全文获取类型
收费全文 | 3034篇 |
免费 | 109篇 |
国内免费 | 7篇 |
专业分类
化学 | 2313篇 |
晶体学 | 42篇 |
力学 | 33篇 |
数学 | 115篇 |
物理学 | 647篇 |
出版年
2022年 | 19篇 |
2021年 | 23篇 |
2020年 | 26篇 |
2019年 | 54篇 |
2018年 | 23篇 |
2017年 | 16篇 |
2016年 | 62篇 |
2015年 | 57篇 |
2014年 | 73篇 |
2013年 | 186篇 |
2012年 | 155篇 |
2011年 | 186篇 |
2010年 | 110篇 |
2009年 | 88篇 |
2008年 | 168篇 |
2007年 | 183篇 |
2006年 | 185篇 |
2005年 | 191篇 |
2004年 | 175篇 |
2003年 | 150篇 |
2002年 | 122篇 |
2001年 | 53篇 |
2000年 | 64篇 |
1999年 | 45篇 |
1998年 | 49篇 |
1997年 | 38篇 |
1996年 | 32篇 |
1995年 | 30篇 |
1994年 | 24篇 |
1993年 | 31篇 |
1992年 | 41篇 |
1991年 | 33篇 |
1990年 | 16篇 |
1989年 | 14篇 |
1988年 | 18篇 |
1987年 | 16篇 |
1986年 | 15篇 |
1985年 | 39篇 |
1984年 | 36篇 |
1983年 | 20篇 |
1982年 | 23篇 |
1981年 | 33篇 |
1980年 | 20篇 |
1979年 | 34篇 |
1978年 | 29篇 |
1977年 | 22篇 |
1976年 | 15篇 |
1975年 | 19篇 |
1974年 | 21篇 |
1969年 | 12篇 |
排序方式: 共有3150条查询结果,搜索用时 93 毫秒
11.
Infrared and nuclear magnetic resonance (NMR) spectroscopies have been applied for quantitative comparison on unsaturated bonds in tetrafluoroethylene (TFE)-propylene (P)-vinylidene fluoride (VdF) terpolymers. These spectroscopies have led to consistent results while they are based on completely different principles. It is shown that the absolute concentration can be evaluated from NMR measurements. The behavior of unsaturation has been discussed in terms of after-treatment such as wet and dry treatments. The result obtained here can give the important information to improve the performance of fluoroelastomer based on TFE-P-VdF terpolymers. 相似文献
12.
Statistical Inference for Stochastic Processes - 相似文献
13.
We have investigated the transient characteristics of discrete Raman Amplifiers and found that the response time caused by gain saturation is dependent upon the wavelength, which corresponds to the effective length of the pump light. 相似文献
14.
A membrane filtration method was examined concerning the effective collection of iron(III) from a homogeneous aqueous solution with Chromazurol B (CAB), one of the triphenylmethane dyes, as a precipitating reagent in the presence of a non-ionic surfactant, polyethylene glycol mono[4-(1,1,3,3-tetramethylbutyl)phenyl]ether (Triton X-100). A formed blue Fe(III)-CAB complex was collected as a precipitate on a membrane filter by filtration under suction from a homogeneous aqueous solution in the pH range over about 2. The original solution was prepared at a concentration ratio of CAB to Fe(III) of to 10, and that of Triton X-100 to CAB of 10 to 100. It was then adjusted to a pH value of between 1.0 and 6.5. A linear relationship (r = 0.999) was obtained between the initial concentration and the found one of Fe(III) in the range of 2.0 x 10(-5) to 4.0 x 10(-4) mol dm(-3) at a fixed concentration ratio of CAB to Fe(III) of 3 and that of Triton X-100 to CAB of 20. This membrane filtration with CAB and Triton X-100 may be utilized for the separation of Fe(III) as a background species. 相似文献
15.
Mauel M.E. Warren H.H. Hasegawa A. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1992,20(6):626-630
A new laboratory terrella has been constructed in order to study collisionless radial diffusion of particles trapped within a dipole magnetic field. Columbia's collisionless terrella experiment (CTX) aims to reproduce the process of wave-induced radial transport and does not try to simulate magnetospheric structure. The first experiment planned for CTX is the direct measurement of stochastic radial diffusion induced from wave-particle drift resonances. The motivation for the CTX experiment is described, and the procedures to be used to measure the intensity and spectrum of fluctuations generating chaos, the rate of radial transport, and the evolution of the density and pressure profiles are illustrated. Because of the success of similar experiments conducted earlier in a long thin magnetic mirror, these dipole experiments can be performed with a high degree of confidence. An example from these earlier experiments is presented 相似文献
16.
K. Niume K. Toyofuku F. Toda K. Uno M. Hasegawa Y. Iwakura 《Journal of polymer science. Part A, Polymer chemistry》1982,20(3):663-673
Polybenzimidazoles that contained anthracene photodimer were prepared. The molecular weights of the polymers prepared by the photopolymerization of bis-anthrylbenzimidazoles were limited by the precipitation of the resulting polymers from the reaction organic solvents. Higher molecular weight polymers were obtained by the photopolymerization of bis-anthryl-Schiff's bases, followed by the oxidation of the resulting polymers. These polymers were soluble in acidic solvents such as formic and sulfuric acids but were insoluble in organic solvents. 相似文献
17.
Masayuki Kuzuya Akihiro Noguchi Hideki Ito Shin-Ichi Kondo Nahoko Noda 《Journal of polymer science. Part A, Polymer chemistry》1991,29(1):1-7
Plasma-induced polystyrene radicals were first studied by electron spin resonance (ESR). The room temperature ESR spectrum was compared with those obtained by γ-irradiation, UV-irradiation, and mechanical fracture. It was found that even less than a few seconds of plasma-irradiation gave rise to a large amount of polystyrene radicals and the ESR spectrum consisted of two types of spectra, a triplet and a single broad line. The spectral feature of the triplet was nearly identical with that of γ-irradiated polystyrene. Thus, it was assigned to the structure of a cyclohexadienyl-type radical formed by a nearly random addition of a hydrogen atom to the aromatic ring. The single broad line, thought to be an outline of multicomponent spectrum, was assigned to an immobilized dangling-bond sites at the plasma-induced crosslinked portion of the polystyrene surface. 相似文献
18.
Koji Hasegawa 《Communications in Mathematical Physics》1997,187(2):289-325
For Belavin's elliptic quantum R-matrix, we construct an L-operator as a set of difference operators acting on functions on
the type A weight space. According to the fundamental relation RLL=LLR, taking the trace of the L-operator gives a set of commuting difference operators. We show that for the above mentioned L-operator
this approach gives Macdonald type operators with elliptic theta function coefficient, actually equivalent to Ruijsenaars'
operators. The relationship between the difference L-operator and Krichever's Lax matrix is given, and an explicit formula
for elliptic commuting differential operators is derived. We also study the invariant subspace for the system which is spanned
by symmetric theta functions on the weight space.
Received: 27 December 1995 / Accepted: 11 November 1996 相似文献
19.
Homologous series of 2-alkoxycarbonyl-4-(4-ethoxyphenylazo)phenyl 4-methoxybenzoates (L) and their orthopalladated μ-chloro dimers (Pd2Cl2L2) have been synthesized and their thermotropic phase transition behaviour has been characterized. The ligands, L, are three-ring nematogens with their central rings substituted in the 2-position by n-alkyl chains of varied length. The thermal stability of the nematic phases decreases rapidly with increasing side chain length and then levels off as the series is ascended. In every case the mesomorphic phase appears only over a small temperature range (less than 20° C). The orthopalladated species also proved to be nematogenic. Melting and clearing points rise on the average by 87° C and 126° C, respectively, and thus the temperature ranges of the nematic phases are enlarged considerably upon metallation. In relation to the observed stabilization of the nematic phases, particularly of higher homologues, a lath-like molecular structure, in which the side chains of the ligands fill up the clefts of the core part, has been deduced for a Pd2Cl2L2 homologue from its solution 1H-NMR spectrum. 相似文献
20.
Haitao Yang Tomoyuki Ogawa Daiji Hasegawa C.N. Chinnasamy Migaku Takahashi 《Journal of magnetism and magnetic materials》2006
Monodisperse bimetallic Pd–Co nanoparticles were prepared via a thermal decomposition of cobalt carbonyl using palladium seeds at the Pd/Co molar ratios 0.5%, 1%, and 5%. The heterogeneously nucleated nanoparticles without any size-selective precipitation are sufficiently uniform to self-assemble into ordered arrays. The as-synthesized nanoparticles are each a single crystal with a complex cubic structure called ε-Co. The presence of Pd seeds seems to improve the stability of Co nanoparticles against oxidation based on the results from time-dependent magnetization measurement. 相似文献