Eu3+-site occupation in CaTiO3 perovskite material at low temperature

In order to clarify the site occupancy of rare-earth ions in rare-earth doped perovskite materials, the un-doped pure CaTiO₃ and Eu³⁺-doped CaTiO₃ samples with a series of Ca/Ti ratio were synthesized via high-temperature solid-state reaction method. X-ray diffraction (XRD) powder patterns confirm that the crystal structure keeps invariant at various Ca/Ti ratios. Measurement results of unit-cell parameters and X-ray photoelectron spectroscopy (XPS) indicate that Eu³⁺ ions enter into the Ca²⁺ site. The high-resolution photoluminescence spectra of Eu³⁺ ions at 20 K in all samples did not witness a significant change under the excitation at different wavelength, implying that Eu³⁺ ions occupy only one type of site. Considering the small spectral splitting range of ⁵D₀ → ⁷F₂ transition and the large intensity ratio of ⁵D₀ → ⁷F₂/⁵D₀ → ⁷F₁, it can be concluded that Eu³⁺ occupies Ca²⁺ site with larger coordinate numbers rather than Ti⁴⁺ site.     

近地层大气光学湍流的分形和间歇性特征分析

利用光纤湍流测量系统获得了合肥西郊科学岛上气象观测场内下垫面平坦的水面上方0.48m、草地上方1.8m和23m高处的大气折射率起伏的观测数据,采用R/S分析法计算了近地层大气光学湍流的赫斯特指数和分形维数,统计分析了分形维数的日变化特征及概率分布特征。结果表明:对于一天的不同时段,分形维数在一定范围内动态变化,且中午时段相对稳定;在三种下垫面条件下,全天分形维数的值大多在1.3~1.4之间,其最可几概率位于1.35处,从均值来看,草地上方1.8m的分形维数最大,水面上方0.48m次之,草地上方23m处最小。最后,初步探讨了近地层大气光学湍流分形维数、间歇性指数和湍流发展程度的相关性。     

227-W output all-fiberized Tm-doped fiber laser at 1908 nm

In this paper, we report that a diode-pumped thulium-doped double clad silica fiber laser can provide powers of up to 227 W at 1908 nm, corresponding to a slope efficiency of 54.3%, and an optical-to-optical efficiency of 51.2%. The output power, to the best of our knowledge, is the highest output at 1908 nm. The beam quality M2 factor is about 1.56. Also discussed in this paper is the dependence of the laser performance on fiber length.     

透射式能见度仪动态范围扩展方法

提出了一种利用光学衰减片与电机组合,扩展透射式能见度仪动态范围的方法。通过改变加载到LED光源的调制信号的幅度,控制LED光源的发射光强;设计测量系统,选择固定透过率的衰减片;设置合理的系统阈值完成数据测量。对测量数据作拟合分析,结果表明:采用透过率为60%的中性密度衰减片,系统动态范围扩展了0.6倍;透过率为12%时,系统动态范围扩展了6.9倍。同时,通过选择不同透过率的中性密度衰减片,可实现系统动态范围的灵活扩展。     

基于拓扑结构的碱金属化合物摩尔磁化率的支持向量回归研究

基于经典电动力学导出的表征简单离子磁化率的磁性点价g_i所构建的分子磁性连接性指数?^mF及45种碱金属化合物的摩尔磁化率χ_m的实测数据集,利用粒子群寻优的支持向量回归（SVR）方法,建立了基于⁰F和¹F的碱金属化合物χ_m的预测模型,并与基于多元线性回归（MLR）模型的计算结果进行了比较.结果显示,基于9次交叉验证的SVR模型预测的平均绝对误差、平均相对误差绝对值以及均方根误差均比MLR模型小,表明SVR模型的回归预测能力优于MLR.研究表明,磁性连接性指数^mF是一种合适的分子描述符,SVR是一种预测碱金属化合物χ_m的有效方法. 关键词： 碱金属化合物 摩尔磁化率 支持向量回归 预测     

Evaluation of an oral carrier system in rats: bioavailability and gastrointestinal absorption properties of curcumin encapsulated PBCA nanoparticles

A new oral delivery system, polybutylcyanoacrylate nanoparticles (PBCNs), was introduced to improve the oral bioavailability of curcumin (CUR), a poorly soluble drug. The formulation was optimized by orthogonal design and the optimal PBCNs loading CUR exhibited a spherical shape under transmission electron microscopy with a range of 40?C400?nm. Physicochemical state of CUR in PBCN was investigated by X-ray diffraction and the possible structure changes occurring in CUR after conjugating with polybutylcyanoacrylate were studied with FTIR. The results indicated that CUR in PBCN was in a non-crystalline state and CUR was encapsulated in PBCN without chemical reaction. The oral pharmacokinetic study was conducted in rats and the relative bioavailability of CUR encapsulated PBCNs to the crude CUR was more than 800%. The in situ absorption experiment in rat intestine indicated the absorption was first order with passive diffusion mechanism. The absorption results in various segments of intestine showed that the main absorption sites were ileum and colon. It can be concluded that PBCNs as an oral carrier can significantly improve the oral absorption of a poorly soluble drug.     

基于压扩变换的60GHz正交频分复用光载无线通信系统实验研究

提出并实验研究了在60GHz正交频分复用(OFDM)-光载无线通信(ROF)系统中采用压扩变换技术降低OFDM信号峰值平均功率比(PAPR),并提高系统的接收灵敏度。实验结果表明,携带基于压扩变换的2.5Gb/s60GHz的OFDM-ROF信号经标准单模光纤传输50km后,在无色散补偿和误码率为10-3的条件下,当入纤功率为12dBm时,系统接收灵敏度提高约2.3dB,并且当互补累积分布函数(CCDF)为10-4时,OFDM信号的PAPR下降约3dB。     

Entanglement dynamics and Bell violation of three-qubit states coupled to an XY spin chain with Dzyaloshinski–Moriya interaction

We investigate the entanglement dynamics and Bell violation of three-qubit quantum states under an environment consisting of an XY spin chain with Dzyaloshinski–Moriya (DM) interaction. From the results, we find that the entanglement dynamics depends not only on the DM interaction, the magnetic field, and the anisotropy parameter but also on the number of the freedom degrees of the environment. The decoherence-free subspaces of our model have been identified and the Bell violation of quantum states is also discussed.     

Luminescence investigation of red phosphors Ca0.54Sr0.34−1.5xEu0.08Smx(MoO4)y (WO4)1−y for UV-white LED device

Ca_0.54Sr_0.34−1.5xEu_0.08Sm_x(MoO₄)_y (WO₄)_1−y red phosphors were prepared by solid-state reaction using Na⁺ as a charge compensator for light-emitting diodes (LED). The effects of Na⁺ concentration, synthesis temperature, reaction time and Eu³⁺ concentration were studied for the properties of luminescence and crystal structure of red phosphors. The results show that the optimum reaction condition is 6%, 900 °C, 2 h and 8%. The photoluminescence spectra show that red phosphors are effectively excited at 616 nm by 292, 395 and 465 nm. The wavelengths of 465 nm nicely match the widely applied emission wavelengths of blue LED chips.     

Scintillation index of astigmatic annular beams in a turbulent atmosphere

The scintillation properties of astigmatic annular beams in a weak turbulent atmosphere are investigated. Expression for the on-axis scintillation index of an astigmatic annular beam is derived. It is found that the scintillation index of an astigmatic annular beam can be smaller than that of a Gaussian beam, an elliptical Gaussian beam and a stigmatic annular beam in a weak turbulent atmosphere under certain conditions. The scintillation properties of astigmatic annular beams are closely controlled by its beam parameters.