Colorizing mechanism of brass surface by femtosecond laser induced microstructures

In this paper, we exhibit the colorizing of brass surfaces by forming femtosecond laser induced microstructures on the sample surfaces. A variety of single colors such as brown, yellow, green, and black are introduced on brass surfaces by engineering periodic microgratings, microholes, and ring-shaped micro-patterns using Single Beam Direct Laser Writing (SBDLW) technique. The color of the micro-structured brass surfaces is certainly dependent on the width, depth, and period of the microstructures. Finally, we explain, in brief, the colorizing mechanism of metals by femtosecond laser induced microstructures.     

Amperometric determination of nanomolar mercury(II) by layered double nanocomposite of zinc/aluminium hydroxide-3(4-methoxyphenyl)propionate modified single-walled carbon nanotube paste electrode

Ionics - A mercury(II) sensor was developed by using single-walled carbon nanotube (SWCNT) paste electrode modified with layered double Zn/Al hydroxide-3(4-methoxyphenyl)propionate nanocomposite...     

Highly Stable Graphene Inks Based on Organic Binary Solvents

Formulating highly stable graphene-based conductive inks with consistency in electrical properties over the storage period has remained a significant challenge in the development of wearable electronics. Two highly stable graphene-based inks (Cyclohexanone:Ethylene glycol (CEG) ink and Cyclohexanone:Terpineol (CT) ink) are prepared by using two different organic binary solvents, for the first time, without using solvent exchange methods. Both the inks display remarkably high stability (stable even after two months) with negligible variability in electrical properties. Here, it is demonstrated how such inks can be utilized to coat flexible substrates to create wearable e-textiles. Both the inks coated e-textiles show significantly low sheet resistance (≈209.1 Ω □⁻¹ for CEG ink and ≈322.4 Ω □⁻¹ CT ink) that show less than a 15% increase in electrical resistance over two months. Therefore, these inks offer high productivity and reproducibility and can be one of the most effective methods for formulating graphene-based inks.     

A Chebotarev Theorem for finite homogeneous extensions of shifts

We derive a Chebotarev Theorem for finite homogeneous extensions of shifts of finite type. These extensions are of the form :X×G/H→X×G/H where (x,gH)=(σx, α(x)gH), for some finite groupG and subgroupH. Given a σ-closed orbit τ, the periods of the -closed orbits covering τ define a partition of the integer |G/H|. The theorem then gives us an asymptotic formula for the number of closed orbits with respect to the various partitions of the integer |G/H|. We apply our theorem to the case of a finite extension and of an automorphism extension of shifts of finite type. We also give a further application to ‘automorphism extensions’ of hyperbolic toral automorphisms. Financially supported by Universiti Kebangsaan Malaysia     

Randomly chosen chaotic maps can give rise to nearly ordered behavior

Parrondo’s paradox [J.M.R. Parrondo, G.P. Harmer, D. Abbott, New paradoxical games based on Brownian ratchets, Phys. Rev. Lett. 85 (2000), 5226–5229] (see also [O.E. Percus, J.K. Percus, Can two wrongs make a right? Coin-tossing games and Parrondo’s paradox, Math. Intelligencer 24 (3) (2002) 68–72]) states that two losing gambling games when combined one after the other (either deterministically or randomly) can result in a winning game: that is, a losing game followed by a losing game = a winning game. Inspired by this paradox, a recent study [J. Almeida, D. Peralta-Salas, M. Romera, Can two chaotic systems give rise to order? Physica D 200 (2005) 124–132] asked an analogous question in discrete time dynamical system: can two chaotic systems give rise to order, namely can they be combined into another dynamical system which does not behave chaotically? Numerical evidence is provided in [J. Almeida, D. Peralta-Salas, M. Romera, Can two chaotic systems give rise to order? Physica D 200 (2005) 124–132] that two chaotic quadratic maps, when composed with each other, create a new dynamical system which has a stable period orbit. The question of what happens in the case of random composition of maps is posed in [J. Almeida, D. Peralta-Salas, M. Romera, Can two chaotic systems give rise to order? Physica D 200 (2005) 124–132] but left unanswered. In this note we present an example of a dynamical system where, at each iteration, a map is chosen in a probabilistic manner from a collection of chaotic maps. The resulting random map is proved to have an infinite absolutely continuous invariant measure (acim) with spikes at two points. From this we show that the dynamics behaves in a nearly ordered manner. When the foregoing maps are applied one after the other, deterministically as in [O.E. Percus, J.K. Percus, Can two wrongs make a right? Coin-tossing games and Parrondo’s paradox, Math. Intelligencer 24 (3) (2002) 68–72], the resulting composed map has a periodic orbit which is stable.     

Simultaneous Determination of Acetylsalicylic Acid and Caffeine in Pharmaceutical Formulation by First Derivative Synchronous Fluorimetric Method

A sensitive, rapid, and specific assay has been developed for the simultaneous determination of acetylsalicylic acid and caffeine in commercial tablets based on their natural fluorescence. The mixture of these drugs was resolved by first derivative synchronous fluorimetric technique using two scans. At Δλ=106 nm, using first derivative synchronous scanning, only acetylsalicylic acid yields a detectable signal at 316 nm (peak to zero method) which is unaffected by caffeine. At Δλ=30 nm, the signal of caffeine at 288 nm (peak to zero method) is not affected by acetylsalicylic acid. The range of application is between 0.021 and 41.62 μg ml⁻¹ (correlation coefficient, R=0.9995) for acetylsalicylic acid and between 0.4486 and 44.86 μg ml⁻¹ (correlation coefficient, R=0.99786) for caffeine. The recovery range of 98.40–102% for acetylsalicylic acid and 90–100.5% for caffeine from their synthetic mixture was reported. Overall recovery of both compounds about 97–99% for acetylsalicylic acid and 97–98% for caffeine was obtained from real sample analysis. The detection limits are 0.0013 μg ml⁻¹ and 0.0306 μg ml⁻¹ for acetylsalicylic acid and caffeine, respectively. The relative standard deviation (n=10) for 20 μg ml⁻¹ of acetylsalicylic acid is 2.75% and for 2.2 μg ml⁻¹of caffeine is 1.7%.     

Visualisation and analysis of large-scale vortex structures in three-dimensional turbulent lid-driven cavity flow

In this paper, large eddy simulation (LES) of a three-dimensional turbulent lid-driven cavity (LDC) flow at Re = 10,000 has been performed using the multiple relaxation time lattice Boltzmann method. A Smagorinsky eddy viscosity model was used to represent the sub-grid scale stresses with appropriate wall damping. The prediction for the flow field was first validated by comparing the velocity profiles with previous experimental and LES studies, and then subsequently used to investigate the large-scale three-dimensional vortical structures in the LDC flow. The instantaneous three-dimensional coherent structures inside the cavity were visualised using the second invariant (Q), Δ criterion, λ₂ criterion, swirling strength (λ_ci) and streamwise vorticity. The vortex structures obtained using the different criteria in general agree well with each other. However, a cleaner visualisation of the large vortex structures was achieved with the λ_ci criterion and also when the visualisation is based on the vortex identification criteria expressed in terms of the swirling strength parameters. A major objective of the study was to perform a three-dimensional proper orthogonal decomposition (POD) on the fluctuating velocity fields. The higher energy POD modes efficiently extracted the large-scale vortical structures within the flow which were then visualised with the swirling strength criterion. Reconstruction of the instantaneous fluctuating velocity field using a finite number of POD modes indicated that the large-scale vortex structures did effectively approximate the large-scale motion. However, such a reduced order reconstruction of the flow based on the large-scale vortical structures was clearly not as effective in predicting the small-scale details of the fluctuating velocity field which relate to the turbulent transport.     

Impact of average photon-energy coefficient of solar spectrum on the short circuit current of photovoltaic modules

The output energy of photovoltaic (PV) modules is influenced by the spectral irradiance distribution of the solar spectrum under outdoor conditions. To rate the precise output energy of PV modules, the correction of short circuit current (I_SC) based on actual environmental conditions is needed, because I_SC significantly depends on the shape of the spectral irradiance distribution. The average photon energy (APE) is a zero-dimensional index for spectral irradiance distribution, and APE value uniquely describes the shape of a solar spectrum. Thus, APE has an impact on I_SC of PV modules. In this contribution, the relationship between APE coefficient and I_SC of the multi-crystalline silicon, single-crystalline silicon, heterojunction intrinsic thin-layer, back contact, copper indium selenide and cadmium telluride PV modules has explored. It is revealed that APE value changes the I_SC of PV modules which appeared to have immense possibilities of I_SC correction using APE coefficient. This new approach can be very effective for precise rating the output energy of PV modules under actual outdoor conditions.     

Infrared Spectroscopic Analysis of Chrysene and 1.2-Benzanthracence in Wax films

Chrysene and 1.2-benzanthracene are successfully doped in a solid wax film and their vibrational spectra in gooo--400cm^-1 are discussed. The harmonic frequencies and relative intensities of both the molecules observed in the film are compared with theoretical values calculated by the density functional theory （DFT） model as well as with the previous experimental data. The effects on spectra due to change of matrix and some additional bands observed in the wax film are also reported. Excellent agreement in the spectral positions and strengths between the experiments and DFT values are found.     

Optical switching in a Ξ system: A comparative study on DROP and EIT

Liquid Lennard-Jones clusters with magic number of atoms N = 55, 147, 309, 561 and 923 were cooled down in Monte Carlo simulations until freezing. Structural properties of the clusters, including the radial dependence of atomic concentration/density and the local regular structure in arrangement of atoms, just before freezing were analysed. Existence of spherical layers in atomic density around the centre of mass of liquid LJ clusters was confirmed. Formation of layers is explained by central net forces acting on every cluster atom and leading to positioning an atom close to the cluster centre of mass. The strong layering in small clusters of N = 55 and 147 affects atomic diffusion in radial and tangential directions inside the cluster, leading to easier movement of atoms on the layer surface. Analysis of radial profiles of four types of structural units detected in liquid clusters reveals that icosahedral units are the most numerous and are located mainly near cluster surface of all clusters and also in the centre of small clusters.