全文获取类型
收费全文 | 621篇 |
免费 | 18篇 |
国内免费 | 4篇 |
专业分类
化学 | 178篇 |
晶体学 | 8篇 |
力学 | 5篇 |
数学 | 216篇 |
物理学 | 236篇 |
出版年
2022年 | 4篇 |
2021年 | 16篇 |
2020年 | 11篇 |
2019年 | 15篇 |
2018年 | 19篇 |
2017年 | 17篇 |
2016年 | 21篇 |
2015年 | 13篇 |
2014年 | 14篇 |
2013年 | 24篇 |
2012年 | 30篇 |
2011年 | 32篇 |
2010年 | 21篇 |
2009年 | 18篇 |
2008年 | 37篇 |
2007年 | 32篇 |
2006年 | 29篇 |
2005年 | 19篇 |
2004年 | 27篇 |
2003年 | 27篇 |
2002年 | 16篇 |
2001年 | 8篇 |
2000年 | 13篇 |
1998年 | 12篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 11篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 9篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 7篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1977年 | 8篇 |
1976年 | 2篇 |
1975年 | 12篇 |
1974年 | 7篇 |
1973年 | 4篇 |
1972年 | 6篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有643条查询结果,搜索用时 15 毫秒
91.
Nick Gravin Mihail N. Kolountzakis Sinai Robins Dmitry Shiryaev 《Discrete and Computational Geometry》2013,50(4):1033-1050
We study multiple tilings of 3-dimensional Euclidean space by a convex body. In a multiple tiling, a convex body $P$ is translated with a discrete multiset $\Lambda $ in such a way that each point of ${\mathbb {R}}^d$ gets covered exactly $k$ times, except perhaps the translated copies of the boundary of $P$ . It is known that all possible multiple tilers in ${\mathbb {R}}^3$ are zonotopes. In ${\mathbb {R}}^2$ it was known by the work of Kolountzakis (Discrete Comput Geom 23(4):537–553, 2000) that, unless $P$ is a parallelogram, the multiset of translation vectors $\Lambda $ must be a finite union of translated lattices (also known as quasi periodic sets). In that work (Kolountzakis, Discrete Comput Geom 23(4):537–553, 2000) the author asked whether the same quasi-periodic structure on the translation vectors would be true in ${\mathbb {R}}^3$ . Here we prove that this conclusion is indeed true for ${\mathbb {R}}^3$ . Namely, we show that if $P$ is a convex multiple tiler in ${\mathbb {R}}^3$ , with a discrete multiset $\Lambda $ of translation vectors, then $\Lambda $ has to be a finite union of translated lattices, unless $P$ belongs to a special class of zonotopes. This exceptional class consists of two-flat zonotopes $P$ , defined by the Minkowski sum of two 2-dimensional symmetric polygons in ${\mathbb {R}}^3$ , one of which may degenerate into a single line segment. It turns out that rational two-flat zonotopes admit a multiple tiling with an aperiodic (nonquasi-periodic) set of translation vectors $\Lambda $ . We note that it may be quite difficult to offer a visualization of these 3-dimensional non-quasi-periodic tilings, and that we discovered them by using Fourier methods. 相似文献
92.
The possibility of a displacement of the front of a shock wave formed in a 1D nitrogen flow to the low gas pressure region (in front of the shock wave) upon absorption of the laser pulse energy in the region of the shock wave front is demonstrated using computer simulation based on the finite difference technique. The low-pressure region formed in the region of the initially high pressure under the action of a light pulse moves in the direction opposite to the direction of propagation of the shock wave front. Analysis is carried out for a typical experimental situation corresponding to the growth of carbon-nitride nanofilms. 相似文献
93.
94.
This study is devoted to the problem of the electron-vibrational interaction in 4f-5d optical transitions. We analyze the room temperature experimental data on the vibronically assisted broad bands arising from the 4f-5d transitions in Ba, Ca, and Sr thiogallates doped with Eu2+ ions. An approximate simple expression is given for the shape function of the broad vibronic bands with allowance for the terms corresponding to the emission (absorption) from both ground and first excited vibrational levels. We estimate the vibronic coupling parameters and the Stokes shifts for these systems. The theoretical results are in a good agreement with the experimental data. 相似文献
95.
96.
Lucian G. Bahrin Henning Hopf Peter G. Jones Mihail L. Birsa Laura G. Sarbu 《Molecules (Basel, Switzerland)》2020,25(22)
The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. Pseudo-geminal bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic procedure that involves 4,15-bis(acetyl)[2.2]paracyclophane, a new compound of interest for many researchers. 相似文献
97.
Dmytro Strilets Dr. Shixin Fa Arthur Hardiagon Dr. Marc Baaden Prof. Tomoki Ogoshi Dr. Mihail Barboiu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(51):23413-23419
Artificial water channels mimicking natural aquaporins (AQPs) can be used for selective and fast transport of water. Here, we quantify the transport performances of peralkyl-carboxylate-pillar[5]arenes dimers in bilayer membranes. They can transport ≈107 water molecules/channel/second, within one order of magnitude of the transport rates of AQPs, rejecting Na+ and K+ cations. The dimers have a tubular structure, superposing pillar[5]arene pores of 5 Å diameter with twisted carboxy-phenyl pores of 2.8 Å diameter. This biomimetic platform, with variable pore dimensions within the same structure, offers size restriction reminiscent of natural proteins. It allows water molecules to selectively transit and prevents bigger hydrated cations from passing through the 2.8 Å pore. Molecular simulations prove that dimeric or multimeric honeycomb aggregates are stable in the membrane and form water pathways through the bilayer. Over time, a significant shift of the upper vs. lower layer occurs initiating new unexpected water permeation events through toroidal pores. 相似文献
98.
Crystallography Reports - A group-theoretical classification of cation and anion orders of crystals with a perovskite structure is presented. Aristotypes are idealized structures (phases), from... 相似文献
99.
Dr. Shao-Ping Zheng Dr. Ji-Jun Jiang Dr. Arie van der Lee Dr. Mihail Barboiu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(43):19082-19088
Transmembrane protein channels are an important inspiration for the design of artificial ion channels. Their dipolar structure helps overcome the high energy barrier to selectively translocate water and ions sharing one pathway, across the cell membrane. Herein, we report that the amino-imidazole (Imu) amphiphiles self-assemble via multiple H-bonding to form stable artificial Cl−-channels within lipid bilayers. The alignment of water/Cl− wires influences the conduction of ions, envisioned to diffuse along the hydrophilic pathways; at acidic pH, Cl−/H+ symport conducts along a partly protonated channel, while at basic pH, higher Cl−/OH− antiport translocate through a neutral channel configuration, which can be greatly activated by applying strong electric field. This voltage/pH regulated channel system represents an unexplored alternative for ion-pumping along artificial ion-channels, parallel to that of biology. 相似文献
100.