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81.
82.
A familyF of subsets is calledk-dense if there exists ak-element setA such that all 2
k
of its subsets can be obtained in the formAF for someFF. Best possible bounds are obtained for the maximum number of sets in notk-densek-partite families. This is a consequence of a new rank formula for inclusion matrices. 相似文献
83.
Isao Watanabe Kusuo Nishiyama Kanetada Nagamine Kenji Kawano Ken-ichi Kumagai 《Hyperfine Interactions》1994,86(1):603-608
Zero field positive muon spin rotation method (
+SR) is applied on La2–x
Sr
x
CuO4 around forx=0.12 at which the high-T
c
superconductivity (SC) is suppressed. The magnetically ordered state of Cu-moments, which is not a spin glass state but an antiferromagnetic like state, appears below 15 K for 0.105x0.120. The magnetic phase boundary is very similar to the one of the La2–x
Ba
x
CuO4 in which the structural transition from the low temperature orthorhombic (LTO) phase to the low temperature tetragonal (LTT) phase is observed aroundx=0.12. The present study suggests that there is no big difference of the electronic state of the CuO2 plane between the La-Ba system and the La-Sr system and that the magnetic ordering of Cu-moments plays an important role for the suppression of the high-T
c
SC aroundx=0.12 in both of the systems, although the LTO-LTT structural transition has not been observed yet in the La-Sr system. 相似文献
84.
85.
Changes in the fluorescence intensity of polyanions bearing 4-acryloylbenzo-18-crown-6 units on the addition of cations were studied in a mixed solvent of methanol and water at 30°C. The sensitivity of the change in fluorescence intensities of the polymers toward cations was strongly enhanced compared to that of the corresponding model compound. When alkali metal cations were added, the fluorescence intensity of the polymers decreased in the orders Li+>Na+>Cs+>Rb+>K+ in a methanol-water (19) mixture and Li+>Na+>Rb+>K+Cs+ in a methanol-water (91) mixture. Alkaline earth metal cations and alkylamine hydrochlorides decreased the fluorescence intensity of the polymers in a methanol-water (19) mixture. The cation-dependent decrease in the fluorescence intensity of the polymers was affected by the water fraction in a mixed solvent of methanol and water. 相似文献
86.
87.
88.
Inoue IH Watanabe M Kinoshita T Kakizaki A Kato R Kobayashi A Kobayashi H Fujimori A 《Physical review. B, Condensed matter》1993,47(19):12917-12920
89.
Wataru Ueda Damian Vitry Tomokazu Kato Nobufumi Watanabe Yusuke Endo 《Research on Chemical Intermediates》2006,32(3-4):217-233
Mo-V-O-based complex metal oxide catalysts were synthesized hydrothermally for the first time, characterized structurally and tested in the selective oxidation of propane to acrylic acid, and the results obtained were compared on the basis of catalyst crystal structures in order to clarify key aspects of alkane selective oxidation over multifunctional metal oxide catalysts. The catalysts tested were black solids of rod-shaped crystals, which had a layer structure in the direction of fiber axis and various high dimensional arrangements of metal octahedra in the cross-section plane. A strong dependency on the octahedra arrangements and a facet dependency were observed, and the roles of metal elements in the course of selective oxidation of propane were clarified by comparing the catalytic performance of various Mo-V-O-based catalysts. We discuss the multi-functional character derived from high dimensional structures of the catalysts and mechanism of the selective oxidation of propane. 相似文献
90.
Kondo F Saito H Hayashi R Onda H Kobayashi S Matsumoto M Suzuki M Ito Y Oka H Nakanishi T Shimizu A 《The Analyst》2003,128(11):1360-1364
We developed a rapid and reliable identification method for Shiga toxins in Shiga toxin-producing Escherichia coli (STEC) using immunoprecipitation and high-performance liquid chromatography-electrospray ionization mass spectrometry (HPLC-ESI-MS). Polyclonal antisera specific for Shiga toxin 1 (Stx1) and Shiga toxin 2 (Stx2) were raised in rabbits so as to be used for the immunoprecipitation. The immunoprecipitaion was carried out by mixing sample solutions with 50 microl each of the antisera to Stx1 and Stx2 followed by allowing the mixed solutions to stand for 30 min. The quantity required to obtain the immunoprecipitate was more than 0.5 microg of Shiga toxins. HPLC-ESI-MS analysis of the resulting immunoprecipitates provided accurate molecular weight information on Shiga toxins, leading to direct evidence for the presence of these toxins. It requires at most two days to perform our procedure from toxin extraction to measurement of HPLC-ESI-MS whereas the previous method using isolation procedures required about two weeks to complete. The usefulness of the present method has been demonstrated by identifying Stx1, Stx2 and a variant of Stx2 (Stx2e) in the immunoprecipitates prepared from STEC strains. 相似文献