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991.
Md. Nizam Uddin Osama A. Fouad Masaaki Yamazato Masamitsu Nagano 《Applied Surface Science》2005,240(1-4):120-130
Carbon nitride thin films were deposited on Si(1 0 0) substrate by microwave plasma-enhanced chemical vapor deposition (PECVD). Hexamethylenetetramine (HMTA) was used as carbon and nitrogen source while N2 gas was used as both nitrogen source and carrier gas. The sp3-bonded C---N structure in HMTA was considered significantly in the precursor selection. X-ray diffraction analysis indicated that the film was a mixture of crystalline - and β-C3N4 as well as graphitic-C3N4 and β-Si3N4 which were not easily distinguished. Raman spectroscopy also suggested the existence of - and β-C3N4 in the films. X-ray photoelectron spectroscopy study indicated the presence of sp2- and sp3-bonded C---N structures in the films while sp3C---N bonding structure predominated to the sp2 C---N bonding structure in the bulk composition of the films. N was also found to be bound to Si atoms in the films. The product was, therefore, described as CNx:Si, where x depends on the film depth, with some evidences of crystalline C3N4 formation. 相似文献
992.
Md Mustafizur Rahman Kaoru Fujinaga Yasushi Seike Minoru Okumura 《Analytical sciences》2004,20(1):165-170
A simple in situ visual and tristimulus colorimetric method for the determination of trace arsenic in environmental water after collecting arsenic on a test paper impregnated with mercury(II) bromide and rosaniline chloride by its reduction aeration has been developed. The color development on the test paper is based on the formations of AsH(HgBr)2 (yellow) and/or As(HgBr)3 (brownish yellow) by a reaction between mercury(II) bromide and arsine (AsH3), which is produced through the reduction of As(III) (arsenite ion) and/or As(V) (arsenate ion) in a sample solution. To a sample solution, potassium iodide, tin(II) chloride, zinc sand and 4 ml of 6 M hydrochloric acid solution were added successively. The liberated arsine was collected on the test paper. The yellow or brownish-yellow color intensity on the test paper was measured by a tristimulus colorimeter and also by a visual method. The established method is applicable to the determination of arsenic in environmental water sample such as river, brackish, and seawater types. 相似文献
993.
994.
Kamruzzaman Khan Md. Abdus Salam Manik Mondal M. Ali Akbar 《Mathematical Methods in the Applied Sciences》2023,46(2):2042-2054
Traveling wave solutions have played a vital role in demonstrating the wave character of nonlinear problems emerging in the field of mathematical sciences and engineering. To depict the nature of propagation of the nonlinear waves in nature, a range of nonlinear evolution equations has been proposed and investigated in the existing literature. In this article, solitary and traveling periodic wave solutions for the (2 + 1)-dimensional modified KdV-KP equation are derived by employing an ansatz method, named the enhanced (G′/G)-expansion method. For this continued equation, abundant solitary wave solutions and nonlinear periodic wave solutions, along with some free parameters, are obtained. We have derived the exact expressions for the solitary waves that arise in the continuum-modified KdV-KP model. We study the significance of parameters numerically that arise in the obtained solutions. These parameters play an important role in the physical structure and propagation directions of the wave that characterizes the wave pattern. We discuss the relation between velocity and parameters and illustrate them graphically. Our numerical analysis suggests that the taller solitons are narrower than shorter waves and can travel faster. In addition, graphical representations of some obtained solutions along with their contour plot and wave train profiles are presented. The speed, as well as the profile of these solitary waves, is highly sensitive to the free parameters. Our results establish that the continuum-modified KdV-KP system supports solitary waves having different shapes and speeds for different values of the parameters. 相似文献
995.
Glow discharge plasmas exhibit various types of self-excited oscillations for different initial conditions like discharge voltages and filling pressures. The behavior of such oscillations associated with the anode glow has been investigated using nonlinear techniques like correlation dimension, largest Lyapunov exponent, etc. It is seen that these oscillations go to an ordered state from a chaotic state with an increase in input energy, i.e., with discharge voltages implying occurrence of inverse bifurcations. These results are different from the other observations wherein the fluctuations have been observed to go from ordered to chaotic state. 相似文献
996.
The polarographic streaming maxima and cyclic voltammetric anodic current oscillation (CVACO) at a hanging mercury drop electrode (HMDE) in room-temperature ionic liquid (RTIL) have been studied for the first time using cyclic voltammetric, potential step chronoamperometric and pulse voltammetric techniques. The reversible redox reaction of the 2,1,3-benzothiadiazole (BTD)/BTD*- (an anion radical of BTD) couple with a formal potential (E0') of -1.36 V versus Ag/AgCl/NaCl(saturated) in 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) RTIL was typically employed for this purpose. A maximum was observed at the rising part of the normal pulse voltammogram for the reduction of BTD to BTD*- as well as of the reversed pulse voltammogram for the reoxidation of BTD*- to BTD at the HMDE. The conditions of the initiation and control of the CVACO at the HMDE in EMIBF4 were extensively investigated. Generally, the CVACO was enhanced by increasing the concentration of BTD at a given potential scan rate (upsilon) and was attenuated by increasing upsilon. An electrocapillary curve was measured using a dropping mercury electrode in EMIBF4, and the potential of zero charge was determined to be -0.23 V. On the basis of the modern theory of the polarographic streaming maxima of the first kind, the observed streaming maxima and CVACO phenomena are successfully explained to originate from the macroscopic instability at the electrode/solution interface wherein the oscillating mode creates the CVACO. 相似文献
997.
998.
999.
Mitsuke K Katayanagi H Kafle BP Huang C Yagi H Prodhan MS Kubozono Y 《The journal of physical chemistry. A》2007,111(34):8336-8343
Partial cross sections for the photoion formation from C(60) and C(70) were determined from the yields of singly, doubly, and triply charged ions which were measured by mass spectrometry combined with tunable synchrotron radiation at hnu = 25-120 eV. The dependence of the detection efficiencies on the mass-to-charge ratio was evaluated by using the formula proposed by Twerenbold et al. Corrections of the detection efficiency were found to be critical for obtaining accurate partial cross sections for photoionization of fullerenes. Revisions were made of the partial cross-section curves for single and double photoionization of C(60) and C(70). The curve for triple photoionization of C(70) was newly proposed. The ratios between the cross sections for double and single photoionization increase with hnu and reach saturated values of 0.78 at 85 eV for C(60) and approximately 1.3 at 100 eV for C(70). In contrast, the ratios at 120 eV between the cross sections for triple and single photoionization of C(60) and C(70) amount to 0.14 and approximately 0.38, respectively. The formation mechanism of multiply charged fullerene ions was discussed in terms of valence-electron excitation to antibonding unoccupied orbitals and/or spherical standing waves inside the cavity of a fullerene. This excitation could be followed by Spectator Auger processes and transmission of the excess electronic energy among numerous vibrational degrees of freedom. 相似文献
1000.
Ali MM Su S Filipe CD Pelton R Li Y 《Chemical communications (Cambridge, England)》2007,(43):4459-4461
We demonstrate that DNA oligonucleotides covalently coupled to colloidal microgel can be manipulated by T4 DNA ligase for DNA ligation and by Phi29 DNA polymerase for rolling circle amplification (RCA). We also show that the long single-stranded RCA product can generate intensive fluorescence upon hybridization with complementary fluorescent DNA probe. We believe DNA-microgel conjugates can be explored for the development of DNA based bioassays and biosensors. 相似文献