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921.
von Eynatten G. Ritter T. Bömmel H. E. Dransfeld K. 《Zeitschrift für Physik B Condensed Matter》1987,65(3):341-345
A new model is presented which explains well the dramatic decrease of the Mössbauer line intensities with raising temperatures for freely dispersed iron microscrystals. In contrast to other theories which consider mainly vibration to be responsible we discuss here the decrease in terms of large amplitude diffusive rotational or translational jumps of the particles. Such diffusive jumps lead — in agreement with the observation — to a strong reduction of the Mössbauer-intensity without broadening the line width in a noticeable way. The typical potential well for a diffusing particle in an equilibrium position is derived quantitatively to be 13 meV. The model might be important also for a new understanding of the dynamics of catalytic clusters either in contact with each other or with larger solid surfaces.Part of this work was supported by the DFG Sonderforschungsbereich 306, Konstanz 相似文献
922.
Tunable properties of light propagation in photonic crystal fibers filled with liquid crystals, called photonic liquid crystal
fibers (PLCFs) are presented. The propagation properties of PLCFs strongly depend on contrast between refractive indices of
the solid core (pure silica glass) and liquid crystals (LCs) filing the holes of the fiber. Due to relatively strong thermo-optical
effect, we can change the refractive index of the LC by changing its temperature. Numerical analysis of light propagation
in PLCF, based on two simulation methods, such as finite difference (FD) and multipole method (MM) is presented. The numerical
results obtained are in good agreement with our earlier experimental results presented elsewhere [1]. 相似文献
923.
Steady state temperature distribution in a model Czochralski crucible has been mapped by liquid crystal thermography (LCT).
The crucible is a water-filled glass beaker. Water is used as the test fluid because of ease of experimentation, as well as
the availability of correct thermo-physical properties. In addition, the Prandtl number of water matches those of molten oxides.
A copper cylinder whose diameter is smaller than that of the beaker is placed centrally at the water surface. Convection patterns
are set up by applying constant temperature difference between the crucible wall and the cylinder surface, in the temperature
range of the liquid crystals. The cylinder is given a fixed rotation, thus creating mixed convection conditions in the test
fluid. The LCT images recorded in the present study clearly reveal convective rolls, and the interaction of buoyancy-driven
convection in the crucible with cylinder rotation. The resulting temperature distributions match numerical simulation quite
well. The pure buoyancy and pure rotation experiments result in axisymmetric temperature fields, while in mixed convection,
the field is unsteady and three dimensional. 相似文献
924.
G. S. Patrin V. V. Beletskiĭ D. A. Velikanov O. A. Bayukov V. V. Vershinin O. V. Zakieva T. N. Isaeva 《Physics of the Solid State》2006,48(4):700-704
The results of experimental and theoretical studies of the low-temperature properties of FeSi crystals are presented. The specific features of the magnetic susceptibility are shown to be related to the superparamagnetic behavior of impurity clusters. The thermomagnetic hysteresis phenomena observed are explained using the model of exchange-coupled clusters. 相似文献
925.
I. P. Dobrovol’skaya M. V. Mokeev Yu. N. Sazanov A. V. Gribanov T. E. Sukhanova 《Russian Journal of Applied Chemistry》2006,79(8):1312-1315
Variation of the supramolecular structure of heat-resistant polymide films in the course of high-temperature treatment was studied by X-ray diffraction analysis and NMR spectroscopy in solids. 相似文献
926.
High temperature GaN layers have been grown on Si (1 1 1) substrate by metalorganic vapor phase epitaxy (MOVPE). AlN was used as a buffer layer and studied as a function of thickness and growth temperature. The growth was monitored by in situ laser reflectometry. High resolution X-ray diffraction (HRXRD) revealed that optimized monocrystalline GaN was obtained for a 40 nm AlN grown at 1080 °C. This is in good agreement with the results of morphological study by scanning electron microscopy (SEM) and also confirmed by atomic force microscopy (AFM) observations. The best morphology of AlN with columnar structure and lower rms surface roughness is greatly advantageous to the coalescence of the GaN epilayer. Symmetric and asymmetric GaN reflections were combined for twist and stress measurements in monocrystalline GaN. It was found that mosaicity and biaxial tensile stress are still high in 1.7 μm GaN. Curvature radius measurement was also done and correlated to the cracks observations over the GaN surface. 相似文献
927.
K.E. Lee T.L. Phan N.D. Ha M.H. Phan S.C. Yu C.O. Kim 《Journal of magnetism and magnetic materials》2006
Influences of oxygen-partial pressure and annealing on the electrical and magnetic properties of CoFeAlO thin films were systematically investigated by means of resistivity, permeability, magnetization and ferromagnetic resonance (FMR) measurements. It was found that, with increasing oxygen-partial pressure or under annealing, the electrical resistivity of the film increased and the magnetic softness decreased, which is attributed to the microstructural change of the film. Interestingly, an as-deposited Co45.30Fe20.65Al19.34O14.71 film was found to exhibit an inverted hysteresis loop with negative coercivity, and this peculiar phenomenon disappeared upon effects of oxygen-partial pressure and annealing. It was also found that the as-deposited films owned a narrow FMR line width that increased with increasing oxygen-partial pressure or under annealing. 相似文献
928.
W. Gao M. Li R. Klie E.I. Altman 《Journal of Electron Spectroscopy and Related Phenomena》2006,150(2-3):136-149
Oxide catalysts are frequently used to convert toxic species to environmentally benign molecules, and to prevent the formation of toxic species in the first place. In this paper, growth and characterization of model oxide systems employed in both approaches is discussed. An example of the former approach is the selective catalytic reduction (SCR) of NO emitted from power plants by NH3, which employs tungsten and vanadium oxides supported on the anatase polymorph of TiO2. To model SCR catalysts, epitaxial titanium, vanadium and tungsten oxide films were grown using molecular beam epitaxy and magnetron sputtering. Two different anatase orientations were grown on LaAlO3 substrates and their interactions with vanadia were characterized. On LaAlO3 (0 0 1), anatase exposed a (4 × 1) reconstructed (0 0 1) surface. Vanadia lifted the reconstruction and at 1 ML a (1 × 1) surface with mostly V5+ was observed. Continued V2O5 growth led to loss of order, but at high temperatures epitaxial VO2 could be grown; vanadia behaved similarly on anatase films on LaAlO3 (1 1 0). Results suggested that the monolayer is pseudomorphic with O adsorption oxidizing the surface V to 5+, since the anatase structure cannot accommodate more bulk oxygen, only a monolayer can be pseudomorphic and have only V5+. Thus the vanadia monolayer has unique structural and chemical properties that can help explain why vanadia monolayers on TiO2 are much more active than bulk V2O5. For WO3, a series of added row reconstructions were observed as the epitaxial films were reduced. The effect of these structures on surface chemistry was characterized by studying 1-propanol adsorption. The results indicated that the structure of the WO3 surface did not alter its catalytic function but had a strong effect on reaction kinetics. As an example of a system where catalysts prevent the formation of toxic species, the reactivity of oxidized Pd surfaces used in CH4 catalytic combustion were studied. An ordered PdO-like monolayer was found to be less reactive towards CO than adsorbed O on Pd. On the other hand, the PdO layer favored a lower activation energy C3H6 oxidation pathway. The results indicated that Pd oxidation reduces the sticking coefficient of reactive species but once molecules adsorb, the oxide surface can reduce the activation energy for subsequent reaction. 相似文献
929.
The possibility that pairs of quarks will form diquark clusters in the regime above deconfinement transition for hadron matter
at finite density is revisited. Here we present the results on the diquark-diquark (dq-dq) interaction in the framework of
constituent quark model taking account of spin, isospin and color degrees of freedom in the spirit of generalized Pauli principle.
By constructing the appropriate spin and color states of the dq-dq clusters we compute the expectation values of the interaction
Hamiltonian involving pairwise quark—quark interaction. We find that the effective interaction between two diquark clusters
is quite sensitive to different configurations characterized by color and spin states, obtained after the coupling of two
diquark states. The value of the coupling parameter for a particular color—spin state, i.e., -3, 1 is compared to the one
obtained earlier by Donoghue and Sateesh,Phys. Rev.
D38, 360 (1988) based on the effective Φ4-theory. This new value of λ derived for different color-spin dq-dq states, may lead to several important implications in
the studies of diquark star and diquark gas. 相似文献
930.
V Ravindran Pankaj Agrawal Rahul Basu Satyaki Bhattacharya J Blümlein V Del Duca R Harlander D Kosower Prakash Mathews Anurag Tripathi 《Pramana》2006,67(5):983-992
This is the report of the subgroup QCD of Working Group-4 at WHEPP-9. We present the activities that had taken place in the
subgroup and report some of the partial results arrived at following the discussion at the working group meetings. 相似文献