全文获取类型
收费全文 | 543篇 |
免费 | 30篇 |
国内免费 | 1篇 |
专业分类
化学 | 419篇 |
晶体学 | 12篇 |
力学 | 8篇 |
数学 | 38篇 |
物理学 | 97篇 |
出版年
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2018年 | 12篇 |
2017年 | 6篇 |
2016年 | 8篇 |
2015年 | 14篇 |
2014年 | 11篇 |
2013年 | 34篇 |
2012年 | 19篇 |
2011年 | 30篇 |
2010年 | 19篇 |
2009年 | 14篇 |
2008年 | 50篇 |
2007年 | 29篇 |
2006年 | 33篇 |
2005年 | 27篇 |
2004年 | 25篇 |
2003年 | 21篇 |
2002年 | 21篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 7篇 |
1982年 | 11篇 |
1981年 | 12篇 |
1980年 | 12篇 |
1979年 | 7篇 |
1978年 | 9篇 |
1977年 | 12篇 |
1976年 | 7篇 |
1975年 | 6篇 |
1974年 | 5篇 |
1973年 | 2篇 |
1962年 | 2篇 |
排序方式: 共有574条查询结果,搜索用时 15 毫秒
481.
When two shear deformations γ1 and γ2 are successively applied to an entangled polymeric system, a composite temporary network is formed. In this article a simple method is proposed for evaluating separately the contributions from the component networks of different deformations, γ1 + γ2 and γ2, to the observed shear and normal stresses. The method is applied to literature data for a polystyrene solution. It is revealed that the entangled chain segments formed between the applications of two deformations relax very rapidly, while those formed prior to the first deformation do not relax for quite a long time. The result is in accord with the conjecture based on the tube model of entanglement that the chain ends lose their orientation as the chain creeps out of an oriented tube. 相似文献
482.
Takaharu Otsuka Takahiro Mizusaki Yutaka Utsuno Michio Honma 《Czechoslovak Journal of Physics》1998,48(6-7):707-714
We propose a Quantum Monte Carlo diagonalization method for solving the quantum many-body interacting systems. Not only the
ground state but also low-lying excited states are obtained with their wave functions. Consequently the level structure of
low-lying states can be studied with realistic interactions. After testing this method with48Cr, we report that the doubly closed shell probability of56Ni is shown to be only 53% in a full pf shell calculation, in contrast to the corresponding probability of48Ca which reaches 86%. The most recent results on32Mg are presented.
Presented by T. Otsuka at the International Conference on “Atomic Nuclei and Metallic Clusters”, Prague, September 1–5, 1997.
This work was supported in part by Grant-in-Aid for Scientific Research (B) (No. 08454058) from the Ministry of Education,
Science and Culture. 相似文献
483.
484.
485.
Sigeru Torii Hideo Tanaka Norio Saitoh Takashi Siroi Michio Sasaoka Junzo Nokami 《Tetrahedron letters》1981,22(33):3193-3196
Chemoselective electrochlorination of the methyl group on the 3-methyl-3-butenoate moiety of thiazoline-azetidinone derivatives derived from penicillins G and V has been performed in a CH2Cl2-H2O-NaCl-H2SO4-(Pt or C electrodes) system by adjusting the amount of electricity passed as well as the concentration of Cl? in the media. 相似文献
486.
Kunihiro Osaki Shinichi Kimura Michio Kurata 《Journal of Polymer Science.Polymer Physics》1981,19(3):517-527
The shear stress σ, two components of birefringence, and extinction angle were measured for a concentrated polystyrene solution in step-shear deformation of magnitude of shear 0.3 ≤ γ ≤ 4.0. The stress-optical coefficient did not depend on either γ or time. The first and the second normal-stress differences v1 and v2 were evaluated with the use of the stress-optical law. Over a certain range of long times, σ could be factored as σ = γh(γ)G(t) and the quantity h(γ) agreed with the prediction of the Doi–Edwards theory based on the de Gennes tube model of entangled polymer chains. At short times the effect of γ on σ/γ was smaller than at long times. The relaxation spectrum became approximately independent of γ at the short-time end of the rubbery plateau region. The ratios v1/σ and v2/v1 were independent of time and were in quantitative agreement with those predicted by the Doi–Edwards theory: v1/σ was equal to γ, v2/v1 was negative, and |v2/v1| decreased with increasing γ. 相似文献
487.
488.
If the collisional ionization is chiefly due to energy transfer from the polar-molecule rotation to an electron in a high Rydberg state of the atom, then theory predicts that the cross section averaged over a thermal distribution of rotational states should show step-like structure as a function of the energy of the Rydberg state. This structure has been experimentally detected, and it can be considered as direct evidence of the rotational effect in the collisional ionization. 相似文献
489.
Naoto Arai Michio Sorai Hiroshi Suga Syûzô Seki 《Journal of Physics and Chemistry of Solids》1977,38(12):1341-1350
The heat capacity of polycrystalline Fe[S2CN(C2H5)2]2Cl has been measured in the temperature range from 0.411 to 19.55 K. The transition between ferromagnetic and paramagnetic states is characterized by a sharp λ-type anomaly centered at the Curie temperature, Tc = 2.412 ± 0.008 K. The enthalpy and the entropy of transition are 40.475 J mol?1 and 11.199 J K?1mol?1 (= 1.347 R), respectively. The transition entropy is only 2.81% smaller than R In 4. This fact ascertains that the spin manifold is really a quartet. The ground spin states of the present compound are characterized by a zero-field splitting of the state into two Kramers' doublets. The overlapping non-cooperative Schottky-type anomaly due to the energy separation between the two Kramers' doublets is separated tentatively from the cooperative heat capacity due to the exchange interaction. Based on a careful analysis of the transition entropy it may be concluded that the magnetic structure of the present complex would be a two-dimensional triangular Ising lattice. The exchange and the Curie-Weiss constants are also determined to be 0.155 and 4.19 K, respectively. 相似文献
490.
Michio Kurata 《Journal of Polymer Science.Polymer Physics》1968,6(9):1607-1612
An approximate closed expression for the excluded volume effect of linear polymer molecules is developed with the aid of a uniform expansion model of perturbed chains. The linear expansion factor α for the end-to-end distance is given by (α3 ? 1) + (3/8) (α5 ? α3) = (5/2)z where z is the excluded volume parameter. This equation is numerically close to the Ptitsyn equation in the ordinary range of α; i.e., for 1 ≤ α ≤ 2. 相似文献