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The ZnO catalysts supported on Silicalite‐1 zeolites with different crystallite sizes (0.08, 0.35, 1 and 1.7 μm, respectively) and 5% Zn were synthesized via an incipient wetness method. The catalysts were characterized by XRD, N2 adsorption, SEM, TEM‐EDX, DRIFT spectra and NH3‐TPD, and their catalytic performance in isobutane dehydrogenation assisted by CO2 was investigated. The catalytic activity is strongly dependent on the crystallite size of Silicalite‐1 support. The ZnO/S‐1‐0.35 catalyst with ca. 0.35 μm crystallite size displays the highest activity, affording an initial isobutane conversion of 51.0% and 74.5% isobutene selectivity. This can be attributed to a higher amount of acid sites present on this catalyst as well as the largest amount of nest silanols possessed by the S‐1‐0.35 support. 相似文献
126.
Hongming He Qian‐Qian Zhu Chuanqi Zhang Ying Yan Jing Yuan Jing Chen Cheng‐Peng Li Miao Du 《化学:亚洲杂志》2019,14(7):917-917
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Jørgen Hoffmann-Jørgensen Yu Miao Xiao Chun Li Shou Fang Xu 《Journal of Theoretical Probability》2016,29(1):32-47
In this paper, we establish the analogue of Kolmogorov-type law of the logarithm for an array of independent random variables. The main methods are to develop the classic Bernstein’s and Kolmogorov’s inequality and replace the boundedness condition by conditions on the cumulant transform. 相似文献
128.
Keyu Jiang Qin Fan Tong Chen Changxi Miao Zhenji Zhao Xielong Yang 《Hyperfine Interactions》2012,205(1-3):81-85
Two series of Fe-K catalysts for dehydrogenation of ethylbenzene to styrene were prepared with different amounts and different compounds of the additional element Ce. M?ssbauer spectroscopy has been used to determine the Fe compound in the catalyst and to investigate the effect of Ce. The catalytic properties of the catalysts have also been measured. The results show that the element Ce in the catalyst is favorable to form the predecessor of the catalytic active phase, the compound KFe11O17 and that the optimal percentage of CeO2 is 8%~15% in the catalyst which is favorable to the formation of KFe11O17 and to get better catalytic properties. 相似文献
129.
A new nonporous Zn-based metal-organic framework (NPMOF) synthesized from a high nitrogen-containing rigid ligand was converted into porous carbon materials by direct carbonization without adding additional carbon sources. A series of NPMOF-derived porous carbons with very high N/O contents (24.1% for NPMOF-700, 20.2% for NPMOF-800, 15.1% for NPMOF-900) were prepared by adjusting the pyrolysis temperatures. The NPMOF-800 fabricated electrode exhibits a high capacitance of 220 F/g and extremely large surface area normalized capacitance of 57.7 μF/cm2 compared to other reported MOF-derived porous carbon electrodes, which could be attributed to the abundant ultramicroporosity and high N/O co-doping. More importantly, symmetric supercapacitor assembled with the MOF-derived carbon manifests prominent stability, i.e., 99.1% capacitance retention after 10,000 cycles at 1.0 A/g. This simple preparation of MOF-derived porous carbon materials not only finds an application direction for a variety of porous or even nonporous MOFs, but also opens a way for the production of porous carbon materials for superior energy storage. 相似文献
130.
Chang Ling Zhao Zhong Jian Chen Xue Song Bai Can Ding Ting Ju Long Fu Gang Wei Kang Ru Miao 《Molecular diversity》2014,18(3):687-700
This paper summarizes the main achievements about the structure–activity relationships of anthocyanidin glycosylation. Anthocyanidin glycosylation is the essential step of anthocyanin biosynthesis and also the prerequisite of the further modifications of anthocyanins, which is jointly characterized by the glycosylation site, the type and number of the glycosyl as well as the glycosidic bond type. It generally enhances the stability, results in the hypsochromic effect and blueing, decreases the bioavailability and anticancer activity, and decreases, increases, or does not change the antioxidant activity of the anthocyanidins or anthocyanins, which is synergetically determined by the glycosylation site and the type and number of the glycosyl. Thereinto, in nature, the blue hues caused by the glycosylation may also be reinforced by the formation of the anthocyanic vacuolar inclusions. This review could provide a reference for the research of the structure-optimizing and function-exploiting of anthocyanins. 相似文献