Discovery of Hexagonal Structured Pd–B Nanocrystals

We report on hexagonal close-packed (hcp) palladium (Pd)–boron (B) nanocrystals (NCs) by heavy B doping into face-centered cubic (fcc) Pd NCs. Scanning transmission electron microscopy–electron energy loss spectroscopy and synchrotron powder X-ray diffraction measurements demonstrated that the B atoms are homogeneously distributed inside the hcp Pd lattice. The large paramagnetic susceptibility of Pd is significantly suppressed in Pd–B NCs in good agreement with the reduction of density of states at Fermi energy suggested by X-ray absorption near-edge structure and theoretical calculations.     

Microstructures and rheology of micellar surfactant solution by Brownian dynamics simulation

In this paper, three-dimensional Brownian dynamics simulation has been conducted for dilute micellar surfactant solution under a steady shear flow. The rodlike micelle in surfactant solution is assumed as a rigid rod made up of lined-up beads. The Lennard–Jones potential and soft-sphere potential are employed and taken as the inter-bead potentials for end–end beads and interior–interior beads, respectively. The motion of the rodlike micelles is determined by solving the translational and rotational equations for each rod under hydrodynamic drag force, Brownian force and inter-rod potential force. Velocity Verlet algorithm has also been exerted in the simulation. The micellar network structure is formed at low shear rates and destroyed by high shear rates. The computed shear viscosities and the first normal stress coefficient represent shear thinning characteristics. The paper reveals the relation between rheology and microstructure of surfactant solution at different shear rates. The effect of surfactant solution concentration rested on the micellar structures and rheological properties has also been investigated.     

Simultaneous measurements of velocity and temperature fluctuations in thermal boundary layer in a drag-reducing surfactant solution flow

The mechanism of turbulent heat transfer in the thermal boundary layer developing in the channel flow of a drag-reducing surfactant solution was studied experimentally. A two-component laser Doppler velocimetry and a fine-wire thermocouple probe were used to measure the velocity and temperature fluctuations simultaneously. Two layers of thermal field were found: a high heat resistance layer with a high temperature gradient, and a layer with a small or even zero temperature gradient. The peak value of was larger for the flow with the drag-reducing additives than for the Newtonian flow, and the peak location was away from the wall. The profile of was depressed in a similar manner to the depression of the profile of in the flow of the surfactant solution, i.e., decorrelation between v and compared with decorrelation between u and v. The depression of the Reynolds shear stress resulted in drag reduction; similarly, it was conjectured that the heat transfer reduction is due to the decrease in the turbulent heat flux in the wall-normal direction for a flow with drag-reducing surfactant additives.List of symbols ensemble averaged value - (·)⁺ normalized by the inner wall variables - (·) root-mean-square value - C concentration of cetyltrimethyl ammonium chloride (CTAC) solution - c _p heat capacity - D hydraulic diameter - f friction factor - H channel height - h heat transfer coefficient - j _H Colburn factor - l length - Nu Nusselt number, h - Pr Prandtl number, c _p/ - q _w wall heated flux - Re Reynolds number, U _b/ - T temperature - T _b bulk temperature - T _i inlet temperature - T _w wall temperature - T friction temperature, q _w /c _p u - U local time-mean streamwise velocity - U ₁ velocity signals from BSA1 - U ₂ velocity signals from BSA2 - U _b bulk velocity - u streamwise velocity fluctuation - u1 velocity in abscissa direction in transformed coordinates - u friction velocity, - v wall-normal velocity fluctuation - v1 velocity in ordinate direction in transformed coordinates - var(·) variance - x streamwise direction - y wall-normal direction - z spanwise direction - _j junction diameter of fine-wire TC - _w wire diameter of fine-wire TC - angle of principal axis of joint probability function p(u,v) - _f heat conduction of fluid - _w heat conduction of wire of fine-wire TC - kinematic viscosity - local time-mean temperature difference, T _w –T - temperature fluctuation - standard deviation - density - _w wall shear stress     

Synthesis of oxosumanenes through benzylic oxidation

Oxosumanenes were synthesized through benzylic oxidation. The electronic and redox properties were revealed to exhibit the expanded π-conjugation compared to sumanene. Single-crystal X-ray analysis of monooxosumanene showed columnar π-stacking in a concave-convex fashion. Stereoselective trimethylation of the trioxo derivative was performed via 1,2-addition to the carbonyl groups.     

Ein metrischer Raum,der eine Verallgemeinerung des Finslerschen Raumes ist

Ohne Zusammenfassung     

Lamellar structural changes in miscible crystalline polymer blends during melting and crystallization processes,as studied by real‐time small‐angle X‐ray scattering measurements

Real‐time small‐angle X‐ray scattering (SAXS) measurement using synchrotron radiation was applied to study the lamellar structural changes in miscible crystalline polymer blends of poly(1,4‐butylene succinate) (PBSU) and poly(vinylidene fluoride) (PVDF) during melting and crystallization processes. The lamella of PBSU is either included in the interlamellar region of PVDF (interlamellar inclusion structure), or rejected from the interlamellar region of PVDF (interlamellar exclusion structure). The two lamellar structures coexists in the melt‐quenched samples of the PBSU/PVDF = 30/70 blend. Only the interlamellar exclusion structure exists in the drawn films of the PBSU/PVDF = 30/70 blend. The real‐time SAXS results show that the interlamellar exclusion structure in these samples is irreversibly transformed into the interlamellar inclusion structure by heating the sample above the melting temperature of PBSU and that the PBSU chains are crystallized between the lamellae of PVDF during the cooling process. The factors controlling the lamellar structural changes are possibly a balance of the miscibility and the chain exclusion by tie‐molecules and/or the chain diffusion under confinement by the lamellae of PVDF with higher melting temperature. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1959–1969, 2007     

Ellipsometric study of the adsorption of comb-branched polystyrene onto a metal surface

The adsorption of well-characterized comb-branched polystyrene onto a chrome plate from cyclohexane solution at the θ temperature has been studied by ellipsometry. Both the adsorbance of the polymer and the extension of the adsorbed layer are compared with values for the linear polystyrene of the same molecular mass. The adsorbance is higher than that of the linear polystyrene, whereas the extension of the adsorbed layer is smaller, reflecting the higher segment density of the branched polymer. The extension t_b of the branched polymer is given approximately t_b = t_lg, where t_l is the extension of linear polystyrene of the same molecular mass and g is the ratio of the radii of gyration of the branched and linear polymers. The ratio of the adsorbances A_b/A_l of branched and linear polymer is approximately equal to g. These results indicate that the comb-branched polymer is adsorbed as a slightly distorted randam coil with extension and adsorbance governed primarily by the experimental g_s factor.