Techniques for Mitigating the Effects of Smoke Taint While Maintaining Quality in Wine Production: A Review

Smoke taint has become a prominent issue for the global wine industry as climate change continues to impact the length and extremity of fire seasons around the world. Although the issue has prompted a surge in research on the subject in recent years, no singular solution has yet been identified that is capable of maintaining the quality of wine made from smoke-affected grapes. In this review, we summarize the main research on smoke taint, the key discoveries, as well as the prevailing uncertainties. We also examine methods for mitigating smoke taint in the vineyard, in the winery, and post production. We assess the effectiveness of remediation methods (proposed and actual) based on available research. Our findings are in agreement with previous studies, suggesting that the most viable remedies for smoke taint are still the commercially available activated carbon fining and reverse osmosis treatments, but that the quality of the final treated wines is fundamentally dependent on the initial severity of the taint. In this review, suggestions for future studies are introduced for improving our understanding of methods that have thus far only been preliminarily investigated. We select regions that have already been subjected to severe wildfires, and therefore subjected to smoke taint (particularly Australia and California) as a case study to inform other wine-producing countries that will likely be impacted in the future and suggest specific data collection and policy implementation actions that should be taken, even in countries that have not yet been impacted by smoke taint. Ultimately, we streamline the available information on the topic of smoke taint, apply it to a global perspective that considers the various stakeholders involved, and provide a launching point for further research on the topic.     

Transport Efficiency of Continuous-Time Quantum Walks on Graphs

Continuous-time quantum walk describes the propagation of a quantum particle (or an excitation) evolving continuously in time on a graph. As such, it provides a natural framework for modeling transport processes, e.g., in light-harvesting systems. In particular, the transport properties strongly depend on the initial state and specific features of the graph under investigation. In this paper, we address the role of graph topology, and investigate the transport properties of graphs with different regularity, symmetry, and connectivity. We neglect disorder and decoherence, and assume a single trap vertex that is accountable for the loss processes. In particular, for each graph, we analytically determine the subspace of states having maximum transport efficiency. Our results provide a set of benchmarks for environment-assisted quantum transport, and suggest that connectivity is a poor indicator for transport efficiency. Indeed, we observe some specific correlations between transport efficiency and connectivity for certain graphs, but, in general, they are uncorrelated.     

Allylic and Allenylic Dearomatization of Indoles Promoted by Graphene Oxide by Covalent Grafting Activation Mode

The site-selective allylative and allenylative dearomatization of indoles with alcohols was performed under carbocatalytic regime in the presence of graphene oxide (GO, 10 wt % loading) as the promoter. Metal-free conditions, absence of stoichiometric additive, environmentally friendly conditions (H₂O/CH₃CN, 55 °C, 6 h), broad substrate scope (33 examples, yield up to 92 %) and excellent site- and stereoselectivity characterize the present methodology. Moreover, a covalent activation model exerted by GO functionalities was corroborated by spectroscopic, experimental and computational evidences. Recovering and regeneration of the GO catalyst through simple acidic treatment was also documented.     

Deuterium-depleted water: A new tracer to label pulmonary surfactant lipids in adult rabbits

Stable isotope tracing can be safely used for metabolic studies in animals and humans. The endogenous biosynthesis of lipids (lipogenesis) is a key process throughout the entire life but especially during brain and lung growth. Adequate synthesis of pulmonary surfactant lipids is indispensable for life. With this study, we report the use of deuterium-depleted water (DDW), suitable for human consumption, as metabolic precursor for lipogenesis. We studied 13 adult rabbits for 5 days. Four rabbits drank tap water (TW) and served as controls; in four animals, DDW was substituted to drinking water, whereas five drank deuterium-enriched water (DEW). After 5 days, a blood sample and a bronchoalveolar lavage (BAL) sample were collected. The ²H/¹H (δ²H) of BAL palmitic acid (PA) desaturated phosphatidylcholine (DSPC), the major phospholipid of pulmonary surfactant, and of plasma water was determined by high-resolution mass spectrometry. We found that the δ²H values of DDW, DEW and TW were −984 ± 2‰, +757 ± 2‰ and −58 ± 1‰, respectively. After 5 days, plasma water values were −467 ± 87‰, +377 ± 56‰ and −53 ± 6‰, and BAL DSPC-PA was −401 ± 27‰, −96 ± 38‰ and −249 ± 9‰ in the DDW, DEW and TW, respectively. With this preliminary study, we demonstrated the feasibility of using DDW to label pulmonary surfactant lipids. This novel approach can be used in animals and in humans, and we speculate that it could be associated with more favourable study compliance than DEW in human studies.     

Ferrous to Ferric Transition in Fe-Phthalocyanine Driven by NO2 Exposure

Due to its unique magnetic properties offered by the open-shell electronic structure of the central metal ion, and for being an effective catalyst in a wide variety of reactions, iron phthalocyanine has drawn significant interest from the scientific community. Nevertheless, upon surface deposition, the magnetic properties of the molecular layer can be significantly affected by the coupling occurring at the interface, and the more reactive the surface, the stronger is the impact on the spin state. Here, we show that on Cu(100), indeed, the strong hybridization between the Fe d-states of FePc and the sp-band of the copper substrate modifies the charge distribution in the molecule, significantly influencing the magnetic properties of the iron ion. The Fe^II ion is stabilized in the low singlet spin state (S=0), leading to the complete quenching of the molecule magnetic moment. By exploiting the FePc/Cu(100) interface, we demonstrate that NO₂ dissociation can be used to gradually change the magnetic properties of the iron ion, by trimming the gas dosage. For lower doses, the FePc film is decoupled from the copper substrate, restoring the gas phase triplet spin state (S=1). A higher dose induces the transition from ferrous to ferric phthalocyanine, in its intermediate spin state, with enhanced magnetic moment due to the interaction with the atomic ligands. Remarkably, in this way, three different spin configurations have been observed within the same metalorganic/metal interface by exposing it to different doses of NO₂ at room temperature.     

Recent trends and advances in microbial electrochemical sensing technologies: An overview

Microbial electrochemical systems utilize the electrochemical interaction between microorganisms and electrode surfaces to convert chemical energy into electrical energy, offering a promise as technologies for wastewater treatment, bioremediation, and biofuel production. Recently, growing research attention has been devoted to the development of microbial electrochemical sensrs as biosensing platforms. Microbial electrochemical sensors are a type of microbial electrochemical technology (MET) capable of sensing through the anodic or the cathodic electroactive microorganisms and/or biofilms. Herein, we review and summarize the recent advances in the design of microbial electrochemical sensing approaches with a specific overview and discussion of anodic and cathodic microbial electrochemical sensor devices, highlighting both the advantages and disadvantages. Particular emphasis is given on the current trends and strategies in the design of low-cost, convenient, efficient, and high performing METs with different biosensing applications, including toxicity monitoring, pathogen detection, corrosion monitoring, as well as measurements of biological oxygen demand, chemical oxygen demand, and dissolved oxygen. The conclusion provides perspectives and an outlook to understand the shortcomings in the design, development status, and sensing applications of microbial electrochemical platforms. Namely, we discuss key challenges that limit the practical implementation of METs for sensing purposes and deliberate potential solutions, necessary developments, and improvements in the field.     

Bromine-Promoted Glycosidation of Conformationally Superarmed Thioglycosides

Presented herein is a study of the conformation and reactivity of highly reactive thioglycoside donors. The structural studies have been conducted using NMR spectroscopy and computational methods. The reactivity of these donors has been investigated in bromine-promoted glycosylations of aliphatic and sugar alcohols. Swift reaction times, high yields, and respectable 1,2-cis stereoselectivity were observed in a majority of these glycosylations.