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61.
62.
Michael Grätzel 《Journal of Sol-Gel Science and Technology》1994,2(1-3):673-677
Transparent nanocrystalline films of oxide semiconductors such as TiO2 and Fe2O3 have been prepared on a conducting glass support employing a sol-gel procedure. The films are composed of nanometer-sized particles sintered together to allow for percolative charge carrier transport. The internal surface of these films is very high, roughness factors of the order of 1000 being readily obtained. Electric polarization was applied for forward and reverse biasing of the films and the resulting optical changes have been analyzed to derive their flat band potential. Band gap excitation of such nanocrystalline semiconductors produces electron-hole pairs which migrate through the film to be collected as electric current. Steady state photolysis and time resolved laser techniques have been applied to scrutinize the mechanism of light induced charge separation within the nanostructure. When derivatized with a suitable chromophore, TiO2 films give extraordinary efficiencies for the conversion of incident photons into electric current, exceeding 90% for certain transition metal complexes within the wavelength range of their absorption band. The underlying physical principles of these astonishing findings will be discussed. Exploiting this discovery, we have developed a new type of photovoltaic device whose overall light to electric energy conversion yield is 10% under simulated AM 1.5 solar radiation. 相似文献
63.
Nitro musks in cosmetic products—determination by headspace solid-phase microextraction and gas chromatography with atomic-emission detection 总被引:1,自引:0,他引:1
Summary The combination of headspace solid-phase microextraction with atomic-emission detection enables highly selective and sensitive
determination of itro musk compounds in cosmetic products. Sample preparation is considerably simplified; there is no solvent
extraction step. Enrichment is influenced by the type and amount of cosmetic product investigated. The lowest amount giving
well detectable peaks is 1 mg musk compound per kg sample. Calibration curves obtained from spiked solutions of selected reference
cosmetics in water show very good linearity. Relative standard deviations of peak areas from repeated measurements are usually
<10%.
Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996 相似文献
64.
Erkki Mäkinen 《BIT Numerical Mathematics》1987,27(3):330-339
The splay tree is a self-adjusting binary search tree which has a good amortized performance. This paper studies some properties of top-down splay trees. Different ways to charge for the primitive operations of top-down splaying are discussed. We also give some empirical results concerning the behaviour of different top-down restructuring algorithms.This work was supported by the Academy of Finland. 相似文献
65.
P. Schwab A. Kochemasov R. Kullmer D. Bäuerle 《Applied Physics A: Materials Science & Processing》1992,54(2):166-169
Pulsed-laser deposition of YBa2Cu3O7 in N2O permits lowering of the substrate temperature with respect to deposition in O2 atmosphere. Additional photodissociation of N2O near the substrate surface deteriorates the superconducting properties of deposited films.On leave from: Institute of Applied Physics of the Academy of Sciences of the USSR, SU-603600 Nishni Nowgorod, USSR 相似文献
66.
E. Possenriede P. Jacobs H. Kröse O. F. Schirmer 《Applied Physics A: Materials Science & Processing》1992,55(1):73-81
On the basis of a previous identification of paramagnetic defects in nominally undoped as grown BaTiO3 single crystals, we have investigated the changes of the concentrations of these centers and their optical absorptions under illumination with light of varying wavelengths. The most pronounced charge transfers occur by hole ionization of Fe4+ and — to a lesser extent — of Cr5+ and Cr4+. At low temperatures the created holes are trapped in the form of O–-ions next to Al3+ or unknown acceptor defects. Corresponding Fe4+ and O– absorptions have been identified. 相似文献
67.
In this paper we present photoionization cross sections of the Cu and Al dimers and tetramers. The local spin density method is applied to calculate the electronic structure and the ground state potential. The cross sections are calculated using the continuum multiple scattering method, and a basic analysis of the photoionization process is given within the independent particle picture. 相似文献
68.
Christian R. Noe M. Knollmüller K. Dungler C. Miculka P. Gärtner 《Monatshefte für Chemie / Chemical Monthly》1991,122(8-9):705-718
Summary Acetals3 and4 of alkylthienylcarbinols1 were prepared using an enantiomerically pure lactol2. In the key step these compounds were desulfurized. After deprotection the target compounds7 andent-7 were obtained.
Herrn Prof. Dr. H. Oelschläger zum 70. Geburtstag gewidmet 相似文献
69.
T. Gleisberg F. Krauss C. G. Papadopoulos A. Schälicke S. Schumann 《The European Physical Journal C - Particles and Fields》2004,34(2):173-180
In this paper total cross sections for signals and backgrounds of top- and Higgs-production channels in e + e- collisions at a future linear collider are presented. All channels considered are characterized by the emergence of six-particle final states. The calculation takes into account the full set of tree-level amplitudes in each process. Two multi-purpose parton level generators, HELAC/PHEGAS and AMEGIC + + , are used, and their results are found to be in perfect agreement.Received: 26 November 2003, Revised: 15 January 2004, Published online: 3 March 2004 相似文献
70.
Solichová D Melichar B Klejna M Jurašková B Královská L Bláha V Zd'ánský P Zadák Z 《Talanta》2003,60(2-3):459-465
Twelve self-sustaining nonagenarians, 10 women and two men, aged 94+/-3 years, and eight institutionalised nonagenarians, eight women, aged 91+/-1 year as well as 11 control subjects, seven women and four men, aged 84+/-5 years entered the study. Urinary neopterin, an indicator of systemic immune activation, and serum thiobarbituric acid reactive substances (TBARS), a marker of lipoperoxidation, were determined initially, and collection of the blood and urine samples was repeated at 3-month interval. Neopterin was measured in the urine specimens by reversed-phase high performance liquid chromatography. A C(18) reversed-phase column 3.3x150 mm, 5 mum-diameter packing Separon SGX was used. Potassium phosphate buffer (15 mmol l(-1), pH 6.4) at flow rate of 0.8 ml min(-1) was used as mobile phase. After centrifugation (5 min, 1300xg) and diluting 100 mul of urine specimens with 1.0 ml of mobile phase containing 2 g of disodium-EDTA per litre, a 20 mul sample was injected on a column. Neopterin was identified by its native fluorescence (353 nm excitation, 438 nm emission). Creatinine was determined by Jaffé kinetic reaction after dilution of sample 1:50 (v/v). The concentration of neopterin in urine was expressed as neopterin/creatinine ratio (mumol mol(-1) creatinine). TBARS were determined spectrofluorometrically using LS-5 spectrofluorimeter (excitation wavelength 528 nm, emission wavelength 558 nm) after extraction with n-butanol treatment with thiobarbituric acid. The significance of differences between nonagenarians and control group was examined by ANOVA-Kruskal-Wallis tests, using statistical software NCSS 6.0.21 (Kaysville, UT, 1996). The decision on significance was based on P=0.05. Urinary neopterin was significantly higher in institutionalised compared to self-sustaining subjects and controls (625+/-565 vs. 203+/-63 mumol mol(-1) creatinine, and 198+/-128 mumol mol(-1) creatinine, respectively, P=0.006). The serum TBARS were higher in both groups of nonagenarians (3.23+/-1.16 mumol l(-1) and 2.69+/-0.39 vs. 2.12+/-0.83 mumol l(-1) for the self-sustaining, institutionalised and controls, respectively, P=0.023). We conclude that the fluorimetric determinations of urinary neopterin and serum TBARS can be useful for the monitoring health status in the elderly patients. 相似文献