Effect of high-dose irradiation on the optically stimulated luminescence of Al2O3:C

This paper examines the effect of high-dose irradiation on the optically stimulated luminescence (OSL) of Al2O3:C, principally on the shape of the OSL decay curve and on the OSL sensitivity. The effect of the degree of deep trap filling on the OSL was also studied by monitoring the sensitivity changes after doses of beta irradiation and after step-annealing of samples previously irradiated with high doses. The OSL response to dose shows a linear-supralinear-saturation behavior, with a decrease in the response for doses higher than those required for saturation. This behavior correlates with the sensitivity changes observed in the samples annealed only to 773 K, which show sensitization for doses up to 20-50 Gy and desensitization for higher doses. Data from the step-annealing study leads to the suggestion that the sensitization is caused by the filling of deep electron traps, which become thermally unstable at 1100-1200 K, whereas the desensitization is caused by the filling of deep hole traps, which become thermally unstable at 800-875 K, along with a concomitant decrease in the concentration of recombination centers (F+ -centers). Changes in the shape of the OSL decay curves are also observed at high doses, the decay becoming faster as the dose increases. These changes in the OSL decay curves are discussed in terms of multiple overlapping components, each characterized by different photoionization cross-sections. However, using numerical solutions of the rate equations for a simple model consisting of a main trap and a recombination center, it is shown that the kinetics of OSL process may also be partially responsible for the changes in the OSL curves at high doses in Al2O3:C. Finally, the implication of these results for the dosimetry of heavy charged particles is discussed.     

Optical bleaching studies of quartz

The bleaching properties of a hydrothermal, Arkansas quartz are studied in detail. The thermoluminescence (TL) and phototransferred TL (PTTL) signals are examined as a function of wavelength, illumination time and temperature at which the sample is illuminated. We have also briefly studied the effects of pre-irradiation annealing on the sample. The results of these experiments are described and their relevance to the models for TL is discussed.     

Remarkably Slow Rotation about a Single Bond between an sp3‐Hybridised Carbon Atom and an Aromatic Ring without ortho Substituents

Look, no ortho substituents! A series of polycycles were prepared by using a three‐component Joullié–Ugi reaction. The rate of rotation about the bond between a highly hindered bridgehead and a phenyl ring with no ortho substituents was measured, and was highly dependent on the substitution. Rotamer half‐lives of up to 21 h at 298 K were observed (see figure). Rotamers resulting from this restricted rotation were isolated for the first time.

     

Concepts and approaches to in situ luminescence dating of Martian sediments

In this paper we present the concept of a robotic instrument for in situ luminescence dating of near-surface sediments on Mars. The scientific objectives and advantages to be gained from the development of such an instrument are described, and the challenges presented by the Mars surface environment to the design and operation of the instrument are outlined.     

Emergency Dose Estimation Using Optically Stimulated Luminescence from Human Tooth Enamel

Human teeth were studied for potential use as emergency Optically Stimulated Luminescence (OSL) dosimeters. By using multiple-teeth samples in combination with a custom-built sensitive OSL reader, (60)Co-equivalent doses below 0.64 Gy were measured immediately after exposure with the lowest value being 27 mGy for the most sensitive sample. The variability of OSL sensitivity, from individual to individual using multiple-teeth samples, was determined to be 53%. X-ray and beta exposure were found to produce OSL curves with the same shape that differed from those due to ultraviolet (UV) exposure; as a result, correlation was observed between OSL signals after X-ray and beta exposure and was absent if compared to OSL signals after UV exposure. Fading of the OSL signal was "typical" for most teeth with just a few of incisors showing atypical behavior. Typical fading dependences were described by a bi-exponential decay function with "fast" (decay time around of 12 min) and "slow" (decay time about 14 h) components. OSL detection limits, based on the techniques developed to-date, were found to be satisfactory from the point-of-view of medical triage requirements if conducted within 24 hours of the exposure.     

The effects of deep trap population on the thermoluminescence of Al2O3:C

The influence of deep traps on the 450 K thermoluminescence (TL) peak of Al₂O₃:C is studied. Depending upon the sample and on the degree of deep trap filling, features such as the TL width, area and height can vary considerably. These effects are interpreted to be due to: (a) sensitivity changes introduced by competition mechanisms involving deep electron and hole traps, and (b) the multiple component nature of the 450 K TL peak. The influence of the deep traps on the TL was studied using different excitation sources (beta irradiation or UV illumination), and step annealing procedures. Optical absorption measurements were used to monitor the concentration of F- and F⁺-centers. The data lead to the suggestion that the competing deep traps which become unstable at 800–875 K are hole traps, and that the competing deep traps which become unstable at 1100–1200 K are electron traps. Both the dose response of the TL signal and the TL sensitivity are shown to be influenced by sensitization and desensitization processes caused by the filling of deep electron and hole traps, respectively. Changes in the TL peak at low doses were also shown to be connected to the degree of filling of deep traps, emphasizing the influence of deep trap concentration and dose history of each sample in determining the TL properties of the material. Implications of these results for the optically stimulated luminescence properties are also discussed.     

Inter-comparison among fast neutron dosimetric services using PADC material of different composition

A trial inter-comparison has been performed among four fast neutron dosimetric services: PSI(CH), ENEA (I), DRPS (UK), LANL (US). The PADC used for the tests has been produced by Intercast Europe S.p.A. Three sets of detectors have been employed: two of PADC standard material from two different batches, and one of PADC with the addition of 0.1% dioctylphthalate. Each set consisted of 50 detectors.

For each set of detectors, 20 have been irradiated free-in-air at 1 mSv of H^*(10) with an ²⁴¹Am–Be source at ENEA-IRP, whilst the other detectors have been used as background samples. For each batch the value of the average background signal, B, the average neutron sensitivity, S, and minimum detectable dose equivalent, MDDE, have been determined. Two identical tests have been completed and separated with a time of 4 months in order to evaluate the ageing effect on the material stored in different conditions. Each dosimetric service processed the detectors according to local routine procedures. Three laboratories used an Autoscan60 reader, whilst one laboratory has an in-house reading system. Therefore, the results of the tests allowed a comparison of either the performance PADC materials, of different batches and of different compositions, or to evaluate how different etching, reading and storage conditions affect the results.     

Particularism and the contingent a priori

Particularism renders the options for a sound moral epistemology few and the prospects dim. One leading approach treats basic knowledge of particular cases as derivable from an a priori moral principle and a posteriori knowledge of the contingent non-moral facts to which the principle applies. Particularists must forgo this approach because it requires principles. Yet a purely a posteriori moral epistemology is also implausible, especially when combined with particularism. Particularists such as Jonathan Dancy are thus led to the view that our basic moral knowledge is a priori knowledge of contingent moral facts. We argue that this epistemology is unsound. While some cases of a priori knowledge of (even deeply) contingent facts may be defensible, they are not sufficient for particularist purposes. Moreover, neither Dancy’s appeal to the distinction between positive and negative dependence nor his discussion of intuitive examples provides sufficient support for this epistemology.     

Observation of the vacuum Rabi spectrum for one trapped atom

The transmission spectrum for one atom strongly coupled to the field of a high finesse optical resonator is observed to exhibit a clearly resolved vacuum Rabi splitting characteristic of the normal modes in the eigenvalue spectrum of the atom-cavity system. A new Raman scheme for cooling atomic motion along the cavity axis enables a complete spectrum to be recorded for an individual atom trapped within the cavity mode, in contrast to all previous measurements in cavity QED that have required averaging over 10(3)-10(5) atoms.