全文获取类型
收费全文 | 313861篇 |
免费 | 4268篇 |
国内免费 | 1091篇 |
专业分类
化学 | 170622篇 |
晶体学 | 4457篇 |
力学 | 13029篇 |
综合类 | 7篇 |
数学 | 36296篇 |
物理学 | 94809篇 |
出版年
2020年 | 1983篇 |
2019年 | 1955篇 |
2018年 | 1966篇 |
2017年 | 1875篇 |
2016年 | 3860篇 |
2015年 | 3236篇 |
2014年 | 4422篇 |
2013年 | 13980篇 |
2012年 | 10729篇 |
2011年 | 13365篇 |
2010年 | 8272篇 |
2009年 | 8255篇 |
2008年 | 12340篇 |
2007年 | 12572篇 |
2006年 | 12218篇 |
2005年 | 11156篇 |
2004年 | 10036篇 |
2003年 | 8848篇 |
2002年 | 8701篇 |
2001年 | 10113篇 |
2000年 | 7710篇 |
1999年 | 6115篇 |
1998年 | 4895篇 |
1997年 | 4733篇 |
1996年 | 4774篇 |
1995年 | 4364篇 |
1994年 | 4116篇 |
1993年 | 3940篇 |
1992年 | 4432篇 |
1991年 | 4293篇 |
1990年 | 4012篇 |
1989年 | 3831篇 |
1988年 | 4123篇 |
1987年 | 3787篇 |
1986年 | 3678篇 |
1985年 | 5317篇 |
1984年 | 5395篇 |
1983年 | 4378篇 |
1982年 | 4753篇 |
1981年 | 4793篇 |
1980年 | 4545篇 |
1979年 | 4664篇 |
1978年 | 4665篇 |
1977年 | 4644篇 |
1976年 | 4597篇 |
1975年 | 4508篇 |
1974年 | 4356篇 |
1973年 | 4524篇 |
1972年 | 2569篇 |
1971年 | 1879篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
951.
Radical reaction of a series of N-(2-bromoallyl)arylcarboxamides led to the production of 4-arylpyrrolidin-2-ones and directly reduced materials in comparable yields. A cascade process, involving sequential 5-exo-trig spirocyclisation, β-scission, and 5-endo-trig cyclisation of the resulting acyl radical, is proposed to explain the pyrrolidinone products. 相似文献
952.
The first-order harmonic balance method via first Fourier coefficient is used to construct an approximate frequency-amplitude relation for a Duffing-harmonic oscillator. This relation is in agreement with the result obtained by the Ritz procedure. 相似文献
953.
J. Fülöp 《Mathematical Methods of Operations Research》1991,35(1):1-13
This paper shows that any linear disjunctive program with a finite number of constraints can be transformed into an equivalent facial program. Based upon linear programming technique, a new, finite cutting plane method is presented for the facial programs.
Zusammenfassung Die Arbeit zeigt, daß jedes lineare disjunktive Optimierungsproblem mit endlich vielen Restriktionen in ein äquivalentes Fazetten-Problem transformiert werden kann. Auf der Grundlage von linearer Optimierungstechnik wird für das Fazetten-Problem ein neues, endliches Schnittebenenverfahren vorgestellt.相似文献
954.
A Haag-Ruelle Scattering Theory for Euclidean Lattice Field Theories is developed.Work supported by DAAD, Deutscher Akademischer Austauschdienst. Partially supported by CNPq 相似文献
955.
The composition of thin perovskite films, especially the oxygen content, is a crucial parameter which influences many physical properties, such as conductivity and catalytic activity. Films produced by pulsed laser deposition are normally annealed in an oxygen atmosphere after deposition to achieve a desired oxygen content. In pulsed reactive crossed beam laser ablation, no annealing step is necessary, but a fundamental question regarding this deposition technique is still open: where does the oxygen in the films come from?There are three possibilities, i.e. from the target, from the gas background, or from the gas pulse. To answer this question two experiments were performed: 18O2 was used during the deposition process as background gas with 16O anions in the target and 16O2 gas pulse, and a 18O2 gas pulse with 16O from the target and background. These experiments revealed that the quantification of the oxygen origin is only possible, when no oxygen exchange occurs at the deposition temperature. The films are characterized after deposition by elastic recoil detection analysis (ERDA) to determine the 16O/18O ratio. Experiments with different oxidizing species in the gas pulse (N2O and O2) confirm that the oxidizing potential (N2O > O2) as well as the number of molecules are important. 相似文献
956.
Investigations of thickness induced percolation process in Ptξ-Al2O3 nano-composites were carried out using grazing angle X-ray scattering. It is shown that the morphological characteristics of the nano-scaled Pt particles change significantly within the growth transversal direction. The initially non percolated two phases Ptξ-Al2O3 nano-composites show a noteworthy tendency to a percolated morphology with a gradual transversal increase of Pt nano-particles' average diameter in addition to the increase of the Pt nano-particles' poly-dispersity. This transversal morphological evolution is followed by a percolation phenomenon of the Pt nano-particles for a thickness of about ∼119.5 nm. This transversal morphological evolution seems to corroborate far too much with a columnar growth process. 相似文献
957.
958.
A file ofn records can be sorted in linear time givenO(log(n)) processors. Four such algorithms are presented and analyzed. All of them have reasonable hardware requirements; no memory access conflicts are generated; a constant number of communication lines per processor are needed (except for one case); and the space requirements areO(n) orO(n log(log(n))). 相似文献
959.
Endoscopic illumination systems conduct light down a built-in fibre-optic bundle to illuminate the object. Many modern endoscopes employ wide-field imaging optical systems and therefore require an illuminating beam of large divergence. This is commonly provided by placing a strong diverging lens at the far end of the fibre bundle, but it results in a poor uniformity of illumination in the object space. This paper describes the design of a telescopic illumination system to overcome this problem. 相似文献
960.
Two methods for sampling and concentration of volatile organic compounds are reported. In the first method, traps coated with a very thick film (ca. 100 μm) of cross-linked silicone stationary phase are employed. Such thick films can be prepared with a modified dynamic coating procedure, which is briefly described. The low phase ratio traps can be utilized for enrichment of volatiles from gaseous as well as aqueous matrices. The second technique is based on chromatographic evaporation of a solvent in a capillary tube, where the process is sustained by a repeated sample injection and a cyclic flow reversal. In this way, large solvent volumes can be handled by a small volume system. Under optimal conditions, when using a solvent barrier, quantitative recovery is possible even for compounds of comparatively high volatility. Another important application of the technique is extraction of trace components from gases such as headspace samples, polluted air, etc. 相似文献