Characterization of nonlinearities in the dose dependence of thermoluminescence

Nonlinearities often occur in the dose dependence of thermoluminescence (TL). These include sublinearity, usually when there is an approach to saturation in the dose dependence, as well as supralinearity, also termed superlinearity in the literature. Different researchers in the field have viewed the effect of supralinearity/superlinearity from two somewhat different points of view. One point of view has to do with the rate of change with dose of the dose dependence function. The other approach is related more to the applications of TL in dosimetry and archaeological and geological dating, and basically has to do with the correction to be made in extrapolation in cases where supra(super) linearity occurs following an initial linear dose range, or prior to such a linear range. In the present work we propose quantitative methods to characterize these nonlinearities. We suggest the use of two different nonlinearity indices, depending upon how one wishes to describe the nonlinearity. We propose use of the term “supra linearity index”, ƒ(D), in cases where the feature of interest is the deviation from linearity, namely, when the correction in extrapolation is the main issue. We propose the term “superlinearity index”, g(D), in dose ranges where the growth is “more than linear” and when extrapolation is not the main issue. We mathematically define each of these indices and give examples of their use for different dose dependencies.     

Rapid colorimetric determination of indoxyl acetate

A rapid colorimetric method is presented for the determination of submilligram amounts of indoxyl acetate. The method depends upon the conversion of the indoxyl acetate into indigo.     

Emergency Dose Estimation Using Optically Stimulated Luminescence from Human Tooth Enamel

Human teeth were studied for potential use as emergency Optically Stimulated Luminescence (OSL) dosimeters. By using multiple-teeth samples in combination with a custom-built sensitive OSL reader, (60)Co-equivalent doses below 0.64 Gy were measured immediately after exposure with the lowest value being 27 mGy for the most sensitive sample. The variability of OSL sensitivity, from individual to individual using multiple-teeth samples, was determined to be 53%. X-ray and beta exposure were found to produce OSL curves with the same shape that differed from those due to ultraviolet (UV) exposure; as a result, correlation was observed between OSL signals after X-ray and beta exposure and was absent if compared to OSL signals after UV exposure. Fading of the OSL signal was "typical" for most teeth with just a few of incisors showing atypical behavior. Typical fading dependences were described by a bi-exponential decay function with "fast" (decay time around of 12 min) and "slow" (decay time about 14 h) components. OSL detection limits, based on the techniques developed to-date, were found to be satisfactory from the point-of-view of medical triage requirements if conducted within 24 hours of the exposure.     

Observation of the vacuum Rabi spectrum for one trapped atom

The transmission spectrum for one atom strongly coupled to the field of a high finesse optical resonator is observed to exhibit a clearly resolved vacuum Rabi splitting characteristic of the normal modes in the eigenvalue spectrum of the atom-cavity system. A new Raman scheme for cooling atomic motion along the cavity axis enables a complete spectrum to be recorded for an individual atom trapped within the cavity mode, in contrast to all previous measurements in cavity QED that have required averaging over 10(3)-10(5) atoms.     

Characteristics of LM-OSL from several different types of quartz

We present Linear-Modulation OSL (LM-OSL) curves from several different types of quartz, including sedimentary quartz, bulk rock crystal and synthetic quartz. The LM-OSL method consists of linearly increasing the intensity of the stimulation light while continuously monitoring the OSL emission from the sample. With this technique, one obtains peaks of luminescence intensity versus time (Bulur, 1996) in which the position of the peak is inversely related to the photoionization cross-section of the trap. The shape of the LM-OSL curve is directly related to the shape of the conventional OSL decay curve in which the stimulating light source is maintained at constant intensity (so-called Continuous-Wave OSL, or CW-OSL). In the latter, the OSL from the traps with the highest photoionization cross-section decays most rapidly with stimulation time, while OSL from those traps with smaller photoionization cross-sections is characterized by longer decay times. In this paper, data are presented comparing the CW-OSL and LM-OSL curves for several different quartz types with particular focus on the changes in the shapes of each of these curves with sample type pre-heat temperature, and measurement temperature. Several different LM-OSL components are found for each sample, each with different photoionization cross-sections, but a universal behavior for quartz is not observed; each sample is different. From the dependence upon pre-heat temperature, features associated with shallow traps can be identified. Traps which empty very rapidly can be observed more easily in the LM-OSL curves than in the conventional CW-OSL curves, and the temperature dependence of the photoionization cross-section for the various components can be clearly discerned.     

Stereoselective Synthesis of Tetrahydroindolizines through the Catalytic Formation of Pyridinium Ylides from Diazo Compounds

Commercially available iron(III) and copper(I) complexes catalyzed multicomponent cycloaddition reactions between diazo compounds, pyridines, and electrophilic alkenes to give alkaloid‐inspired tetrahydroindolizidines in high yield with high diastereoselectivity. Hitherto, the catalytic formation of versatile pyridinium ylides from metal carbenes has been poorly developed; the broad utility demonstrated herein sets the stage for the invention of further multicomponent reactions in future.     

Total synthesis of mollamide, a reverse prenyl substituted cytotoxic cyclic peptide from Didemnum molle

A total synthesis of the novel reverse prenyl substituted cyclic peptide mollamide, isolated from the ascidian Didemnum molle, is described.     

Reanalysis of the D → X fluorescence spectrum of I2

The uv fluorescence spectrum of I₂ excited by iodine atomic radiation at 1830 Å is photographed and analyzed using a direct least-squares-fitting method with consistency constraints on the centrifugal distortion constants. The analysis confirms Verma's [J. Chem. Phys.32, 738–749 (1960)] prior analysis of this spectrum and yields improved molecular constants for v = 0–99 of the X state and $\text{v ? 204–208}$ of the D state.