Dynamic multi-axial behavior of shape memory alloy nanowires with coupled thermo-mechanical phase-field models

The objective of this paper is to provide new insight into the dynamic thermo-mechanical properties of shape memory alloy (SMA) nanowires subjected to multi-axial loadings. The phase-field model with Ginzburg–Landau energy, having appropriate strain based order parameter and strain gradient energy contributions, is used to study the martensitic transformations in the representative 2D square-to-rectangular phase transformations for FePd SMA nanowires. The microstructure and mechanical behavior of martensitic transformations in SMA nanostructures have been studied extensively in the literature for uniaxial loading, usually under isothermal assumptions. The developed model describes the martensitic transformations in SMAs based on the equations for momentum and energy with bi-directional coupling via strain, strain rate and temperature. These governing equations of the thermo-mechanical model are numerically solved simultaneously for different external loadings starting with the evolved twinned and austenitic phases. We observed a strong influence of multi-axial loading on dynamic thermo-mechanical properties of SMA nanowires. Notably, the multi-axial loadings are quite distinct as compared to the uniaxial loading case, and the particular axial stress level is reached at a lower strain. The SMA behaviors predicted by the model are in qualitative agreements with experimental and numerical results published in the literature. The new results reported here on the nanowire response to multi-axial loadings provide new physical insight into underlying phenomena and are important, for example, in developing better SMA-based MEMS and NEMS devices     

Laser-assisted generation of gold nanoparticles and nanostructures in liquid and their plasmonic luminescence

Nanoparticles (NPs) and surface nanostructures (NS) are produced via laser ablation of a bulk gold target in liquid using second harmonics of 10 ps Nd:YAG laser (532 nm) with repetition rate of 50 kHz. The morphology and plasmon photoluminescence (PL) properties of obtained nanoscale objects are described. Transmission electron microscopy and field emission scanning electron microscopy are used for morphology characterization of NPs and NS, respectively. Plasmon PL of both gold NPs and NS is experimentally studied using the third harmonics of the Nd:YAG picosecond laser (355 nm) as a pump. The wavelength of intensity maximum of PL of Au NPs colloidal solution virtually coincides with the position of Au NPs plasmon absorption peak. Real-time excitation of both plasmon PL and Raman scattering of surrounding liquid by picosecond laser pulses in aqueous colloidal solution is also investigated. The efficient cross section of plasmon PL of Au NPs colloid is evaluated using Raman scattering of water as a comparative parameter. The results are in good agreement with values obtained in previous works. Plasmon PL from self-organized NS on the Au surface produced via laser ablation is observed for the first time. Its spectrum is compared to PL spectra of both aqueous colloidal solutions of NPs and of NPs deposited on a Si wafer. The obtained experimental data are discussed with reference to the band structure of bulk Au.     

Synthesis of carbon films by magnetron sputtering of a graphite target using hydrogen as plasma-forming gas

During magnetron sputtering of graphite using hydrogen as plasma-forming gas, a material sputtered from the target deposited only on heated substrates. When using currentheated Ni-Fe foils as substrates, carbon deposits of different crystal structures were obtained. The conditions for growing single-crystal graphite layers and single- and multilayer graphenes are found by analyzing deposits by Raman scattering.     

Neutron Collimator for the Diagnostic System of Neutral Particle Analyzers of the ITER Tokamak

Physics of Atomic Nuclei - A neutron collimator is developed to attenuate the neutron flux and reduce the residual induced activity in the interportal space of the diagnostic system of neutral...     

Numerical simulation of formation of a concentrated brine lens subject to magma chamber degassing

The mathematical model of flow of a binary salt-water mixture through a porous medium in a wide range of pressure and temperature is developed taking different multiphase thermodynamic equilibria of the mixture into account. Formation of concentrated brine lenses above a degassing magma chamber is investigated within the framework of the model. The lenses are assumed to be coupled with generation of ore deposits. It is shown that the lens formation is caused by phase transitions of two different types undergoing at different depths in the magmatic fluid rising towards the surface. In the shallow zones salt precipitation on the skeleton of the porous medium in the form of a solid phase leads to clogging of pore space and reduction of the permeability. As a result, the magmatic fluid flow towards the surface is blocked and this facilitates the concentrated brine accumulation in a local zone.     

Design Features of the Neutral Particle Diagnostic System for the ITER Tokamak

The control of the deuterium–tritium (DT) fuel isotopic ratio has to ensure the best performance of the ITER thermonuclear fusion reactor. The diagnostic system described in this paper allows the measurement of this ratio analyzing the hydrogen isotope fluxes (performing neutral particle analysis (NPA)). The development and supply of the NPA diagnostics for ITER was delegated to the Russian Federation. The diagnostics is being developed at the Ioffe Institute. The system consists of two analyzers, viz., LENPA (Low Energy Neutral Particle Analyzer) with 10–200 keV energy range and HENPA (High Energy Neutral Particle Analyzer) with 0.1–4.0MeV energy range. Simultaneous operation of both analyzers in different energy ranges enables researchers to measure the DT fuel ratio both in the central burning plasma (thermonuclear burn zone) and at the edge as well. When developing the diagnostic complex, it was necessary to account for the impact of several factors: high levels of neutron and gamma radiation, the direct vacuum connection to the ITER vessel, implying high tritium containment, strict requirements on reliability of all units and mechanisms, and the limited space available for accommodation of the diagnostic hardware at the ITER tokamak. The paper describes the design of the diagnostic complex and the engineering solutions that make it possible to conduct measurements under tokamak reactor conditions. The proposed engineering solutions provide a safe—with respect to thermal and mechanical loads—common vacuum channel for hydrogen isotope atoms to pass to the analyzers; ensure efficient shielding of the analyzers from the ITER stray magnetic field (up to 1 kG); provide the remote control of the NPA diagnostic complex, in particular, connection/disconnection of the NPA vacuum beamline from the ITER vessel; meet the ITER radiation safety requirements; and ensure measurements of the fuel isotopic ratio under high levels of neutron and gamma radiation.     

Vibration of piezoelectric elements surrounded by fluid media

In this paper we analyse vibrational characteristics of piezoceramic shells surrounded by acoustic media. Main results are presented for radially polarized piezoceramic PZT5 elements of hollow cylindrical shapes. The coupling in the radial direction between the solid and the acoustic media is accounted for indirectly, via impedance boundary conditions. The model based on such impedance boundary condition approximations offers a robust simplified alternative to a full scale fluid-solid interaction modelling. By using this model, we analyse numerically the influence of the boundary conditions imposed in the axial direction for long, medium, and short (disk-like) piezoceramic elements.     

Luminescent Hybrid Materials Based on Polymers of Poly(Alpha-Fluoroacrylates) Doped with Tb(III) Complex

This study is devoted to the development of efficient luminescent hybrid materials excited by UV radiation and featuring narrow luminescence lines as well as light, humidity, and temperature resistance. As a luminescent material, a terbium ion coordination compound introduced into the matrix of an organofluorine polymer is used. It has been shown that efficient excitation transfer to electronic levels of the terbium ion can be achieved by proper ligand selection. The polymer matrix material does not affect the luminescence properties of the Tb(III) coordination compound.     

On the short-range order of the SiOx (0 ≤ x ≤ 2) surface

Fine (oscillating) structure (FS) in the elastically scattered electron spectra (ESES) [O. Bondarchuk, S. Goysa, I. Koval, P. Melnik, M. Nakhodkin, Surf. Sci. 258 (1991) 239; O. Bondarchuk, S. Goysa, I. Koval, P. Melnik, M. Nakhodkin, Surf. Rev. Lett. 4 (1997) 965] was used to investigate surface structure of the SiO_x (0 ≤ x ≤ 2). SiO_x surface with different stoichiometry was prepared by implantation of 500 eV oxygen ions into a silicon wafer. Fourier transformation of the FS ESES contains one peak at 2.32 Å for Si, two peaks at 1.62 Å and 2.65 Å for a-SiO₂ and three peaks centered at 1.6-1.7 Å, 2.1-2.2 Å and 2.65-3.04 Å for SiO_x. Peaks at 1.62 Å and 2.65 Å are assigned to Si-O and O-O nearest distances correspondently. Ratio of the area under the peak at 2.65 Å to the area under the peak at 1.62 Å turned out to be not constant but grows linearly with the composition parameter x. The latter is considered to prove validity of the Random Bond Model to describe short-range order on the surface of non-stoichiometric silicon oxide.     

Wavelength stabilization and spectrum narrowing of high-power multimode laser diodes and arrays by use of volume Bragg gratings

Spectral line narrowing (by a factor of 8) and stabilization of the emission wavelength (by a factor of 30) of multimode high-power laser diodes and arrays is demonstrated by use of volume Bragg gratings fabricated in high-stability inorganic photorefractive glasses. Applications include stabilization of pump laser diodes and arrays for solid-state lasers and metal-vapor lasers, spin hyperpolarization of noble gases used in medical imaging, and others.