Illumination of the shadow zone in a two-channel oceanic waveguide with a fine structure of sound speed inhomogeneities

The experimental data on the sound field structure, which were obtained by emitting a continuous pseudonoise signal (a midfrequency of 3.2 kHz) in a two-channel oceanic waveguide, are compared with the calculations performed by the wave program with allowance for the fine structure of the sound speed inhomogeneities. A considerable increase in the intensity of the sound field with a definite angular spectrum is observed in the upper channel in the first shadow zone, and, in the experiment, the increase begins nearer to the sound source than predicted by the wave and ray calculations for a smooth sound speed profile. These features of the field structure are explained by the illumination of the shadow zone by the regular scattering of signals from highly anisotropic fine-structure inhomogeneities of the sound speed profile, which are clearly pronounced in the region of the given oceanic experiment.     

Ultrasonic attenuation in a LiIO3 crystal

The temperature dependences of the attenuation of longitudinal acoustic waves along the x axis of a LiIO₃ crystal are studied experimentally by the method of Bragg diffraction of light by ultrasound. The measurements are performed in the temperature range from 215 to 335 K at frequencies of 400–690 MHz. Above 260 K, the attenuation is found to exhibit a frequency-independent growth of a relaxational character, which is used to calculate the enthalpy of the activation of ionic motion in the direction normal to the hexagonal axis. In addition, resonance attenuation peaks are observed; as the frequency increases, the peaks are shifted toward lower temperatures. A phenomenological model is proposed to explain the origin of the resonance absorption.     

Synthesis of oxazolidinedione derived bicalutamide analogs

The synthesis of chiral oxazolidinedione derived bicalutamide analogs has been discussed.     

Synchrotron radiation total reflection X-ray fluorescence (SR-TXRF) for evaluation of food contamination

Summary The objective of this study was to use synchrotron radiation total reflection X-ray fluorescence analysis (SR-TXRF) for the determination of metals and other elements in food available to the population in commercial establishments, in order to evaluate the risks of contamination by these products. The analyzed species were vegetables, leafy vegetables, fruits, cereal and grain. The results indicated that some species were contaminated by Cr, Cu, Zn and Pb with concentrations much higher than the reference values.     

Excess noise peaks in porous silicon-based diode structures

Results of an experimental observation of the voltage oscillations associated with a discrete tunneling of holes in porous silicon at room temperature are presented. The noise characteristics of diode structures with a porous silicon interlayer formed on heavily boron-doped silicon single crystals are studied. Peaks of excessive noise are observed at frequencies of ～1 MHz, at which single-electron oscillations should be expected. The peak noise power is found to increase with current according to the ～2.5 power law and, at a current density of 0.15 A/cm², to exceed the noise power of the receiver by three to four orders of magnitude. The complex shape of the noise spectrum and its extension to the higher frequency region with increasing current are explained by the three-dimensionality of the system of nanometer-sized silicon grains embedded in insulating silicon dioxide of porous silicon.     

High resolution electronic study of ONO, ONO and ONO: A rovibronic survey covering 11 800-14 380 cm

The 11 800-14 380 cm⁻¹ frequency range has been scanned for rotationally resolved rovibronic transitions in the A²B₂-X²A₁ electronic band system of the symmetric (C_2v) ¹⁶O¹⁴N¹⁶O and ¹⁸O¹⁴N¹⁸O isotopologues and in the corresponding electronic band system of the asymmetric (C_s) ¹⁸O¹⁴N¹⁶O isotopologue. The rotational analysis—reflecting minor differences in mass—in combination with symmetry induced spectral differences allows an identification of 68 ¹⁶O¹⁴N¹⁶O vibronic levels, 26 ¹⁸O¹⁴N¹⁸O vibronic levels and 51 ¹⁸O¹⁴N¹⁶O vibronic levels. The bands are recorded using near infrared fluorescence spectroscopy and a piezo valve based pulsed molecular beam expansion of premixed ¹⁸O₂ and ¹⁴N¹⁶O in Ar. The majority of the observed bands is rotationally assigned and can be identified as transitions starting from the vibrational ground state of one of the isotopologues. Numerous hot bands have also been identified. A comparison of the overall spectroscopic features of C_2v vs. C_s symmetric species provides qualitative information on symmetry dependence of vibronic couplings.     

Study of the dielectric properties of water in the frequency range 75–120 GHz

We study experimentally the frequency dependences of the refractive index n and the absorption coefficient k of distilled, sea, and river water. The measurements were performed using a quasioptical device with a backward-wave oscillator as the radiation source and OAP-7 optical-acoustic receivers at a water temperature of 27°C in the cell. The quantities n and k were determined from the measured transmission and reflection coefficients of the cell with water by means of joint numerical solution of the equations for these quantities. For distilled water in the frequency range f = 75–120 GHz, we obtained n = 6.142–3.926 · 10–2f[GHz] + 1.307 · 10–4(f[GHz])² and k = 3.607–2.101 · 10⁻² f[GHz] + 5.252 · 10–5(f[GHz])². On the whole, these data are in good agreement with the measurement results obtained by other authors at several frequencies of the indicated range and coincide with the calculation data based on the models by Meissner and Wentz and by Liebe et al. within the limits of the rms determination errors 0.05 and 0.02 for the parameters n and k, respectively. The values of n and k for different seawater samples and river water containing insoluble admixtures coincide with the values of these quantities for distilled water within the limits of the experimental measurement errors 3–5% and 1–2%, respectively. The dependences n(f) and k(f) obtained experimentally for seawater are compared with those calculated on the basis of the developed models. Measurements of the transmission spectrum of a cell with double distilled water were performed for low power density of radiation (less than μW/cm²) to reproduce the effect of water resonant transparency reported many times in the literature. Our measurements did not reveal any resonant features in the spectral behavior of the refractive index n and the absorption coefficient k of water and gave the same result as for a power density exceeding the threshold of appearance of this effect. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 49, No. 6, pp. 489–501, June 2006.