Synthesis,crystal structures,spectral, electrochemical and magnetic properties of di-µ-phenoxido-bridged dinuclear copper(II) complexes with N-salicylidene-2-hydroxybenzylamine derivatives: axial coordination effect of dimethyl sulphoxide molecule

The template reaction of salicylaldehyde and its substituted derivatives and 2-hydroxy-5-bromobenzylamine or 2-hydroxy-5-chlorobenzylamine with copper(II) acetate in dimethyl sulphoxide (dmso) afforded eight dinuclear Cu(II) complexes, [Cu₂(L)₂(dmso)₂] (H₂ L = N-salicylidene-2-hydroxy-5-bromobenzylamine, N-salicylidene-2-hydroxy-5-chlorobenzylamine and their 5-bromo, 5-nitro and 5-methyl-substituted salicylidene derivatives). These Cu(II) complexes were characterised by IR and UV-VIS-NIR spectroscopy, electric conductivity, cyclic voltammetry, and temperature dependence of magnetic susceptibilities (4.5–300 K). In the THF solution, the complexes are nonelectrolytes and exhibit a characteristic CT band due to phenoxido-bridging at 360–384 nm. In the cyclic voltammograms, an irreversible reduction process was observed at ?1.18–1.54 V vs Fc/Fc⁺. Single-crystal X-ray crystallography revealed that two Cu(II) ions were bridged by the two phenoxido-oxygen atoms of the two Schiff-base ligands with axial coordination of dmso molecules forming a square pyramid with a Cu-Cu distance of 3.0628(8)–3.0931(6) °A. In accordance with the crystal structures, the magnetic interaction between the two Cu(II) ions is relatively anti-ferromagnetic with ?2J value of 386–575 cm^?1. The axial coordination effect of the dmso molecule was discussed in relation to the correlation between the Cu-O-Cu angle and the ?2J value.     

Numerical simulation of shock propagation in a polydisperse bubbly liquid

The effect of distributed bubble nuclei sizes on shock propagation in a bubbly liquid is numerically investigated. An ensemble-averaged technique is employed to derive the statistically averaged conservation laws for polydisperse bubbly flows. A finite-volume method is developed to solve the continuum bubbly flow equations coupled to a single-bubble-dynamic equation that incorporates the effects of heat transfer, liquid viscosity and compressibility. The one-dimensional shock computations reveal that the distribution of equilibrium bubble sizes leads to an apparent damping of the averaged shock dynamics due to phase cancellations in oscillations of the different-sized bubbles. If the distribution is sufficiently broad, the phase cancellation effect can dominate over the single-bubble-dynamic dissipation and the averaged shock profile is smoothed out.     

(2S,3R,4S,5R,6S)‐6‐Benzyl­oxy­methyl‐4‐(methoxy­methyloxy)‐9‐oxo‐8‐oxa‐1‐aza­bi­cyclo­[4.3.0]­nonane‐2,3,5‐triyl tri­acetate

The relative configuration of the title compound, C₂₃H₂₉NO₁₁, prepared in a synthetic study on the natural product sphingofungin E, has been determined. The six‐membered ring adopts a chair form and the five substituents are all axial.     

Enhancement of Chiroptical Responses of trans-Bis[(β-iminomethyl)naphthoxy]platinum(II) Complexes with Distorted Square Planar Coordination Geometry

The relationship between the coordination geometry and photophysical properties of trans-bis[(β-iminomethyl)naphthoxy]platinum(II) was investigated both experimentally and theoretically. A series of platinum(II) complexes with differently substituted iminomethyl groups were synthesized, and their photophysical properties were examined in solution, in the crystalline, and in the PMMA film-dispersed state, respectively (PMMA=poly(methyl methacrylate)). These complexes showed structure-dependent emission spectra, in which the color of the luminescence in the crystalline state varied over a range of about 40 nm depending on the specific bowl-shaped molecular structure. The chiral complexes with (R,R)- and (S,S)-configurations were found to have structure-dependent chiroptical properties both in solution and the PMMA film-dispersed state such that the intensity of circular dichroism (CD) and circularly polarized luminescence (CPL) were enhanced with bulky cyclic substituents at the nitrogen atoms. A theoretical study using density functional theory (DFT) and time-dependent (TD)-DFT calculations revealed that the enhancement of chiroptical responses is due to the amplification of the magnetic dipole moment caused by the distortion of the square planar geometry.     

Interfacial instability of a condensing vapor bubble in a subcooled liquid

The European Physical Journal Special Topics - A special attention is paid to the condensing and collapsing processes of vapor bubble injected into a subcooled pool. We try to extract the...     

A plastic scintillator film for an electron beam-excitation assisted optical microscope

Optical Review - A plastic scintillator film for use in an electron beam excitation-assisted (EXA) optical microscope is characterized. The thin film scatters an incident electron beam weakly and...     

ESR study of free radicals in mango

An electron spin resonance (ESR) spectroscopic study of radicals induced in irradiated fresh mangoes was performed. Mangoes in the fresh state were irradiated with γ-rays, lyophilized and then crushed into a powder. The ESR spectrum of the powder showed a strong main peak at g = 2.004 and a pair of peaks centered at the main peak. The main peak was detected from both flesh and skin specimens. This peak height gradually decreased during storage following irradiation. On the other hand, the side peaks showed a well-defined dose–response relationship even at 9 days post-irradiation. The side peaks therefore provide a useful means to define the irradiation of fresh mangoes.