Singular Perturbations of Self-Adjoint Operators

Singular finite rank perturbations of an unbounded self-adjoint operator A ₀ in a Hilbert space ₀ are defined formally as A ₍₎=A ₀+GG ^*, where G is an injective linear mapping from = ^d to the scale space _-k(A₀)k , kN, of generalized elements associated with the self-adjoint operator A ₀, and where is a self-adjoint operator in . The cases k=1 and k=2 have been studied extensively in the literature with applications to problems involving point interactions or zero range potentials. The scalar case with k=2n>1 has been considered recently by various authors from a mathematical point of view. In this paper, singular finite rank perturbations A ₍₎ in the general setting ran G – _k (A ₀), kN, are studied by means of a recent operator model induced by a class of matrix polynomials. As an application, singular perturbations of the Dirac operator are considered.     

One-dimensional three-body problem via symbolic dynamics

Symbolic dynamics is applied to the one-dimensional three-body problem with equal masses. The sequence of binary collisions along an orbit is expressed as a symbol sequence of two symbols. Based on the time reversibility of the problem and numerical data, inadmissible (i.e., unrealizable) sequences of collisions are systematically found. A graph for the transitions among various regions in the Poincare section is constructed. This graph is used to find an infinite number of periodic sequences, which implies an infinity of periodic orbits other than those accompanying a simple periodic orbit called the Schubart orbit. Finally, under reasonable assumptions on inadmissible sequences, we prove that the set of admissible symbol sequences forms a Cantor set. (c) 2000 American Institute of Physics.     

Boundary-value problems for two-dimensional canonical systems

The two-dimensional canonical systemJy=–Hy where the nonnegative Hamiltonian matrix functionH(x) is trace-normed on (0, ) has been studied in a function-theoretic way by L. de Branges in [5]–[8]. We show that the Hamiltonian system induces a closed symmetric relation which can be reduced to a, not necessarily densely defined, symmetric operator by means of Kac' indivisible intervals; of. [33], [34]. The formal defect numbers related to the system are the defect numbers of this reduced minimal symmetric operator. By using de Branges' one-to-one correspondence between the class of Nevanlinna functions and such canonical systems we extend our canonical system from (0, ) to a trace-normed system on which is in the limit-point case at ±. This allows us to study all possible selfadjoint realizations of the original system by means of a boundaryvalue problem for the extended canonical system involving an interface condition at 0.     

A generative model and a generalized trust region Newton method for noise reduction

In practical applications related to, for instance, machine learning, data mining and pattern recognition, one is commonly dealing with noisy data lying near some low-dimensional manifold. A well-established tool for extracting the intrinsically low-dimensional structure from such data is principal component analysis (PCA). Due to the inherent limitations of this linear method, its extensions to extraction of nonlinear structures have attracted increasing research interest in recent years. Assuming a generative model for noisy data, we develop a probabilistic approach for separating the data-generating nonlinear functions from noise. We demonstrate that ridges of the marginal density induced by the model are viable estimators for the generating functions. For projecting a given point onto a ridge of its estimated marginal density, we develop a generalized trust region Newton method and prove its convergence to a ridge point. Accuracy of the model and computational efficiency of the projection method are assessed via numerical experiments where we utilize Gaussian kernels for nonparametric estimation of the underlying densities of the test datasets.     

Utilization of cascade chemo-bio catalysis for the synthesis of R -1-phenylethyl acetate

Liquid phase tert-butylation of m-cresol was carried out using 12-tungstosilicic acid supported on neutral alumina by varying different parameters. The reaction has also been carried out by using calcined samples under optimized conditions. The present catalyst shows an excellent activity of 93.2%, conversion of 100% selectivity for the o-isomer, an important industrial product.     

Cleavage and isomerization of UpU promoted by dinuclear metal ion complexes

The catalysis of phosphoryl transfer by metal ions has been intensively studied in both biological and artificial systems, but the status of the transient pentacoordinate phosphoryl species (as transition state or intermediate) is the subject of considerable debate. We report that dinuclear metal ion complexes that incorporate second sphere hydrogen bond donors not only promote the cleavage of RNA fragments just as efficiently as the activated analogue HPNPP but also provide the first examples of metal ion catalyzed phosphate diester isomerization close to neutral pH. This observation implies that the reaction catalyzed by these complexes involves the formation of a phosphorane intermediate that is sufficiently long-lived to pseudorotate.     

Parametrization of Contractive Block Operator Matrices and Passive Discrete-Time Systems

Passive linear systems τ = have their transfer function in the Schur class S . Using a parametrization of contractive block operators the transfer function is connected to the Sz.-Nagy–Foiaş characteristic function of the contraction A. This gives a new aspect and some explicit formulas for studying the interplay between the system τ and the functions and . The method leads to some new results for linear passive discrete-time systems. Also new proofs for some known facts in the theory of these systems are obtained. Dedicated to Eduard Tsekanovskiĭ on the occasion of his seventieth birthday This work was supported by the Research Institute for Technology at the University of Vaasa. The first author was also supported by the Academy of Finland (projects 212146, 117617) and the Dutch Organization for Scientific Research N.W.O. (B 61-553). Received: December 22, 2006. Revised: February 6, 2007.     

Tolokonnikov’s Lemma for Real H ∞ and the Real Disc Algebra

We prove Tolokonnikov’s Lemma and the inner-outer factorization for the real Hardy space , the space of bounded holomorphic (possibly operator-valued) functions on the unit disc all of whose matrix-entries (with respect to fixed orthonormal bases) are functions having real Fourier coefficients, or equivalently, each matrix entry f satisfies for all z ∈ . Tolokonnikov’s Lemma for means that if f is left-invertible, then f can be completed to an isomorphism; that is, there exists an F, invertible in , such that F = [ f f _c ] for some f _c in . In control theory, Tolokonnikov’s Lemma implies that if a function has a right coprime factorization over , then it has a doubly coprime factorization in . We prove the lemma for the real disc algebra as well. In particular, and are Hermite rings. The work of the first author was supported by Magnus Ehrnrooth Foundation. Received: December 5, 2006. Revised: February 4, 2007.