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31.
Forty four stationary points have been located on the lowest singlet and triplet potential energy surfaces of S(2)N(2). Ten minima and ten saddle points on the lowest singlet surface and eleven minima and thirteen saddle points on the lowest triplet surface were found. All saddle points were connected to minima or lower-order saddle points by following the intrinsic reaction coordinate. Renner-Teller effects in the linear isomers were studied by examining their bending curves. The S(2)N(2) polymerization mechanism was investigated by first locating the transition state corresponding to ring opening and then considering all species connected to it that are close in energy. The commonly accepted mechanism is problematic due to the number of species that would lead to dissociation to SN + SN. Other possible isomers that are consistent with the experimental evidence but do not connect to SN radicals in the dissociation limit were examined. A mechanism of polymerization to (SN)(x)() is proposed that involves excitation of the square planar singlet molecule to the triplet surface. The triplet species then undergoes a puckering, and polymerization occurs in a direction approximately perpendicular to the S(2)N(2) plane. Consideration of the predicted vibrational frequencies suggests the structure of the second isomer of S(2)N(2). This isomer has a trans-NSSN structure with a long SS bond. The energetics of trans-NSSN are consistent with the observed temperature effects in the dimerization of SN. Analysis of the bending curves of linear NSSN and NSNS indicates that trans-NSSN is the only isomer which has a small yet significant barrier to that dimerization. 相似文献
32.
Vanderford BJ Mawhinney DB Trenholm RA Zeigler-Holady JC Snyder SA 《Analytical and bioanalytical chemistry》2011,399(6):2227-2234
Proper collection and preservation techniques are necessary to ensure sample integrity and maintain the stability of analytes
until analysis. Data from improperly collected and preserved samples could lead to faulty conclusions and misinterpretation
of the occurrence and fate of the compounds being studied. Because contaminants of emerging concern, such as pharmaceuticals
and personal care products (PPCPs) and steroids, generally occur in surface and drinking water at ng/L levels, these compounds
in particular require such protocols to accurately assess their concentrations. In this study, sample bottle types, residual
oxidant quenching agents, preservation agents, and hold times were assessed for 21 PPCPs and steroids in surface water and
finished drinking water. Amber glass bottles were found to have the least effect on target analyte concentrations, while high-density
polyethylene bottles had the most impact. Ascorbic acid, sodium thiosulfate, and sodium sulfite were determined to be acceptable
quenching agents and preservation with sodium azide at 4 °C led to the stability of the most target compounds. A combination
of amber glass bottles, ascorbic acid, and sodium azide preserved analyte concentrations for 28 days in the tested matrices
when held at 4 °C. Samples without a preservation agent were determined to be stable for all but two of the analytes when
stored in amber glass bottles at 4 °C for 72 h. Results suggest that if improper protocols are utilized, reported concentrations
of target PPCPs and steroids may be inaccurate. 相似文献
33.
Valeri V. Mossine Charles L. Barnes Thomas P. Mawhinney 《Journal of carbohydrate chemistry》2013,32(4):249-266
Nano n-propylsulfonated γ-Fe2O3 was found to be a highly efficient, reusable heterogeneous catalyst for the conversion of a range of monosaccharides and some of their derivatives to the corresponding O-isopropylidene derivatives in good to excellent yields by refluxing the reaction mixture in dry acetone. The magnetic property of the catalyst enabled its separation from the reaction mixture by a simple process of filtration along with the aid of an external magnet. The efficiency of the catalyst was found to be largely unaffected for at least up to six cycles of reuse, thus proving the new methodology to be environmentally rewarding besides being simple and facile in operation. 相似文献