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81.
We show, by computer simulation, that tapered or pear-shaped particles, interacting through purely repulsive interactions, can freely self-assemble to form the three-dimensionally periodic, gyroid cubic phase. The Ia3d gyroid cubic phase is formed by these particles on both compression of an isotropic configuration and expansion of a smectic A bilayer arrangement. For the latter case, it is possible to identify the steps by which the topological transformation from nonintersecting planes to fully interpenetrating, periodic networks takes place. 相似文献
82.
Dr. Michel Holler Dr. Béatrice Delavaux-Nicot Dr. Jean-François Nierengarten 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(18):4543-4550
Heteroleptic copper(I) complexes combining phenanthroline derivatives (NN) and chelating bisphosphine ligands (PP) are an important class of luminescent materials for various applications. Although thermodynamically stable, [Cu(NN)(PP)]+ derivatives are also kinetically unstable. As a result, a dynamic ligand-exchange reaction is often observed in solution, leading to a dynamic mixture of heteroleptic and homoleptic complexes. To prevent the formation of the homoleptic species, macrocyclic phenanthroline ligands have been used for the preparation of [Cu(NN)(PP)]+ pseudorotaxanes. The topological constraint resulting from the macrocyclic structure of the NN ligand drives the thermodynamic equilibrium towards the exclusive formation of the heteroleptic complex as long as the macrocycle is large and flexible enough to allow for the threading of the PP ligand. Conversely, when the threading is prevented by steric constraints, unprecedented copper(I) complexes with a trigonal coordination geometry are obtained. These results are summarized in the present concept article. 相似文献
83.
Matveev Vladimir B. Semenov-Tian-Shansky Michel 《Letters in Mathematical Physics》2019,109(6):1269-1270
Letters in Mathematical Physics - 相似文献
84.
85.
Auger electron spectroscopy (AES), low energy electron diffraction (LEED) and work function (Kelvin probe) measurements have been used to study the initial interaction of clean Al(111), (100) and (110) surfaces with oxygen at room temperature. The oxidation process was found to be surface orientation dependent, but a common feature has been always observed on the three low-index surfaces: they show two distinct phases, i.e. a chemisorbed phase followed then by an oxidized phase. From analysis of AES, LEED and Kelvin probe results, an adsorption mechanism of O on Al for each surface orientation is proposed. 相似文献
86.
Density waves analogous to second sound are studied in a gas of magnons. Quasiparticle interaction is considered for both equilibrium and non equilibrium thermodynamics. The non equilibrium theory is based on a Boltzmann equation for magnon-magnon scattering. Contrary to the total energy and magnetization, (quasi)-momentum is not strictly conserved. In the hydrodynamic regime, the transport equation is reduced to a set of two coupled equations for the magnetization and the local temperature. For low temperatures these have diffusive and propagating solutions while for high temperatures, where momentum is dissipated by Umklapp processes, the solutions are only diffusive. The magnetization response function and the corresponding spectral function are discussed for various wavenumbers and temperatures. 相似文献
87.
Alain Tressaud Jean Louis Soubeyroux Jean Michel Dance René Sabatier Paul Hagenmuller Barbara M. Wanklyn 《Solid State Communications》1981,37(6):479-484
The nature of the magnetic interactions in the chain compound Rb2FeF5 has been investigated using neutron diffraction and magnetic measurements under high applied fields. Rb2FeF5 orders antiferromagnetically at TN = 8.0 ± 0.5 K; the magnetic structure is of the AZ + GX mode and the moment of the Fe3+ ion extrapoled to 0K is 3.5 ± 0.2 μB, this low value being due to zero-point spin reduction. Within a chain the Fe3+ ions are antiferromagnetically coupled with an exchange constant of J/k = ?8.8 K. A spin-flop behavior has been observed and interpreted on the basis of the molecular field theory. The critical field was found to be HC = 65 kOe at 1.7 K. 相似文献
88.
We prove a general subconvex bound in the level aspect for Rankin–Selberg L-functions associated with two primitive holomorphic or Maass cusp forms over Q. We use this bound to establish the equidistribution of incomplete Galois orbits of Heegner points on Shimura curves associated
with indefinite quaternion algebras over Q.
Mathematics Subject Classification (2000) 11F66, 11F67, 11M41 相似文献
89.
In Geoffroy et al, Acceleration of convergence in Dontchev's iterative method for solving variational inclusions Serdica Math. J. 29 (2003), pp. 45–54] we showed the convergence of a cubic method for solving generalized equations of the form 0 ∈ f(x) +- G(x) where f is a function and G stands for a set-valued map. We investigate here the stability of such a method with respect to some perturbations. More precisely, we consider the perturbed equation y ∈ f(x) +- G(x) and we show that the pseudo-Lipschitzness of the map (f +- G)−1 is closely tied to the uniformity of our method in the sense that the attraction region does not depend on small perturbations of the parameter y. Finally, we provide an enhanced version of the convergence theorem established by Geoffroy, et al. 相似文献
90.
We show that if the number of directions not determined by a pointset
of
, of size q2 is at least pe q then every plane intersects
in 0 modulo pe+1 points and apply the result to ovoids of the generalised quadrangles
and
. 相似文献