全文获取类型
收费全文 | 443篇 |
免费 | 19篇 |
国内免费 | 4篇 |
专业分类
化学 | 326篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 87篇 |
物理学 | 49篇 |
出版年
2023年 | 6篇 |
2022年 | 18篇 |
2021年 | 21篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 6篇 |
2017年 | 6篇 |
2016年 | 26篇 |
2015年 | 21篇 |
2014年 | 10篇 |
2013年 | 31篇 |
2012年 | 36篇 |
2011年 | 37篇 |
2010年 | 25篇 |
2009年 | 20篇 |
2008年 | 27篇 |
2007年 | 23篇 |
2006年 | 21篇 |
2005年 | 31篇 |
2004年 | 25篇 |
2003年 | 24篇 |
2002年 | 18篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有466条查询结果,搜索用时 0 毫秒
21.
Mordini A Sbaragli L Valacchi M Russo F Reginato G 《Chemical communications (Cambridge, England)》2002,(7):778-779
Aziridinyl ethers are selectively and easily converted to either amino vinyl ethers or alkoxy allylamines by treatment with mixed metal bases (superbases). 相似文献
22.
23.
Guido Gentile Vieri Mastropietro Michela Procesi 《Communications in Mathematical Physics》2005,256(2):437-490
We consider the nonlinear string equation with Dirichlet boundary conditions utt–uxx=(u), with (u)=u3+O(u5) odd and analytic, 0, and we construct small amplitude periodic solutions with frequency for a large Lebesgue measure set of close to 1. This extends previous results where only a zero-measure set of frequencies could be treated (the ones for which no small divisors appear). The proof is based on combining the Lyapunov-Schmidt decomposition, which leads to two separate sets of equations dealing with the resonant and non-resonant Fourier components, respectively the Q and the P equations, with resummation techniques of divergent powers series, allowing us to control the small divisors problem. The main difficulty with respect to the nonlinear wave equations utt–uxx+Mu=(u), M0, is that not only the P equation but also the Q equation is infinite-dimensional. 相似文献
24.
Antonello?Vicenzo Michela?Rea Luca?Vonella Massimiliano?Bestetti Pietro?Luigi?CavallottiEmail author 《Journal of Solid State Electrochemistry》2004,8(3):159-166
In the present work the electrochemical deposition of Au-Sn alloys is addressed and a cyanide-free process is presented. The electrolyte is an acidic thiourea solution containing gold as a Au[CS(NH2)2]+ complex and tin as stannous ions. Results concerning the plating process development and deposit characterization are reported. Au-Sn alloy films with a Sn content up to 50 at% and a single-phase structure can be obtained from the acidic thiourea–Au(I) solution under pulsed current plating conditions. Alloy deposits show three main crystal structures: a face centred cubic (fcc) Au(Sn) solid solution, extending up to 7 at% Sn; a hexagonal close-packed structure, of the same type as the metallurgical phase, up to about 18 at% Sn; and a NiAs-type structure, corresponding to the phase of the equilibrium diagram, with an enlarged homogeneity range. Mechanical properties of thin layers of Au-Sn alloys derived from micro-indentation measurements follow the structural modification with the alloy composition. The ordered intermetallic phases occurring in the equilibrium binary system, in particular the and phases at 8 at% and 16 at% Sn, respectively, are not detected in the electrodeposited alloys. The main factors controlling electrochemical phase formation are pointed out, considering the differences between the phase structure of the electrodeposited alloys and the equilibrium phase diagram.Presented at the 3rd International Symposium on Electrochemical Processing of Tailored Materials held at the 53rd Annual Meeting of the International Society of Electrochemistry, 15–20 September 2002, Düsseldorf, Germany 相似文献
25.
Cover Picture: Robust Chemical Preservation of Digital Information on DNA in Silica with Error‐Correcting Codes (Angew. Chem. Int. Ed. 8/2015) 下载免费PDF全文
26.
Michela Eleuteri 《Journal of Mathematical Analysis and Applications》2008,344(2):1120-1142
We prove regularity results for minimizers of functionals in the class , where is a fixed function and f is quasiconvex and fulfills a growth condition of the type
L−1|z|p(x)?f(x,ξ,z)?L(1+|z|p(x)), 相似文献
27.
Mangani G Canestrari F Berloni A Maione M Pagliarani S Mangani F 《Annali di chimica》2004,94(9-10):715-719
Phenyl acetic acid, a metabolite of 2-phenyl ethylamine, acts as a neuromodulator in the nigrostriatal dopaminergic pathway stimulating the release of dopamine. The evaluation of phenyl acetic acid concentration in the biological fluid reflects phenyl ethylamine levels thus allowing the assessment of the modulatory role of this endogenous substance. Changes in biological fluids levels of 2-phenylethylamine and/or in its metabolite have been reported in affective disorders, such as depression and schizophrenia. Recently, the occurrence of the "attention deficit hyperactivity syndrome" has been frequently reported in childhood population and involvement of dopaminergic dysfunction in this disease has been suspected. A fast, reliable and reproducible method for the determination of phenyl acetic acid in human blood, is therefore needed in order to have a screening tool for monitoring both healthy childhood population and suspected "attention deficit hyperactivity syndrome" patients. The gas chromatographic-mass spectrometric method here described makes use of a deuterated internal standard in order to overcome problems related to the lack of reproducibility often encountered when a derivatization step is performed. 相似文献
28.
Allevi M Bonizzoni M Fabbrizzi L 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(13):3787-3795
The tripodal system 4, in which urea fragments are appended to the three terminal amine nitrogen atoms of a tris(2-aminoethyl)amine (tren) subunit, includes a Cu(II) ion and two anions X-, according to a cascade mechanism through three well defined stepwise equilibria in a DMSO solution. The first anion X- (halide, N3-, NCS-, NO2-, H2PO4-) seeks the Cu(II) centre coordinated by the tren moiety; the second anion X- interacts with the trisurea cavity, but this occurs only if the stronger H-bond acceptors, such as N3- and H2PO4-, are used. Binding of the second X- ion is favoured by the preorganising effect exerted by the metal and disfavoured by the steric and electrostatic repulsions between the anions. Under the appropriate conditions, heterodinuclear complexes of formula [Cu(II)(4)(Cl)(H2PO4)] can be obtained in solution, in which Cl- is bound to the metal centre and H2PO4- interacts with the trisurea compartment. 相似文献
29.
A new method has been devised to allow the determination of small inorganic anions using isotachophoresis. This method makes use of indium(III) as a counter ion to manipulate the effective mobilities of inorganic anion species by means of complexation reactions. This new procedure successfully allowed the simultaneous determination of nitrate, chloride and sulphate to be realised on a capillary scale instrument and in a chip-based separation device. The electrolyte system developed to allow the separation to be achieved employed a 10mM bromide-based leading electrolyte containing 1.25 mM indium(III) at pH 3.15 and a terminating electrolyte of cyanoacetic acid. 相似文献
30.
Favero LB Giuliano BM Melandri S Maris A Ottaviani P Velino B Caminati W 《The journal of physical chemistry. A》2005,109(33):7402-7404
The molecular beam Fourier transform microwave spectrum of 1,4-dioxane-trifluoromethane has been assigned and measured. The two subunits form a cage stabilized by one C-H...O and two C-H...F weak hydrogen bonds. The C-H...O link involves the axial lone pair of one of the two equivalent ring oxygens, while the two C-H...F bridges connect trifluoromethane to the two axial hydrogens in positions 3 and 5. The dissociation energy has been estimated from the D(J) centrifugal distortion parameter to be approximately 6.8 kJ/mol. 相似文献