A Mild and Efficient Synthesis of Chiral N-Boc-α-aminoaldehydes

N-Boc-α-aminoaldehydes, represented by Boc-L-leucinal and its congener Boc-L- phenylalaninal, have received considerable attention in the past four decades1. This interest mainly stems from their wide application as important synthons in the preparation …     

荧光层析法研究由胶束溶液分离出的两种抗菌素

喹诺酮药物是一类重要的化学合成抗菌素 ,其临床应用正在不断扩大[1] 。氧氟沙星 (OFLX)和环丙沙星 (CPLX)结构非常相似。本文采用胶束薄层色谱法分离了两种药物。加入 1%氨水的 0 0 0 15mol·L-1十六烷基三甲基溴化铵 (CTAB)和 1%十二烷基磺酸钠 (SDS)的等体积水溶液作为展开剂 ,聚酰胺薄膜作为固定相。考查了CTAB浓度 ,SDS浓度及氨水对氧氟沙星和环丙沙星Rf 值的影响。在选定条件下 ,Rf 值分别为 0 87和 0 76 ,在激发波长为 2 80nm处对其进行了荧光测定。测定了该方法的稳定性和灵敏度。本文首次使用胶束溶液分离了氧氟沙星和环丙沙星     

态|Ψ_n~((2))〉_q的广义非线性等阶N次方H压缩效应

构造了一种新型的多模叠加态 |Ψ(2 )n 〉q=C(R)n |{ -i Z*j }〉q+C(0 )n |{ 0 j}〉q;并首次详细地研究了此量子态的等阶 N次方 H压缩特性 .大量的计算和分析表明 :态 |Ψ(2 )n 〉q是一种多模典型的非经典光场 ;还发现了“相似压缩”等现象     

SURFACE MODIFICATION AND DISPERSION OF NANODIAMOND IN CLEAN OIL

The effect of different kinds of surfactants on the size distribution of nanodiamond particles in clean oil was studied.Results show that the dispersing stability of nanodiamond modified with surfactangts YS-1 and SB-18 simulta-neously is much better than those modified with either of them because of synergism of the surfactangts.And the particle size distribution in the system can be improved remarkably after the adoption of hyperdispersants such as SA-E and SA-F.Anchoring groups of those hyperdispersants can be bonded with the particle surface by chemical and/or hydrogen bonding and their soluble chains are well compatible with the dispersion media.As a result,the particles are uniformly distrbuted in the system owing to the steric stabilization.A very stable clean-oil based nanodiamond suspension with an average particle size of around 53.2 nm was prepared.     

构造本构方程的另一种方法——非平衡不可逆热力学方法

重点介绍了以Onsager-Casimir倒易定律为基础,从不可逆热力学观点出发,对远离平衡状态,引进新的变量(被称为动态变量),构造本构方程．并以简单剪切流场为例,求出了测黏函数．     

双周期圆截面纤维复合材料平面问题的解析法

结合双准周期Riemann边值问题理论与Eshelby等效夹杂原理，为双周期圆截面纤维复合材 料平面问题发展了一个实用有效的解析方法，获得了问题的全场级数解并与有限元结果进行 了比较. 该方法为非均匀材料的力学性质分析和复合材料等新材料的微结构设计提供了 一个有效的计算工具，也可用来评估有限元等数值与近似方法的精度.     

SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION

A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane.     

An actuator-disc model for the prediction of abrupt stall in an axial compressor rotor

The representation of loss in a cascade by the appearance of blockage has been extended to deal with blade rows by the use of a source distribution to represent this blockage, and in the case of the actuator disc approximation, the presence of sources is confined to an axi-symmetric dìstribution over the actuator disc. It is found that if a typical dependence of loss (and consequently diffusion ratio) upon incidence for each section of an axial compressor rotor is represented in this manner, the influence of blockage on the axial velocity distribution may be found using the potential equation combined with the usual actuator disc approximation. Study of the behaviour of the controlling ordinary differential equation for the axial velocity ahead of the disc reveals that as the flow is reduced, the equation contains a singularity within the range of radius and a meaningful solution does not exist. This result is interpreted as the limit to continuous operation and reasonable agreement between this predicted limit and the appearance of abrupt stall (experimentally) is found.     

平面弹性介质多孔多裂纹问题的一种数值方法

提出了平面弹性介质中多孔洞多裂纹相互作用问题的一种数值计算方 法. 通过把适于单一裂纹的Bueckner原理扩充到含有多孔洞多裂纹的一般体系，将原问题 分解为承受远处载荷不含裂纹不含孔洞的均匀问题，和在远处不承受载荷但在裂纹面上和孔 洞表面上承受面力的多孔洞多裂纹问题. 于是，以应力强度因子作为参量的问题可以通过考 虑后者(多孔洞多裂纹问题)来解决，而利用提出的杂交位移不连续法，这种多孔 洞多裂纹问题是容易数值求解的. 算例说明该数值方法对分析平面弹性介质中多孔洞多裂纹 相互作用的问题既简单又有效.     

白洋淀内水体的流动特征研究

研究了风对白洋淀内水体循环流动的影响，研究指出：(1)风应力可看作是水体循环 的主要驱动力. (2)在风应力的作用下，水体表层的流动主方向与风的方向一致，下层水体 的流动方向与表层方向相逆或近似相逆. (3)表层以下水体流动复杂，次表层水平流动有明 显的双涡结构. (4)淀底地形对水体垂向流动影响很大，垂向速度变化复杂，垂向上有双涡 流动现象. 从动力学角度研究了淀内水体流动的情况.