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31.
Enantioselective Construction of Silicon‐Stereogenic Silanes by Scandium‐Catalyzed Intermolecular Alkene Hydrosilylation 下载免费PDF全文
Dr. Gu Zhan Dr. Huai‐Long Teng Dr. Yong Luo Dr. Shao‐Jie Lou Dr. Masayoshi Nishiura Prof. Dr. Zhaomin Hou 《Angewandte Chemie (International ed. in English)》2018,57(38):12342-12346
The catalytic asymmetric construction of silicon‐stereogenic silanes is of great interest and significance, but has met with only limited success to date. We herein report the enantioselective hydrosilylation of alkenes with dihydrosilanes by a chiral half‐sandwich scandium catalyst, which constitutes an efficient and general route for the synthesis of a wide range of enantioenriched silicon‐stereogenic silanes from easily accessible starting materials. This reaction features a broad substrate scope, high yields, and high enantioselectivity. Some of the chiral tertiary silane products were also converted into valuable derivatives, such as chiral silanol, quaternary silane, and benzosilole compounds. 相似文献
32.
Masayoshi Takeda 《Proceedings of the American Mathematical Society》2006,134(9):2729-2738
For symmetric -stable processes, an analytic criterion for a measure being gaugeable was obtained by Z.-Q. Chen (2002), M. Takeda (2002) and M. Takeda and T. Uemura (2004). Applying it, we consider the ultracontractivity of Feynman-Kac semigroups and expectations of the number of branches hitting closed sets in branching symmetric -stable processes.
33.
Ryosuke Hyakuna Masayoshi Tsutsumi 《NoDEA : Nonlinear Differential Equations and Applications》2011,18(3):309-327
We consider the Cauchy problem for the nonlinear Schrödinger equations $ \begin{array}{l} iu_t + \triangle u \pm |u|^{p-1}u =0, \qquad x \in \mathbb{R}^d, \quad t \in \mathbb{R} \\ u(x,0)= u_0(x), \qquad x \in \mathbb{R}^d \end{array} $ for 1 < p < 1 + 4/d and prove that there is a ${\rho (p ,d) \in (1,2)}We consider the Cauchy problem for the nonlinear Schr?dinger equations
l iut + \triangle u ±|u|p-1u = 0, x ? \mathbbRd, t ? \mathbbR u(x,0) = u0(x), x ? \mathbbRd \begin{array}{l} iu_t + \triangle u \pm |u|^{p-1}u =0, \qquad x \in \mathbb{R}^d, \quad t \in \mathbb{R} \\ u(x,0)= u_0(x), \qquad x \in \mathbb{R}^d \end{array} 相似文献
34.
Tetsuji Ohata Akira Matsumoto Masayoshi Oiwa 《Journal of polymer science. Part A, Polymer chemistry》1980,18(2):467-475
In order to elucidate the effect of the hydroxyl group on the polymerization of diallyl hydroxydicarboxylates, we investigated in detail the radical polymerizations of diallyl succinate (DASu), diallyl malate (DAMa), and diallyl tartrate (DATa), each of which have similar structure differing only in the number of hydroxyl groups present. The rate of polymerization (Rp) was quite enhanced in the order DASu < DAMa < DATa, in accord with the increase in the number of hydroxyl groups within a monomer unit. The enhanced ability of the allylic monomer radical to reinitiate chain growth was also in the same order, as was clear from the dependence of Rp on the initiator concentration. The dependence of the residual unsaturation of the polymer on the monomer concentration in the polymerizations of DAMa and DATa was abnormal in terms of cyclopolymerization. These results are discussed in connection with the formation of the intermolecular hydrogen bond through the hydroxyl groups. 相似文献
35.
Tetsuji Ohata Etsuro Fukumori Akira Matsumoto Masayoshi Oiwa 《Journal of polymer science. Part A, Polymer chemistry》1980,18(3):1011-1019
The radical copolymerization of diallyl tartrate (DATa) (M1) with diallyl succinate (DASu), diallyl phthalate (DAP), allyl benzoate (ABz), vinyl acetate (VAc), or styrene (St) was investigated in order to disclose in more detail the characteristic hydroxyl group's effect observed in the homopolymerization of DATa. In the copolymerization with DASu or DAP as a typical diallyldicarboxylate, the dependence of the rate of copolymerization on monomer composition was different for different copolymerization systems and unusual values larger than unity for the product of monomer reactivity ratios, r1r2, were obtained. In the copolymerization with ABz or VAc (M2), the r1 and r2 values were estimated to be 1.50 and 0.64 for the DATa/ABz system and 0.76 and 2.34 for the DATa/VAc system, respectively; the product r1r2 for the latter copolymerization system was found again to be larger than unity. In the copolymerization with St, the largest effect due to DATa monomer of high polarity was observed. Solvent effects were tentatively examined to improve the copolymerizability of DATa. These results are discussed in terms of hydrogen-bonding ability of DATa. 相似文献
36.
Polymerization of allyl esters of unsaturated acids. V. Cyclopolymerization of methyl allyl fumarate
Kunio Urushido Akira Matsumoto Masayoshi Oiwa 《Journal of polymer science. Part A, Polymer chemistry》1980,18(6):1771-1785
The kinetics of radical polymerization of methyl allyl fumarate (MAF) is discussed in terms of cyclopolymerization and compared with the polymerization results of methyl allyl maleate (MAM) as a cis isomer. In the polymerization of MAF, the rate and degree of polymerization were quite enhanced compared with MAM, and gelation occurred at low conversion. The content of the unreacted allylic double bonds of the MAF polymer was quite large; whereas those of the unreacted fumaric double bonds and the cyclic structural units showed reverse tendencies. Only a slight presence of a five-membered ring was observed in the MAF polymer. The cyclization constants KA and KV, the ratios of the rate constants of the unimolecular cyclization reaction to those of the bimolecular propagation reaction of the uncyclized allylic and fumaric radicals, were estimated to be 2.73 and 1.48 mole/liter, respectively. These values suggest the great difference in the cyclopolymerization behavior between two isomeric monomers. These results are discussed in detail in connection with the high reactivity of the fumaric double bond compared to the maleic double bond. In addition, the formation mode and the sequence distribution of the structural units of the polymer produced are discussed on the basis of these analytical results. Thus, for the MAF polymer obtained in the bulk polymerization, about 60% of the cyclic structure can be formed via the intramolecular attack of the uncyclized fumaric radical on the allylic double bond, as opposed to the case of MAM via the predominant intramolecular attack (ca. 90%) of the uncyclized allylic radical on the maleic double bond; these results and the low probability for the succession of cyclic structures and the rather high probability of a vinyl-to-vinyl addition are presented. 相似文献
37.
Masayoshi Yoshikawa 《代数通讯》2013,41(5):2046-2060
We will investigate the structure of noncommutative imprimitive association schemes of rank 6 and the representation of their adjacency algebras. From this investigation, we will construct new integral standard generalized table algebras with three parameters. These algebras are noncommutative, imprimitive, and 6-dimensional. 相似文献
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40.
The effects of drawing temperature on the physical and mechanical properties of poly(p-phenylene sulfide) have been studied. A melt-quenched film was drawn by solid-state coextrusion both below (75°C) and above (95 and 110°C) the glass transition temperature Tg (85°C) of PPS. The maximum extrusion draw ratio (EDRmax) increased from 3.4 to 5.6 with increasing extrusion temperature Te from 75 to 110°C. It was found that extrusion drawing just above the Tg of PPS (95°C) produced more stress-induced crystals. A high efficiency of draw in the amorphous region was achieved by extrusion at Te-75°C. The tensile modulus at EDRmax decreased from 5.1 to 3.5 GPa with increasing Te from 75 to 110°C. The low efficiency of draw for the samples extruded at 110°C is explained in terms of disentanglement and chain slippage during drawing due to a less effective network. 相似文献
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