全文获取类型
收费全文 | 621篇 |
免费 | 18篇 |
国内免费 | 4篇 |
专业分类
化学 | 178篇 |
晶体学 | 8篇 |
力学 | 5篇 |
数学 | 216篇 |
物理学 | 236篇 |
出版年
2022年 | 4篇 |
2021年 | 16篇 |
2020年 | 11篇 |
2019年 | 15篇 |
2018年 | 19篇 |
2017年 | 17篇 |
2016年 | 21篇 |
2015年 | 13篇 |
2014年 | 14篇 |
2013年 | 24篇 |
2012年 | 30篇 |
2011年 | 32篇 |
2010年 | 21篇 |
2009年 | 18篇 |
2008年 | 37篇 |
2007年 | 32篇 |
2006年 | 29篇 |
2005年 | 19篇 |
2004年 | 27篇 |
2003年 | 27篇 |
2002年 | 16篇 |
2001年 | 8篇 |
2000年 | 13篇 |
1998年 | 12篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 11篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 9篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 7篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1977年 | 8篇 |
1976年 | 2篇 |
1975年 | 12篇 |
1974年 | 7篇 |
1973年 | 4篇 |
1972年 | 6篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有643条查询结果,搜索用时 15 毫秒
21.
We report on a global potential energy hypersurface for the upper sheet of the lowest triplet state of H3+. The analytic representation is based on the double many-body expansion theory. The ab initio data points, calculated with a large cc-pV5Z basis, are represented with a root mean square deviation of only 5.54 cm(-1) in the energy region below the H(+)+2H(2S) dissociation threshold. The quasi-bound vibronic states supported by this surface have also been calculated. 相似文献
22.
Mihaylov M Chakarova K Hadjiivanov K Marie O Daturi M 《Langmuir : the ACS journal of surfaces and colloids》2005,21(25):11821-11828
Different carbonyls are formed after CO adsorption at ambient temperature on a Pt-Na-mordenite (Pt-Na-MOR) sample. Pt(3+)(CO)(2) dicarbonyls (nu(s) at 2205 cm(-1) and nu(as) at 2167 cm(-1)) are decomposed without formation of monocarbonyls. The respective mixed-ligand species, Pt(3+)((12)CO)((13)CO), formed after (12)CO-(13)CO coadsorption, display bands at 2192 and 2131 cm(-1), in excellent agreement with the theoretically calculated values. Pt(2+)-CO species absorb at 2145 cm(-1) and are not able to accept a second CO molecule. Pt(+)-CO carbonyls are characterized by a band at 2111 cm(-1). Under CO equilibrium pressure, these species are converted into dicarbonyls (nu(s) at 2135 cm(-1) and nu(as) at 2101 cm(-1)). The respective mixed-ligand species, Pt(+)((12)CO)((13)CO), manifest bands at 2123 and 2069 cm(-1), in good agreement again with the theory. Different carbonyls of metallic platinum are observed below 2100 cm(-)(1). In addition, weakly adsorbed CO was registered as Na(+)-CO complexes (2177 and 2165 cm(-1)) and Na(+)-OC-Na(+) species (2138 cm(-1)). It was found that during desorption of CO platinum was reduced, ultimately to metal. However, heating in a NO + O(2) mixture leads to reoxidation of the metal particles and restoration of the initial state of the sample. 相似文献
23.
Under high pressure conditions, cycloheptatriene reacts with methyl propiolate to afford mono-, bis- and trisadducts all retaining, the norcaradiene structure. The four new compounds are formed via [4+21] and [2+2+2] cycloadditions. The latter are examples for the high pressure extension of the scope of homo-Diels-Alder reactions. 相似文献
24.
Dr. Christiane Stoll Prof. Dr. Mihail Atanasov Jascha Bandemehr Prof. Dr. Frank Neese Clemens Pietzonka Prof. Dr. Florian Kraus Prof. Dr. Antti J. Karttunen Dr. Markus Seibald Assoc. Prof. Dr. Gunter Heymann Prof. Dr. Hubert Huppertz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(38):9801-9813
As a consequence of the static Jahn-Teller effect of the 5E ground state of MnIII in cubic structures with octahedral parent geometries, their octahedral coordination spheres become distorted. In the case of six fluorido ligands, [MnF6]3− anions with two longer and four shorter Mn−F bonds making elongated octahedra are usually observed. Herein, we report the synthesis of the compound K3[MnF6] through a high-temperature approach and its crystallization by a high-pressure/high-temperature route. The main structural motifs are two quasi-isolated, octahedron-like [MnF6]3− anions of quite different nature compared to that met in ideal octahedral MnIII Jahn-Teller systems. Owing to the internal electric field of Ci symmetry dominated by the next-neighbour K+ ions acting on the MnIII sites, both sites, the pseudo-rhombic (site 1) and the pseudo-tetragonally elongated (site 2) [MnF6]3− anions are present in K3[MnF6]. The compound was characterized by single-crystal and powder X-ray diffraction, and magnetometry as well as by FTIR, Raman, and ligand field spectroscopy. A theoretical interpretation of the electronic structure and molecular geometry of the two Mn sites in the lattice is given by using a vibronic coupling model with parameters adjusted from multireference ab-initio cluster calculations. 相似文献
25.
26.
27.
This note gives necessary and sufficient conditions for exponential stability of semigroups of linear operators in Banach spaces. Generalizations of a well-known result due to Datko, Pazy and Neerven are obtained for the case of semigroups of operators that are not strongly continuous. 相似文献
28.
gota Simon Adriana Smarandache Vicentiu Iancu Mihail Lucian Pascu 《Molecules (Basel, Switzerland)》2021,26(8)
The evolution of different antimicrobial drugs in terrestrial, microgravity and hypergravity conditions is presented within this review, in connection with their implementation during human space exploration. Drug stability is of utmost importance for applications in outer space. Instabilities may be radiation-induced or micro-/hypergravity produced. The antimicrobial agents used in space may have diminished effects not only due to the microgravity-induced weakened immune response of astronauts, but also due to the gravity and radiation-altered pathogens. In this context, the paper provides schemes and procedures to find reliable ways of fighting multiple drug resistance acquired by microorganisms. It shows that the role of multipurpose medicines modified at the molecular scale by optical methods in long-term space missions should be considered in more detail. Solutions to maintain drug stability, even in extreme environmental conditions, are also discussed, such as those that would be encountered during long-duration space exploratory missions. While the microgravity conditions may not be avoided in space, the suggested approaches deal with the radiation-induced modifications in humans, bacteria and medicines onboard, which may be fought by novel pharmaceutical formulation strategies along with radioprotective packaging and storage. 相似文献
29.
30.
S. Yu. Igashov A. M. Shirokov 《Bulletin of the Russian Academy of Sciences: Physics》2007,71(6):769-775
An approach is developed which allows the JISP16 realistic NN interaction to be included in calculations within the algebraic version of the resonating group approach. A particular α + n system is examined. The approach is based on the use of the generating function method. The results obtained can be generalized to the case of more complicated systems and included in calculations of potentials with separable coordinate dependence. 相似文献