On the mechanism of phenol ozonolysis

The mechanisms of liquid-phase phenol ozonation are revised. A new mechanism in which a significant role is played by free-radical reactions is suggested for this process.     

Differential subordinations concerning starlike functions

Denote byS ^* (⌕), (0≤⌕<1), the family consisting of functionsf(z)=z+a ₂z²+...+a_nzⁿ+... that are analytic and starlike of order ⌕, in the unit disc ⋎z⋎<1. In the present article among other things, with very simple conditions on μ, ⌕ andh(z) we prove the f’(z) (f(z)/z)^μ−1<h(z) implies f∈S^*(⌕). Our results in this direction then admit new applications in the study of univalent functions. In many cases these results considerably extend the earlier works of Miller and Mocanu [6] and others.     

Determination of U,Ra and Th in waters from the Danube Delta area

The methods applied for natural uranium, radium and thorium determinations in water samples are shortly presented together with some preliminary results. The measurements will be continued as part of an extended program of ecological study of the Danube Delta area.     

Investigation of the reaction order for nucleophilic substitution of dialkyl methylphosphonates by alkoxides

The rate of nucleophilic substitution at the phosphorus centre of dialkyl methylphosphonates by methoxide and ethoxide has been studied to investigate the possible involvement of hexacoordinated phosphorus species in this reaction. For alkoxide concentrations less than ca. 1.5 M the rate increases with the square of alkoxide concentration. However, consideration of the activity of the alkoxides, represented by an appropriate acidity function, reveals that only one equivalent of alkoxide is involved in the rate-determining step. Thus, there is no requirement to invoke the intermediacy of a hexacoordinated species in the reaction pathway. © John Wiley & Sons, Inc.     

The inverse problem of the scatter of unguided missiles

The inverse scatter problem determines the characteristics of the perturbations of the initial conditions, design parameters, and the wind velocity from given characteristics of the scatter of the point of impact of an unguided missile. A deterministic and a probabilistic formulation of the problem are considered. Some properties of its solutions are noted and a method of computing them is proposed.     

Scattering of scalar fields by rough surfaces. Accounting for multiple scattered waves

Physical Engineering Institute, Moscow. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 34, No. 5, pp. 565–574, May, 1991.     

The electron current to a Langmuir probe in a flowing high-pressureplasma

The electron current to a Langmuir probe in a moving high-pressure plasma has been measured and analyzed. The plasma is an atmospheric-pressure propane flame, and the probe's speed relative to the plasma was varied from 10 ms^-1 to 30 ms^-1. The current is linearly dependent on the speed and appears to be comprised of two components-one driven by diffusion and the other by convection. A model is devised which can be used to measure the electron density. By comparing the density computed from this model to that measured from the ion current, it has been possible to measure the electron mobility in the flame gases. The value obtained by the authors is in good agreement with theoretical calculations found in the literature     

Electron Energy Distribution Functions in CO2 Laser Mixture: The Effects of Second Kind Collisions from Metastable Electronic States

Electron energy distribution functions (eedf) in CO₂ laser discharge (He—CO₂—N₂—CO mixture) have been calculated by solving the Boltzmann equation in the presence of given concentrations of excited (vibrational and electronic) states. The results show a well structured eedf as a result of second kind collisions coming from metastable electronic states of N₂ and He as well as a strong dependence of rate coefficients for CO₂ dissociation and for the ionization of the different species.