The electronic structure of lithium metagallate

Herein we present a study of the electronic structure of lithium metagallate (LiGaO(2)), a material of interest in the field of optoelectronics. We use soft x-ray spectroscopy to probe the electronic structure of both the valence and conduction bands and compare our measurements to ab initio density functional theory calculations. We use several different exchange-correlation functionals, but find that no single theoretical approach used herein accurately quantifies both the band gap and the Ga 3d(10) states in LiGaO(2). We derive a band gap of 5.6 eV, and characterize electron hybridization in both the valence and conduction bands. Our study of the x-ray spectra may prove useful in analysing spectra from more complicated LiGaO(2) heterostructures.     

Matheuristics for solving a multi-attribute collection problem for a charity organisation

This paper studies a real-life multi-attribute profit collecting vehicle routing problem, arising in the collection operations of a charity organisation in the United Kingdom. The problem involves a heterogeneous fleet of vehicles of different capacities, mandatory visits to a subset of vertices, time windows, rest requirements associated with maximum driving and working times, and partial collection. A mixed integer programming formulation of the problem is described, along with three matheuristics based on Tabu Search and Large Neighbourhood Search. Computational results on instances derived from the case study are presented, and insights are given from a practical implementation.     

Behavioral event detection and rate estimation for autonomous vehicle evaluation

Autonomous vehicles are continually increasing their presence on public roads. However, before any new autonomous driving software can be approved, it must first undergo a rigorous assessment of driving quality. These quality evaluations typically focus on estimating the frequency of (undesirable) behavioral events. While rate estimation would be straight-forward with complete data, in the autonomous driving setting this estimation is greatly complicated by the fact that detecting these events within large driving logs is a non-trivial task that often involves human reviewers. In this article, we outline a streaming partial tiered event review configuration that ensures both high recall and high precision on the events of interest. In addition, the framework allows for valid streaming estimates at any phase of the data collection process, even when labels are incomplete, for which we develop the maximum likelihood estimate and show it is unbiased. Constructing honest and effective confidence intervals (CI) for these rate estimates, particularly for rare safety-critical events, is a novel and challenging statistical problem due to the complexity of the data likelihood. We develop and compare several CI approximations, including a novel gamma CI method that approximates the exact but intractable distribution with a weighted sum of independent Poisson random variables. There is a clear trade-off between statistical coverage and interval width across the different CI methods, and the extent of this trade-off varies depending on the specific application settings (e.g., rare vs. common events). In particular, we argue that our proposed CI method is the best-suited when estimating the rate of safety-critical events where guaranteed coverage of the true parameter value is a prerequisite to safely launching a new ADS on public roads.