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71.
Lechosław Łomozik Anna Wojciechowska 《Monatshefte für Chemie / Chemical Monthly》1985,116(6-7):719-727
The influence of the solvent and the substituents on the complexing properties of methyl and phenyl glycine derivatives is discussed. On the basis of a computer analysis of potentiometric titration results, the composition and the stability constants of the complexes ofN-methylglycine,N,N-dimethylglycine,N-phenylglycine and phenylglycine with H+ and with Ni(II), Cu(II), Zn(II) were determined. The ligand-metal coordination mode as well as the zwitterion level in percent in ligand/proton systems were determined by spectral analyses and equilibria studies.
Komplexbildung der Methyl- und Phenylglycin-Derivate in ihren Verbindungen mit dem Proton und Ni(II), Cu(II) und Zn(II)
Zusammenfassung Der Einfluß des Lösungsmittels und der Substituenten auf die komplexbildenden Eigenschaften der Methyl- und Phenylglycin-Derivate wird diskutiert. Anhand einer Computer-Analyse von potentiometrischen Daten wurden die Zusammensetzung und die Beständigkeitskonstanten der Komplexe vonN-Methylglycin,N,N-Dimethylglycin,N-Phenylglycin und Phenylglycin mit H+, Ni(II), Cu(II) und Zn(II) festgestellt. Mittels spektroskopischer Methoden und Gleichgewichtstudien wurde der Koordinationstyp des Liganden mit dem Metall festgestellt sowie der Prozentanteil des Zwitterions im Ligand/Proton-System.相似文献
72.
73.
Tadeusz Bałaban 《Communications in Mathematical Physics》1987,109(2):249-301
We study four-dimensional pure gauge field theories by the renormalization group approach. The analysis is restricted to small field approximation. In this region we construct a sequence of localized effective actions by cluster expansions in one step renormalization transformations. We construct also -functions and we define a coupling constant renormalization by a recursive system of renormalization group equations. 相似文献
74.
The Monte-Carlo model of a light-emitting diode 总被引:1,自引:0,他引:1
The first complete Monte-Carlo model of a surface light-emitting diode is presented in this paper. In the model all important phenomena (including the two-dimensional diffusion of minority carriers before their recombination in the active region and the re-emission of radiation) are taken into account. The influence of various construction parameters on the external quantum efficiency of the homojunction GaAs diode is examined. 相似文献
75.
76.
Summary
A simple two-velocity model (-model)of the Boltzmann-Enskog equation for a gas of hard spheres is proposed. Physical properties of such a model are analyzed and its differences with respect to the Carleman model are investigated. Global existence theorems and some qualitative properties of solutions of the -model are also proved.On leave from Dept. of Mathematics and Mechanics, University of Warsaw, Poland. 相似文献
77.
The thermal decomposition of cadmium acetate dihydrate in helium and in air atmosphere has been investigated by means of a
coupled TG-DTA-MS method combined with X-ray diffraction analysis. Dehydration of Cd(CH3COO)2·2H2O is a two-stage process with Cd(CH3COO)2·H2O as intermediate. The way of Cd(CH3COO)2 decomposition strongly depends on the surrounding gas atmosphere and the rate of heating. CdO, acetone and CO2 are the primary products of decomposition in air. In helium decomposition goes by two parallel and consecutive reactions
in which intermediates, Cd and CdCO3, are formed. Metallic cadmium oxidizes and cadmium carbonate decomposes giving CdO. Some of the metallic cadmium, depending
on the heating rate and the concentration of oxygen, evaporates. Acetone is partially oxidized in secondary reactions with
oxygen.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
78.
D. Płusa J. J. Wysłocki B. Wysłocki R. Pfranger 《Applied Physics A: Materials Science & Processing》1986,40(3):167-170
From measurements of the magnetic domain widthsD versus grain thicknessL, we have determined the domain wall energy in the demagnetized state for a sintered Nd15Fe77B8 magnet: = 56 erg/cm2. Using this wall energy and the published magnetocry-stalline constantK
1=4.9×107 erg/cm3, we have calculated the exchange constantA=4.0×10–6 erg/cm, domain wall thickness
B=89 Å, and the critical diameter for single domain particlesD
c=0.67 m. 相似文献
79.
Mangos MM Min KL Viazovkina E Galarneau A Elzagheid MI Parniak MA Damha MJ 《Journal of the American Chemical Society》2003,125(3):654-661
The ability of modified antisense oligonucleotides (AONs) containing acyclic interresidue units to support RNase H-promoted cleavage of complementary RNA is described. Manipulation of the backbone and sugar geometries in these conformationally labile monomers shows great benefits in the enzymatic recognition of the nucleic acid hybrids, while highlighting the importance of local strand conformation on the hydrolytic efficiency of the enzyme more conclusively. Our results demonstrate that the duplexes support remarkably high levels of enzymatic degradation when treated with human RNase HII, making them efficient mimics of the native substrates. Furthermore, interesting linker-dependent modulation of enzymatic activity is observed during in vitro assays, suggesting a potential role for this AON class in an RNase H-dependent pathway of controlling RNA expression. Additionally, the butyl-modified 2'F-ANA AONs described in this work constitute the first examples of a nucleic acid species capable of eliciting high RNase H activity while possessing a highly flexible molecular architecture at predetermined sites along the AON. 相似文献
80.
Z. Rzączyńska A. Ostasz M. Sikorska-Iwan H. Głuchowska E. Olszewska S. Pikus 《Journal of Thermal Analysis and Calorimetry》2006,84(3):575-579
The complexes
of yttrium(III) and lanthanides(III) with 1,2,4,5-benzenetetracarboxylic acid
were prepared as crystalline solids of the general formula Ln4(C10H2O8)3⋅14H2O. They
are insoluble in water. On heating in air or inert gas atmosphere all compounds
lose water molecules; next anhydrous compounds decompose to oxides. The yttrium
complex and heavy lanthanide (from Ho to Lu) ones crystallize in monoclinic
crystal system. The dehydration does not change the crystal structure of the
compounds. 相似文献