(Zn、Cd)S:Cu、Br黄色交流电致发光材料的晶体结构和发光特性

本文首次提出一种制备黄色交流粉末电致发光材料的新方法.在以ZnS为基质的绿色材料的基础上,低温扩散CdS,获得系列黄材料.并测量了晶体结构和发光特性.     

Calculations on the hyperfine constants of the ground states for lithium-like system

In this paper a relativistic many-body perturbation calculation is performed to calculate the hyperfine constants of the ground states for lithium-like isoelectronic sequence. Zeroth-order hyperfine constants are calculated with Dirac--Fock wavefunctions, and the finite basis sets of the Dirac--Fock equations are constructed by B splines. With the finite basis sets, the core polarization and the correlation effect are evaluated.     

铽－甲基吲哚乙酰丙酮三元配合物发光过程研究

测定和分析了ＲＥ．Ｌ１．Ｌ２（ＲＥ＝Ｔｂ（Ⅲ）、Ｇｄ（Ⅲ），Ｌ１＝３Ｍ（３甲基吲哚－１－乙酰基丙酮），Ｌ２＝ＴＰＰＯ、Ｐｈｅｎ、Ｄｉｐｙ）三元配合物的荧光光谱、磷光光谱、磷光寿命及变温荧光光谱等．讨论了Ｔｂ（Ⅲ）与配体之间的能级匹配和Ｌ１与Ｌ２的三重态之间传能的问题，说明了影响这些三元配合物荧光效率的主要因素及其发光过程．     

Photoemission of LaI2 and CeI2

The electronic structure of the layered compounds LaI₂ and CeI₂ was investigated by photoemission and electron energy loss spectroscopy. From the experimental results we are able to confirm the metallic nature of these compounds, and by using photon energy dependent measurements of the valence band we can identify the orbital character of the conduction band as essentially 5d¹-like. A detailed analysis of the Ce 3d and 4f spectra yields a remarkably small 4f-5d hybridization strength, almost completely decoupling the f-electron from the conduction band, which makes CeI₂ a somewhat unusual system compared to other metallic Ce compounds. Band structure calculations by Jepsen and Andersen [1] confirm these experimental results.     

Analysis of Coupling and Radiation Properties for an Improved Dielectric Waveguide Directional Coupler Utilizing a Tapering Left-Handed Slab Core

The coupling and radiation characteristics of an improved dielectric waveguide directional coupler with a tapering left-handed slab core located in the coupling region are analyzed by the staircase approximation method, which combines the building block approach and multi-mode network theory with a rigorous mode-matching procedure. Particular attentions are directed toward the radiation characteristics under different structural parameters of the coupler. Numerical results indicate that the proposed coupler is very promising by shortening the coupling length significantly while keeping the radiation loss at a low level.     

A facile method for the synthesis of large‐size Ag nanoparticles as efficient SERS substrates

Silver nanoparticles (Ag NPs) enjoy a reputation as an ultrasensitive substrate for surface‐enhanced Raman spectroscopy (SERS). However, large‐scale synthesis of Ag NPs in a controlled manner is a challenging task for a long period of time. Here, we reported a simple seed‐mediated method to synthesize Ag NPs with controllable sizes from 50 to 300 nm, which were characterized by scanning electron microscopy (SEM) and UV–Vis spectroscopy. SERS spectra of Rhodamine 6G (R6G) from the as‐prepared Ag NPs substrates indicate that the enhancement capability of Ag NPs varies with different excitation wavelengths. The Ag NPs with average sizes of ~150, ~175, and ~225 nm show the highest SERS activities for 532, 633, and 785‐nm excitation, respectively. Significantly, 150‐nm Ag NPs exhibit an enhancement factor exceeding 10⁸ for pyridine (Py) molecules in electrochemical SERS (EC‐SERS) measurements. Furthermore, finite‐difference time‐domain (FDTD) calculation is employed to explain the size‐dependent SERS activity. Finally, the potential of the as‐prepared SERS substrates is demonstrated with the detection of malachite green. Copyright © 2016 John Wiley & Sons, Ltd.     

RIBLL终端LASCAR闪烁体阵列探测器研制进展

介绍了RIBLL终端LASCAR闪烁体阵列探测器的工作原理和结构特点. 描述了为满足放射性核束实验的要求而对阵列所作的重要改进. 给出了LASCAR构型优化改造的工作设想和实施步骤. The principles and structure characteristics of LASCAR scintillator array detector at RIBLL terminal are described. Special emphases are laid upon the latest progress for the development of LASCAR array detector to meet the requirements of the RIB experiments. The working plan and steps for optimizing configuration of the LASCAR multi unit neutron scintillator array detector are also presented.     

Photocatalytic degradation of methyl orange by nano-TiO_2 thin films prepared by RF magnetron sputtering

Nano-TiO2 thin films are deposited by radio frequency （RF） magnetron sputtering using TiO2 ceramic target and characterized by X-ray diffractometer, atomic force microscope, and ultraviolet-visible spectrophotometer. The photocatalytic activity is evaluated by light-induced degradation of methyl orange solutions （5, 10, and 20 ppm） using a high pressure mercury lamp as the light source. The film is amorphous, and its energy gap is 3.02 eV. The photocatalytic degradation of methyl orange solution is the first-order reaction and the apparent reaction rate constants are 0.00369, 0.0024, and 0.00151 for the methyl orange solution concentrations of 5, 10, and 20 ppm, respectively.     

Facile Construction of 3D Reduced Graphene Oxide Wrapped Ni3S2 Nanoparticles on Ni Foam for High‐Performance Asymmetric Supercapacitor Electrodes

3D reduced graphene oxide (rGO)‐wrapped Ni₃S₂ nanoparticles on Ni foam with porous structure is successfully synthesized via a facile one‐step solvothermal method. This unique structure and the positive synergistic effect between Ni₃S₂ nanoparticles and graphene can greatly improve the electrochemical performance of the NF@rGO/Ni₃S₂ composite. Detailed electrochemical measurements show that the NF@rGO/Ni₃S₂ composite exhibits excellent supercapacitor performance with a high specific capacitance of 4048 mF cm^?2 (816.8 F g^?1) at a current density of 5 mA cm^?2 (0.98 A g^?1), as well as long cycling ability (93.8% capacitance retention after 6000 cycles at a current density of 25 mA cm^?2). A novel aqueous asymmetric supercapacitor is designed using the NF@rGO/Ni₃S₂ composite as positive electrode and nitrogen‐doped graphene as negative electrode. The assembled device displays an energy density of 32.6 W h kg^?1 at a power density of 399.8 W kg^?1, and maintains 16.7 W h kg^?1 at 8000.2 W kg^?1. This outstanding performance promotes the as‐prepared NF@rGO/Ni₃S₂ composite to be ideal electrode materials for supercapacitors.