排序方式: 共有58条查询结果,搜索用时 15 毫秒
41.
Cristina Bogatu Dan Geană Rodica Vîlcu Anca Duţă Wim Poot Theo W. de Loos 《Fluid Phase Equilibria》2010
Vapour–liquid, liquid–liquid and liquid–liquid–vapour equilibria in the binary system consisting of trifluoromethane (refrigerant R23) and 1-phenyloctane were determined in the temperature range T = 250–400 K and at pressures up to 15 MPa. The experiments were carried using a Cailletet apparatus according to the synthetic method. The investigated system exhibits type III phase behaviour according to the classification of van Konynenburg and Scott. Modelling of the equilibrium data was done with the Peng–Robinson (PR) and Soave–Redlich–Kwong (SRK) equations of state coupled with classical van der Waals mixing rules. In order to predict the global phase behaviour of the system, one single set of binary parameters was used. The topology of the phase behaviour was correctly reproduced. 相似文献
42.
Anas F. Jarjour Rachel A. Oliver Abbes Tahraoui Menno J. Kappers Robert A. Taylor Colin J. Humphreys 《Superlattices and Microstructures》2008,43(5-6):431
We present a study of the effect of externally applied vertical electric field on the optical properties of single InGaN/GaN quantum dots via microphotoluminescence spectroscopy. This is achieved by incorporating the quantum dot layer in the intrinsic region of a p–i–n diode structure. We observe a large blue energy shift of 60 meV, which is explained by the partial compensation of the internal piezoelectric field. The energy shift dependence on the applied field allows the determination of the vertical component of the permanent dipole and the polarizability. We also present theoretical modelling of our results based on atomistic semi-empirical tight-binding simulations. A good quantitative agreement between the experiment and the theory is found. 相似文献
43.
Black Carbon (BC) quantification methods are reviewed, including new Rock-Eval 6 data on BC reference materials. BC has been reported to have major impacts on climate, human health and environmental quality. Especially for risk assessment of persistent organic pollutants (POPs) it is important to account for risk reduction caused by BC, as suggested for POP safety assessment in the framework of the new European Community Regulation on Registration, Evaluation, Authorization and Restriction of Chemicals (REACH). Four major classes of BC quantification methods are reviewed including application to BC reference materials. Methods include chemical oxidation, thermal oxidation, molecular marker, optical methods and Rock-Eval analyses. Residual carbon from Rock-Eval 6 analysis correlated well with BC data from 'gentle' methods like optical and molecular marker methods, which capture a major part of the BC continuum including labile fractions (e.g. char). In contrast, the temperature at which 50% of the organic matter was oxidized (T(50%)) in an oxidation-only Rock-Eval analysis, correlated well with data from chemothermal oxidation (CTO), which captures only refractory BC fractions (e.g. soot). Rock-Eval analysis can further be used for BC characterization through deconvolution of the dominant peaks of the thermogram and appears to be a powerful tool in BC analysis. 相似文献
44.
Kristenson EM Korytár P Danielsson C Kallio M Brandt M Mäkelä J Vreuls RJ Beens J Brinkman UA 《Journal of chromatography. A》2003,1019(1-2):65-77
Different cryogenic and a heated GC x GC modulator(s) were evaluated and compared for the analysis of high-boiling halogenated compounds. The cryogenic modulators investigated were: (i) the longitudinally modulated cryogenic system; (ii) the liquid-nitrogen-cooled jet modulator (KT2001); (iii) a dual-jet CO2 modulator (made in-house); (iv) a semi-rotating cryogenic modulator (made in-house) and (v) a CO2 loop modulator (KT2003); the heated modulator was the slotted heater system (sweeper). Each modulator was optimised with respect to analyte peak widths at half height in the second-dimension. n-Alkanes, chlorinated alkanes, polychlorinated biphenyls (PCBs) and fluorinated polycyclic aromatic hydrocarbons (F-PAHs) were used as test analytes. The flow rate of the coolant was found to be an important parameter, i.e. the flow rate of the gaseous nitrogen in the KT2001, and of the liquid CO2 in the other cryogenic modulators. For the slotted heater the stroke velocity and pause time were important parameters. This modulator had a limited application range in terms of temperature due to a necessary 100 degrees C difference between sweeper and oven temperature. All cryogenic modulators were found to be suitable for the GC x GC analysis of high-boiling compounds, but the CO2 modulators are to be preferred to the KT2001 due to a wider application range and slightly narrower peaks. As regards the performance of three commercially available electron-capture detectors (ECDs), the aim was to obtain narrow peak widths in GC x GC, i.e. to avoid band broadening caused by the cell volume. The most important parameters were the flow rate of the make-up gas and the detector temperature which both should be as high as possible. Comparison of analyte peak widths obtained with ECD mode and flame ionisation detection (FID) showed that all ECDs exhibited band broadening compared to the FID. The narrowest peaks were obtained with the Agilent micro-ECD, which has a cell volume of only 150 microl. 相似文献
45.
Deij MA ter Horst JH Meekes H Jansens P Vlieg E 《The journal of physical chemistry. B》2007,111(7):1523-1530
Knowledge of the nucleation and growth behavior of polymorphs is vital in a variety of industrial applications. With the aid of the growth probability method the nucleus size is obtained as a function of the driving force for crystallization by simulating the growth probability of clusters of various sizes. From these values the cluster interfacial energy can be computed, allowing for the determination of the nucleation rate. The simulations show that nucleation of the metastable form of a yellow isoxazolone dye dominates at higher driving forces while below a certain driving force the stable form nucleates. Two other compounds show dominant nucleation of their stable form, even at extreme driving forces. This is in accordance with experimental findings for all these compounds. The growth probability method is therefore a promising indicator for polymorph nucleation behavior. 相似文献
46.
Menno Genseberger Gerard L. G. Sleijpen 《Numerical Linear Algebra with Applications》1999,6(3):235-253
The correction equation in the Jacobi‐Davidson method is effective in a subspace orthogonal to the current eigenvector approximation, whereas for the continuation of the process only vectors orthogonal to the search subspace are of importance. Such a vector is obtained by orthogonalizing the (approximate) solution of the correction equation against the search subspace. As an alternative, a variant of the correction equation can be formulated that is restricted to the subspace orthogonal to the current search subspace. In this paper, we discuss the effectiveness of this variant. Our investigation is also motivated by the fact that the restricted correction equation can be used for avoiding stagnation in the case of defective eigenvalues. Moreover, this equation plays a key role in the inexact TRQ method [18]. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
47.
48.
Cornelis Lensink Graeme J. Gainsford Menno J. R. Brandsma 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(11):m529-m530
The title compound, [Ti(C15H17NO2S)Cl2], has a Ti atom bound to the N and O atoms of a p‐toluenesulfonamide ligand, which is tethered by a three‐carbon chain to a η5‐cyclopentadienyl group. The distorted square‐pyramidal geometry is completed by two Cl atoms. The Ti—N bond length of 2.0375 (13) Å is longer than that in related compounds, the N atom having asymmetric trigonal–planar geometry. Conformational strain relief is noted when compared with ethyl‐tethered compounds. 相似文献
49.
We report on the synthesis of ZnO and TiO2 nanoparticles by solution-phase methods, with a particular focus on the influence of experimental parameters on the kinetics
of nucleation and coarsening. The nucleation rate of ZnO from the reaction between ZnCl2 and NaOH in ethanol was found to increase with increasing precursor concentration, while the coarsening rate is independent
of precursor concentration up to a threshold concentration. The nucleation rate of ZnO from Zn(OOC-CH3)2 and NaOH in n-alkanols was found to decrease with decreasing chain length, which is explained by the increase of the dielectric
constant of the solvent. Due to the larger solubility of ZnO, nucleation is significantly slower than that observed in the
case of TiO2. TiO2 nanoparticles coarsen according to the Lifshitz-Slyozov-Wagner model for Ostwald ripening. We also show that using amorphous
titania as a base material, pure anatase and brookite nanoparticles can be synthesized. 相似文献
50.