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961.
Xavier Gerbaux Armand Hadni Masato Tazawa 《International Journal of Infrared and Millimeter Waves》1996,17(4):693-704
We have studied the Far Infrared transmission spectra of an MgO plate covered with an YBaCuO film of thickness t=200 Å, at different temperatures. By cooling from room temperature to temperatures < 140 K, the Far Infrared interference fringes are displaced by half a period. Explanation in terms of different adaptations of the YBaCuO sheet resistance to the MgO substrate impedance during cooling. 相似文献
962.
Kakihana Masato Okubo Toru Arima Momoko Nakamura Yoshiyuki Yashima Masatomo Yoshimura Masahiro 《Journal of Sol-Gel Science and Technology》1998,12(2):95-109
Powders of SrTiO3 were prepared by the Pechini-type polymerized complex technique, wherein a mixed solution of citric acid (CA), ethylene glycol (EG), Sr and Ti ions with a molar ratio of CA/EG/Sr/Ti = 10/40/1/1 was polymerized at 130°C to produce a yellowish transparent polyester-type resin without undergoing precipitation, which after decomposition on heating at 350°C was used as a powder precursor for SrTiO3. The formation of pure perovskite SrTiO3 practically free from carbonates occurred when the powder precursor was heat treated at temperatures higher than 500°C in static air. No X-ray diffraction and Raman spectroscopic evidence for phase separation of crystalline SrCO3 and TiO2 as distinct intermediates has been obtained during the thermal decomposition of the powder precursor, suggesting the molecular-scale mixing of cations in the Sr-Ti powder precursor. 13C-NMR spectroscopic measurements have indicated that unusual alkoxylation of CA occurred exclusively when both strontium and titanium ions in equal amounts coexist in CA/EG solutions, the phenomenon of which was discussed in connection with possible formation of a Sr-Ti heterometallic CA complex. The number of CA participating in formation of (Sr, Ti)-CAn was estimated to be n 3 from the variation of 13C-NMR spectra with relative concentrations of metal ions and CA. This heterometallic complex was thermally stable in CA/EG solutions upon heating at 130°C, implying that the molecular-level homogeneity achieved in the Sr/Ti precursor solution was preserved throughout the polymerization process. 相似文献
963.
Masato Tomiyama 《Journal of Algebraic Combinatorics》1998,7(2):197-220
Let be a distance-regular graph with diameter
and height
, where
. Suppose that for every in and every in
, the induced subgraph on
is isomorphic to a complete multipartite graph
with
. Then
and is isomorphic to the Johnson graph
. 相似文献
964.
Yamamura Y Shimoi H Sumita M Yasuzuka S Adachi K Fuyuhiro A Kawata S Saito K 《The journal of physical chemistry. A》2008,112(19):4465-4469
The heat capacity of [Hdamel]2[Cu(II)(tdpd)2] x 2 THF was measured from 6 to 250 K by adiabatic calorimetry. There are four heat anomalies around 150 K associated with disordering in the orientation of the uncoordinated THF molecules and in the conformation of the out-of-plane allyl groups of [Hdamel](+) units. The total entropy of transition was determined to be 19.8 J K(-1) mol(-1), less than the 4R ln 2 (R = gas constant) expected from the crystal structure at room temperature. The smallness of the total entropy change on phase transitions proves the presence of the strong motional correlation between the adjacent allyl groups. The calorimetric conclusion agreed with the crystal structure at 200 K re-examined in this study. 相似文献
965.
Photo-responsive gel droplet as a nano- or pico-litre container comprising a supramolecular hydrogel
Matsumoto S Yamaguchi S Wada A Matsui T Ikeda M Hamachi I 《Chemical communications (Cambridge, England)》2008,(13):1545-1547
Photo-responsive gel droplets having nano- or pico-L volume that showed photo-induced gel-sol transition were successfully developed, for which the inter-droplet mass transport and the subsequent enzymatic reactions in the interior of the gel droplets were photo-triggered. 相似文献
966.
Metal ion induced allosteric transition in the catalytic activity of an artificial phosphodiesterase
An artificial phosphodiesterase () bearing two types of metal binding sites, a catalytic site and a regulatory bipyridine site showed a unique allosteric transition in the catalytic activity against the metal concentration. The rate constants for the hydrolysis reaction of 2-hydroxypropyl-p-nitrophenyl phosphate (HPNP) and RNA dimer (ApA) with and without an effector metal ion were evaluated; the k(obs) value of HPNP hydrolysis for .(Zn(2+))(3) (2.0 x 10(-4) s(-1)) is 3.3 times larger than that for .(Zn(2+))(2). In the case of and Cu(2+), a 19.4 times larger k(obs) value was obtained for .(Cu(2+))(3) (1.2 x 10(-3) s(-1)) against .(Cu(2+))(2). The increase in the catalytic activity is ascribed to the allosteric conformational transition of induced by the coordination of effector metal ion to the Bpy moiety. A detailed investigation revealed that a conformational change of induced by the third M(2+) complexation enhances the rate of hydrolysis rather than a change in the substrate affinity. 相似文献
967.
Total synthesis of salvinorin A (1), a neoclerodane diterpenoid having the most potent hallucinogenic activity and a selective kappa-opioid agonist, was completed in 20 steps starting from enantiomerically pure hydroxy-Wieland-Miescher ketone 5. 相似文献
968.
Induction of Optical Activity in an Oligothiophene Synchronized with pH‐Sensitive Folding of Amylose
Control of the helical sense in α‐sexithiophene (6T) through pH‐responsive wrapping with left‐handed‐helical amylose is demonstrated. A change in pH of the medium caused a significant conformational change in amylose as the host polymer, which resulted in either supramolecular complexation with 6T as the guest molecule to induce optical activity or decomplexation leading to loss of optical activity. Furthermore, we observed that chirality reversal in 6T does not require hosts of opposite helical chirality, but can be made possible simply by taking advantage of the pH sensitivity of the amylose folding, which is dependent on the pH history of the aqueous medium. In helical amylose, 6T assumes a clockwise‐twisted conformation when the pH is changed from acidic to neutral, but assumes an anticlockwise‐twisted conformation when the aqueous solution is acidified from very basic conditions. 相似文献
969.
The SUSY CP problem is one of serious problems in construction of realistic supersymmetric standard models. We consider the problem in a framework in which adjoint chiral multiplets are introduced and gauginos have Dirac mass terms induced by a U(1) gauge interaction in the hidden sector. This is realized in hidden sector models without singlet chiral multiplets, which are favored from a recent study of the Polonyi problem. We find that the dominant contributions to electron and neutron electric dipole moments (EDMs) in the model come from phases in the supersymmetric adjoint mass terms. When the supersymmetric adjoint masses are suppressed by a factor of ∼100 compared with the Dirac ones, the electron and neutron EDMs are suppressed below the experimental bound even if the SUSY particle masses are around 1 TeV. Thus, this model works as a framework to solve the SUSY CP problem. 相似文献
970.
Zhou J Takeuchi M Ray AK Anpo M Zhao XS 《Journal of colloid and interface science》2007,311(2):497-501
An ion-implantation method was used to prepare V-ion-implanted P25 TiO2 photocatalysts. Their photocatalytic activity for the degradation of formic acid under visible light irradiation (lambda>450 nm) was investigated. Upon implantation of V ions into the lattice of P25 TiO2, the photoactivity was remarkably enhanced. HRTEM images showed that the implanted V ions existed in the form of VO2(T) in the lattice of P25 TiO2. The intensity of photoluminescence (PL) spectra of V-ion-implanted P25 TiO2 decreased with the increase of the amount of implanted V ions, indicating the decrease of electron-hole pair recombination. It was also observed that the lower the PL intensity of V-ion-implanted P25 TiO2, the higher the photoactivity. 相似文献