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11.
This review covers crystallographic and structural data for almost fifty polymeric FeM complexes (M = transition Cu, Ag, Au, Mo, W, Mn, Co, Ni and Pt and lanthanide elements Sm, Er and Yb) where iron is involved in polymeric chains. The complexes are for the most part yellow or black, but there are complexes of brown, orange, red, purple, blue and green colour. The complexes crystallized in the monoclinic (by far prevails), triclinic, tetragonal, orthorhombic, trigonal, hexagonal and rhombohedral crystal classes. The iron atoms are found in oxidation states 0, +2 and +3, of which +3 by far prevails. The inner coordination spheres about the Fe(0) atom are tetrahedral (FeC4) or sandwiched (FeC10), Fe(II) atoms are six-coordinated, and Fe(III) are six or even seven-coordinated. The inner coordination about M atoms range from four- through six- to eight-coordinated. The shortest Fe-Fe, Fe-M (transition) and Fe-M (lanthanide) and M-M separations are: 8.08 Å, 3.033 Å for Fe-Cu, 3.010 Å for Fe-Yb and 2.505 Å for Mo-Mo. 相似文献
12.
The asymptotics of the solution to the Neumann spectral problem in a domain of the “dense-comb” type
Convergence theorems and asymptotic estimates (as ε → 0) are proved for the eigenvalues and the eigenfunctions of the Neumann
problem in a dense singular junction Ω
ɛ
of a domain Ω0 and a large number N of thin cylinders with thickness of order ε=lN−1, where l is the total length of common boundaries for Ω0 and the cylinders in question. Bibliography: 27 titles.
We dedicate the present paper to Olga Arsenievna Oleinik, as a symbol of our deep respect and gratitude
Translated from Trudy Seminara imeni I G. Petrovskogo, No. 19. pp. 000-000. 0000. 相似文献
13.
K.R Allakhverdiev N.Yu Safarov M.A Nizametdinova E.A vinogradov N.N Melnik A.F Goncharov S.I Subbotin 《Solid State Communications》1982,42(7):485-488
First order Raman spectra of TIS and TlInSe2 single crystals excited with 1.064μm line of the continuously operated YAG: Nd3+ laser have been investigated in equilibrium conditions under various hydrostatic pressures up to 1.08 × 109 and 7.06 × 108 Pa, respectively. Mode parameters γj = (1/νj)(dνj/dP) were determined for all the Raman bands observed. Comparison of a set of these parameters in both crystals showed that the character of binding interatomic forces in these crystals appeared to be similar. For both crystals the intensity of Raman bands decreased with increasing the pressure. 相似文献
14.
I.P. Koval Yu.N. Krynko P.V. Melnik N.G. Nakhodkin A.I. Shaldervan 《Surface science》1978,77(1):40-51
A technique is presented of electron mean free path determination in solids using the spectra of backscattered electrons. The mean free path without energy loss (λ0) in Ge, and the mean free paths for excitation of volume (λv) and surface (λs) plasmons in Al, are determined in the electron energy range E0 = 0.1–10 kev. The depth ds of surface plasmon localization is estimated for Al. 相似文献
15.
An experimental study has been carried out to investigate Raman scattering spectra of GaS1-xSex solid solutions in which a one-dimensional localization of interlayer mode due to a disorder in the layer stacking was observed. 相似文献
16.
17.
Alena A. Nastulyavichus Irina N. Saraeva Andrey A. Rudenko Roman A. Khmelnitskii Alexander L. Shakhmin Demid A. Kirilenko Pavel N. Brunkov Nikolay N. Melnik Nikita A. Smirnov Andrey A. Ionin Sergey I. Kudryashov 《Particle & Particle Systems Characterization》2020,37(5):2000010
Si nanoparticles (NPs), which are innovative promising light-harvesting components of thin-film solar cells and key-enabling biocompatible theranostic elements of infrared-laser and radiofrequency hyperthermia-based therapies of cancer cells in tumors and metastases, are significantly advanced in their near/mid-infrared band-to-band and free-carrier absorption via donor sulfur-hyperdoping during high-throughput facile femtosecond-laser ablative production in liquid carbon disulfide. High-resolution transmission electron microscopy and Raman microscopy reveal their mixed nanocrystalline/amorphous structure, enabling the extraordinary sulfur content of a few atomic percents and very minor surface oxidation/carbonization characterized by energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. A 200-nm thick layer of the nanoparticles exhibits near−mid-infrared absorbance, comparable to that of the initial 380-micron thick n-doped Si wafer (phosphor-dopant concentration ≈1015 cm−3), with the corresponding extinction coefficient for the hyperdoped NPs being 4–7 orders higher over the broadband spectral range of 1–25 micrometers. Such ultimate, but potentially tunable mid-IR structured, multi-band absorption of various sulfur-impurity clusters and smooth free-carrier absorption are break through advances in mid-infrared (mid-IR) laser and radiofrequency (RF) hyperthermia-based therapies, as envisioned in the RF-heating tests, and in fabrication of higher-efficiency thin-film and bulk photovoltaic devices with ultra-broad (UV−mid-IR) spectral response. 相似文献
18.
Contrary to conventional light emitting diodes for visible and very near infrared utilizing interband (ω>Eg) luminescence, the longer infrared emitting diodes (LIREDs) we describe here utilize intraband (ω<Eg) electron transitions and emit beyond the fundamental absorption range of the material used. Made of indirect band gap semiconductors (like Ge, Si) and, therefore, free from the Auger recombination impact, LIREDs efficiently operate at higher temperatures (T>300 K) in the longer wavelength atmospheric window (8–12 μm). Electrically modulated power emitted is comparable to that for black body sources whereas shorter rise–fall times are due to recombination processes (200 μs) and not dependent on pixel thermal mass and thermal conduction. LIREDs can be made of different semiconductor structures provided the controllable modulation of free carrier concentration in the device base is achieved. The main parameters of Ge based LIREDs under injection mode are reported. 相似文献
19.
Kudryashov S. I. Danilov P. A. Porfirev A. P. Rudenko A. A. Melnik N. N. Kuchmizhak A. A. Vitrik O. B. Ionin A. A. 《JETP Letters》2019,109(11):755-761
JETP Letters - The spatial dependence of the differential conductivity of ultrathin Pb films deposited on the Si(111)7 × 7 surface has been studied by low-temperature scanning tunneling... 相似文献
20.
T. N. Zavaritskaya N. N. Melnik F. A. Pudonin O. S. Talarico I. A. Sherstnev 《Bulletin of the Russian Academy of Sciences: Physics》2017,81(3):301-304
A new method is proposed that allows an integrated technology to be used for the synthesis of carbon planar structures with predetermined properties. The method is based on the avalanche annealing of amorphous short-period superlattices. The synthesized samples are investigated by Raman spectroscopy and photoluminescence. The possibility of synthesizing carbon layers with diamond-like, graphite-like, graphene, or other structures is demonstrated experimentally using the example of a C/SiC superlattice. 相似文献