Purealin,a novel enzyme activator from the Okinawan marine sponge Psammaplysilla purea

Purealin , a novel secondary metabolite, which modurates enzymic reactions of ATPases, has been isolated from the okinawan marine sponge $\text{Psammaplysilla}$$\text{purea}$ and the structure has been determined by the ¹H-¹H homonuclear and ¹H-¹³C heteronuclear NMR chemical shift correlations and CD spectra.     

Electron scattering by a ring-shaped barrier in magnetic fields

We investigate the transport phenomena through a region containing a ring-shaped barrier in a quasi-one-dimensional quantum wire in magnetic fields. The calculated magnetoconductance curve shows a periodic dip structure, which is superimposed upon by another quasi-periodic dip structure. The current distributions for resonant states and the magnetoconductance features are well explained on the basis of the magnetic field dependence of the eigenvalue in the two-dimensional system.     

Investigations of morphology, purity and crystal defects of the InN pillar crystals prepared by means of halide chemical vapor deposition under atmospheric pressure

Indium nitride prepared under atmospheric pressure using a halide chemical vapor deposition method has been examined by means of a variety of analytical techniques. Scanning electron microscopic observations showed that the crystals deposited onto a Si(100) substrate have hexagonal pillar structure. Based on the X-ray diffraction and X-ray pole-figure analyses, it was deduced that each InN pillar crystal grows with a different rotation angle around the 〈001〉 axis. Transmission electron diffraction showed that they are of single-like form. This was also confirmed by the selected area electron diffraction image as well.     

Scattering function for wormlike chains with finite thickness

The particle scattering function P(k) is approximately evaluated for the Kratky–Porod wormlike chain with a circular cross section to examine the effect of chain diameter d on the scattering curve of k²P(k) versus k, the magnitude of the scattering vector, for stiff chains and also the applicability of the cross‐section plot of ln[kP(k)] versus k² to them. In the evaluation, series expansions from the rod and coil limits up to the fifth‐order and third‐order deviations, respectively, are combined together. The major results or conclusions derived are as follows. First, the conventional equation, P(k) = P₀(k) exp(?k²d²/16), for straight cylinders overestimates k²P(k) at relatively large values of k, whereas its alternative, P(k) = P₀(k)[2J₁(kd/2)/(kd/2)]², is a good approximation to exact P(k) unless contour length L is shorter than 10d. Here, P₀(k) denotes the scattering function for the chain contour, and J₁(x) is the Bessel function of the first order. Second, as d is increased for a fixed value of L (relative to the Kuhn segment length), the k²P(k)–k curve lowers with a pronounced maximum, and the peak position shifts to a lower scattering angle. Third, if the chain is somewhat flexible, the cross‐section plot has an approximately linear region, with a slope fairly close to ?d²/16 expected from the aforementioned conventional equation. This plot for rods appreciably bends down, and thus the experimental observation of an approximately linear relation (over a wide k range) implies that, in contrast to the prevailing notion, the polymer examined is not completely rigid but instead is somewhat flexible. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1398–1407, 2004     

Structures and chromatographic characteristics of capsule-type silica gels coated with hydrophobic polymers in reversed-phase liquid chromatography

Summary Silicone polymer-coated silica gels modified with octadecyl and octyl groups (S/S-C₁₈, S/S-C₈), or “capsule-type silica gels” were developed as packing materials for reversed-phase liquid chromatography. They were obtained by coating the surface of totally porous silica gel with a homogeneous silicone polymer film, and thereafter modifying the coating polymer with octadecyl or octyl groups. Retaining the advantages of silica-based packings, they show strong resistance of alkali-like organic porous polymeric materials.     

Palladium-catalyzed addition of nitrogen pronucleophiles to alkylidenecyclopropanes

The inter- and intramolecular additions of cyclic amides (nitrogen pronucleophiles) to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh(3))(4), affording the corresponding hydroamination products in good to high yields with high regioselectivities. The ring opening of methylenecyclopropanes occurred at the distal position of the cyclopropane ring.