Thermodynamic analysis of the copper production step in a copper–chlorine cycle for hydrogen production

The hybrid copper–chlorine (Cu–Cl) thermo/electrochemical cycle for decomposing water into its constituents is a novel method for hydrogen production. The process involves a series of closed-loop chemical reactions. The cycle is assumed driven in an environmentally benign manner using nuclear energy. The cycle involves five steps of which three are thermally driven chemical reactions and one has an electrochemical reaction. In the present study, the electrochemical reaction, copper (Cu) production step, is described with its operational and environmental conditions, and analyzed thermodynamically. Various parametric studies are carried out on energetic and exergetic aspects of the step, considering variable reaction and reference-environment temperatures. At a reaction temperature of 45 °C, the reaction heat of the Cu production step is 140,450 kJ/kmol H₂. At a constant reaction temperature of 45 °C, the exergy destruction of the step varies between 50 kJ/kmol H₂ and 7000 kJ/kmol H₂ when the reference-environment temperature increases from 0 °C to 30 °C. At a reaction temperature of 45 °C and a reference-environment temperature of 25 °C, the exergy efficiency of this step is 99% and decreases with increasing reference-environment and/or reaction temperatures.     

Application of Impedimetric and Voltammetric Genosensor for Detection of a Biological Warfare: Anthrax

A strategy for the detection of anthrax, which is a potential biological weapon by using an electrochemical genosensing technology, is investigated. An alkanathiol‐linked or unlabeled capture probe related to B. anthracis is immobilized onto gold or graphite electrode surface. A 101‐mer anthrax target is used for hybridization. The extent of hybridization between probe and target sequences is determined by using differential pulse voltammetry (DPV) and electrochemical impedance spectrometry (EIS). EIS analysis are based on electron transfer resistance (R_ct) in the presence of [Fe(CN)₆]^3?/4? and DPV measurements are based on transduction of both guanine oxidation and Meldola's blue (MDB) reduction signal as hybridization indicator. The response of the probe‐modified electrodes which was interacted with a noncomplementary sequence was the same as the responses of probe‐modified surface and proved the specifity of the hybridization with the target. According to these results the developed genosensors based on EIS and DPV techniques can be employed for rapid and selective detection of B. anthracis.     

Tractive rolling contact mechanics of graded coatings

In this study, the tractive rolling contact problem between a rigid cylinder and a graded coating is investigated. The main objective of this study is to investigate the effect of the stiffness ratio, the coefficient of friction and the coating thickness on the surface contact tractions, the surface in-plane stress, the stick zone length and the creep ratio parameter that may have a bearing on the fatigue life of the component. Assuming that the shear modulus varies exponentially through the thickness of the coating, the governing integral equations associated with the rolling contact problem are constructed. Furthermore, it is supposed that the contact patch is controlled by a central stick zone accompanied by two slip zones. The conventional Goodman approximation is employed in order to decouple the governing singular integral equations. Finally, the numerical solution of the integral equations is obtained by applying the Gauss–Chebyshev integration method.     

Fully Developed Forced Convection in a Parallel Plate Channel with a Centered Porous Layer

In this study, fully developed heat and fluid flow in a parallel plate channel partially filled with porous layer is analyzed both analytically and numerically. The porous layer is located at the center of the channel and uniform heat flux is applied at the walls. The heat and fluid flow equations for clear fluid and porous regions are separately solved. Continues shear stress and heat flux conditions at the interface are used to determine the interface velocity and temperature. The velocity and temperature profiles in the channel for different values of Darcy number, thermal conductivity ratio, and porous layer thickness are plotted and discussed. The values of Nusselt number and friction factor of a fully clear fluid channel (Nu _cl = 4.12 and fRe _cl = 24) are used to define heat transfer increment ratio (e_th = Nu_p/Nu_cl)({\varepsilon _{\rm th} =Nu_{\rm p}/Nu_{\rm cl})} and pressure drop increment ratio (e_p = fRe_p/fRe_cl )({\varepsilon_{\rm p} =fRe_{\rm p}/fRe_{\rm cl} )} and observe the effects of an inserted porous layer on the increase of heat transfer and pressure drop. The heat transfer and pressure drop increment ratios are used to define an overall performance (e = e_th/e_p)({\varepsilon = \varepsilon_{\rm th}/\varepsilon_{\rm p})} to evaluate overall benefits of an inserted porous layer in a parallel plate channel. The obtained results showed that for a partially porous filled channel, the value of e{\varepsilon} is highly influenced from Darcy number, but it is not affected from thermal conductivity ratio (k _r) when k _r > 2. For a fully porous material filled channel, the value of e{\varepsilon} is considerably affected from thermal conductivity ratio as the porous medium is in contact with the channel walls.     

Synthesis,photophysical and antioxidant properties of pyrrolo[3,2-c]carbazole and dipyrrolo[3,2-c:2′,3′-g]carbazole compounds

Research on Chemical Intermediates - The synthesis of (6-ethyl-1,6-dihydropyrrolo[3,2-c]carbazol-2-yl)methanol 5 and...     

A Boron Doped Diamond Electrode Modified with Nano‐carbon Black for the Sensitive Electrochemical Determination of Chlorogenic Acid

An electrochemical method was developed for the sensitive determination of chlorogenic acid using a boron doped diamond electrode (BDDE) modified with nano‐carbon black (nano‐CB). The active surface areas were found to be 0.059 and 0.146 cm² for the unmodified BDDE, and nano‐CB/BDDE, respectively. Compared with a BDDE, the nano‐CB/BDDE exhibited a well‐defined redox couple for chlorogenic acid. In addition, the plot of the peak current response changing from a square root to a linear dependence on scan rate is attributed to the transition from planar diffusion to surface behaviour. The anodic and cathodic peak separations (ΔE_p) were 97 mV and 14 mV at BDDE and nano‐CB/BDDE, respectively. The decrease in ΔE_p at the proposed electrode indicated that the process of chlorogenic acid was greatly accelerated. Square wave voltammetry (SWV) exhibited a dynamic range in which the current versus the concentration of chlorogenic acid were linear from 2.0×10^?8 to 2.0×10^?6 M with a LOD of 4.1×10^?9 M (based on 3S_b/m). The nano‐CB modified BDDE provided improved electrochemical behavior, high electrocatalytic activity, high sensitivity and good reproducibility.     

Determination of thermal conductivities of Sn–Zn lead-free solder alloys with radial heat flow and Bridgman-type apparatus

The variations of thermal conductivities of solid phases versus temperature for pure Sn, pure Zn and Sn–9 wt.% Zn, Sn–14 wt.% Zn, Sn–50 wt.% Zn, Sn–80 wt.% Zn binary alloys were measured with a radial heat flow apparatus. The thermal conductivity ratios of liquid phase to solid phase for the pure Sn, pure Zn and eutectic Sn–9 wt.% Zn alloy at their melting temperature are found with a Bridgman-type directional solidification apparatus. Thus, the thermal conductivities of liquid phases for pure Sn, pure Zn and eutectic Sn–9 wt.% Zn binary alloy at their melting temperature were evaluated by using the values of solid phase thermal conductivities and the thermal conductivity ratios of liquid phase to solid phase.     

Hexagonal Type Ising Nanowire with Spin-1 Core and Spin-2 Shell Structure

Thermodynamic properties and phase diagrams of a mixed spin-(1,2) Ising ferrimagnetic system with single ion anisotropy on hexagonal nanowire are studied by using effective-field theory with correlations. The susceptibility, internal energy and specific heat of the system are numerically examined and some interesting phenomena in these quantities are found. The effect of the Hamiltonian parameters on phase diagrams are examined in detail. Besides second-order phase transition, lines of first-order transition and tricritical points are found. In particular, we found that for some negative values of single-ion anisotropies, there exist first-order phase transitions.     

Numerical investigation of BB-AMR scheme using entropy production as refinement criterion

In this work, a parallel finite volume scheme on unstructured meshes is applied to fluid flow for multidimensional hyperbolic system of conservation laws. It is based on a block-based adaptive mesh refinement strategy which allows quick meshing and easy parallelisation. As a continuation and as an extension of a previous work, the useful numerical density of entropy production is used as mesh refinement criterion combined with a local time-stepping method to preserve the computational time. Then, we numerically investigate its efficiency through several test cases with a confrontation with exact solution or experimental data.     

Complexiton solutions for two nonlinear partial differential equations via modification of simplified Hirota method

In this study, we obtain complexiton solutions of Sawada–Kotera equation and ninth-order KdV equation. For this cause, we employ Wazwaz and Zhaqilao’s method which can be regarded as generalization of simplified Hirota method through extension real parameters into complex parameters. Special conditions to distinguish complexiton, soliton, and soliton–complexiton interaction solutions from each other are given.