzzy 相似文献
89.
Precise measurement of magnetic moment of short-lived β-emitting nuclei12B ( I π=1+, T 1/2=20.18 ms)
Zhou Dongmei Zheng Yongnan Du Enpeng Xu Yongjun Zhu Jiazheng Yuan Daqing Wang Zhiqiang Luo Hailong Zuo Yi Ma Ruigang Duan Xiao M. Mihara M. Fukuda K. Matsuta T. Minamisono Zhu Shengyun 《中国科学G辑(英文版)》2004,47(5):531-539
The spin polarized β-emitting nuclei12B (I
π=1+,T
1/2=20.18 ms) were produced by the nuclear reaction11B(d, p)12B and by the selection technique of the incident deuteron energy and the12B recoil angle following the nuclear reaction. The nuclear magnetic moment of the short-lived nuclei12B was measured by β-NMR with the β-NMR and β-NQR setup established for the first time in China. The nuclear magnetic moment
of12B was determined to be μ=0.99993±0.00048 nm org=0.99993±0.00048 after the precise correction of the Knight shift. 相似文献
90.
In this paper, by means of the method of upper and lower solutions and monotone iterative technique, the existence of maximal and minimal solutions of the boundary value problems for first order impulsive delay differential equations is established. 相似文献