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991.
Masato Miyake Hiroshi Nagai Makoto Shirai Ryuichiro Kurane Yasuo Asada 《Applied biochemistry and biotechnology》1999,77(1-3):267-275
A 2.5 kb high-copy-number plasmid, pM A4 in thermophilic cyanobacterium Synechococcus sp. M A4 was isolated and characterized to develop a genetic engineering system for thermophilic cyanobacteria. The copy
number of pM A4 was determined to be by densitometry about 350/cell. The pM A4 may be a type of rolling-circle plasmid, because
a possible rep gene encoding 34 k D-protein and a consensus sequence of a double-stranded origin nick site of rolling circle plasmids were
found in the pM A4 sequence. The pM A4 was electro-introduced into another thermophile, Synechococcus sp. MA 19, which is the strongest poly-β-hydroxybutyrate (PHB) accumulator in photoau totrophic organisms. The pM A4 was
incorporated and retained in MA 19. These results indicate that pM A4 could be developed as a useful vector for thermophilic
cyanobacteria. 相似文献
992.
Masaaki Sakai Masato Ueda Norio Miyaura 《Angewandte Chemie (International ed. in English)》1998,37(23):3279-3281
Highly inert to ionic additions to aldehydes , aryl- and 1-alkenylboronic acids succumb to a catalytic variant mediated by a [Rh(acac)(CO)2]–diphosphane complex in aqueous phase at 80–95°C to yield secondary alcohols [Eq. (a)]. A key step in the catalytic cycle is the transmetalation between the boron reagent and the rhodium complex. Ln=diphosphane (e.g. 1,1′-bis(diphenylphosphanyl)ferrocene); R=aryl, 1-alkenyl; R′=alkyl, aryl; acac=acetylacetonate. 相似文献
993.
Shigeo Nakamura Masato Amano 《Journal of polymer science. Part A, Polymer chemistry》1997,35(16):3359-3363
Nitrogen-containing cellulose derivatives hydrazinodeoxycellulose (HDC) and carboxyalkyl hydrazinodeoxycelluloses (α- and β-CAHDCs) were prepared from 6-chlorodeoxycellulose (CDC). Their adsorption of divalent transition metal ions was determined from dilute aqueous solutions and compared with that of aminoalkyl celluloses (AmACs) reported previously. HDC scarcely adsorbs metal ions in the pH range of 1–2, whereas α- and β-CAHDCs adsorb metal ions in this pH range. However, the adsorption of metal ions on HDC increases rapidly with increasing pH and HDC more effectively adsorbs metal ions than α- and β-CAHDCs in weakly acidic conditions. The ability to adsorb Cu2+ ions was in the order of AmAC (carbon number in the diamine moiety m = 2) > HDC > α-CAHDC > β-CAHDC in the weakly acidic region. These adsorbents selectively adsorb Cu2+ ions from the solutions containing other metal ions such as Mn2+, Co2+, and Ni2+, and the Irving–Williams series is obeyed in these adsorbent/metal ion systems. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35 : 3359–3363, 1997 相似文献
994.
β‐Cyclodextrin (β‐CD) derivatives 1 with an amino group at C(6), C(3), or C(2) were homogeneously linked together by an ethylenediaminetetraacetic acid (EDTA) bridge (Scheme). Coordination of the linker to metal ions and cooperation of the dual cavities of 3 in binding hydrophobic guests were properly demonstrated by NMR techniques and a fluorescence‐based titration method, respectively. The hydrolysis of bis(4‐nitrophenyl) phosphate (BNPP) in the presence of CeIV complexes of β‐CD dimers 3 was tens of millionfold faster than that in the absence of the CeIV complexes. Hydrophobic binding of the β‐CD cavities was estimated to contribute to the catalysis by a factor of up to 520, and the type of modified sugar unit and the bridging positions influenced this cooperation between the β‐CD moieties and the catalytic metal center. 相似文献
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999.
Masato Suzuki Osamu Numata Tomofumi Shimazaki 《Macromolecular rapid communications》2001,22(16):1354-1357
It has been disclosed for the first time that a cyclodextrin (CD) derivative is able to act as a macrocyclic monomer for ring‐opening polymerization to produce linear polyglucan. O‐Permethylated α‐, β‐, and γ‐CDs were found to be polymerizable with the aid of a cationic initiator, e.g., Et3O+PF6– in dichloromethane. Interestingly, the more strained monomer (α‐ > β‐ > γ‐CD) was less reactive, which is ascribable to the characteristic shape of the CD molecule. 相似文献
1000.