全文获取类型
收费全文 | 11545篇 |
免费 | 314篇 |
国内免费 | 86篇 |
专业分类
化学 | 8285篇 |
晶体学 | 115篇 |
力学 | 231篇 |
数学 | 1512篇 |
物理学 | 1802篇 |
出版年
2023年 | 62篇 |
2022年 | 92篇 |
2021年 | 118篇 |
2020年 | 157篇 |
2019年 | 146篇 |
2018年 | 120篇 |
2017年 | 110篇 |
2016年 | 222篇 |
2015年 | 227篇 |
2014年 | 282篇 |
2013年 | 506篇 |
2012年 | 664篇 |
2011年 | 855篇 |
2010年 | 418篇 |
2009年 | 355篇 |
2008年 | 769篇 |
2007年 | 775篇 |
2006年 | 812篇 |
2005年 | 825篇 |
2004年 | 720篇 |
2003年 | 588篇 |
2002年 | 556篇 |
2001年 | 151篇 |
2000年 | 137篇 |
1999年 | 127篇 |
1998年 | 148篇 |
1997年 | 166篇 |
1996年 | 181篇 |
1995年 | 107篇 |
1994年 | 116篇 |
1993年 | 113篇 |
1992年 | 88篇 |
1991年 | 80篇 |
1990年 | 55篇 |
1989年 | 58篇 |
1988年 | 59篇 |
1987年 | 63篇 |
1986年 | 49篇 |
1985年 | 93篇 |
1984年 | 90篇 |
1983年 | 62篇 |
1982年 | 69篇 |
1981年 | 83篇 |
1980年 | 81篇 |
1979年 | 61篇 |
1978年 | 48篇 |
1977年 | 44篇 |
1976年 | 32篇 |
1975年 | 38篇 |
1973年 | 30篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
951.
Sunkyu Park David K. Johnson Claudia I. Ishizawa Philip A. Parilla Mark F. Davis 《Cellulose (London, England)》2009,16(4):641-647
The crystallinity index of cellulose is an important parameter to establish because of the effect this property has on the
utilization of cellulose as a material and as a feedstock for biofuels production. However, it has been found that the crystallinity
index varies significantly depending on the choice of instrument and data analysis technique applied to the measurement. We
introduce in this study a simple and straightforward method to evaluate the crystallinity index of cellulose. This novel method
was developed using solid state 13C NMR and subtraction of the spectrum of a standard amorphous cellulose. The crystallinity indexes of twelve different celluloses
were measured and the values from this method were compared with the values obtained by other existing methods, including
methods based on X-ray diffraction. An interesting observation was that the hydration of the celluloses increased their crystallinity
indexes by about 5%, suggesting that addition of water increased cellulose order for all the cellulose samples studied. 相似文献
952.
953.
954.
955.
Current models for pressure drop prediction of slug flow pneumatic conveying in a horizontal pipeline system assume some type of steady state conditions for prediction,which limits their capability for increased predictive accuracy relative to experimental data.This is partly because of the nature of slug flow pneumatic conveying system,which,as a dynamic system,never becomes stable.By utilising conservation of mass (airflow),a dynamic pressure analysis model is proposed on the basis of the derivative of the upstream pressure behaviour.The rate of air permeation through slug,one of the important factors in the conservation model,is expressed as a function of a slug permeability factor.Other factors such as slug velocity,slug length and the fraction of stationary layer were also considered.Several test materials were conveyed in single-slug tests to verify the proposed pressure drop model,showing good agreement between the model and experimental results. 相似文献
956.
We consider a new class of estimators for volatility functionals in the setting of frequently observed Itō diffusions which are disturbed by i.i.d. noise. These statistics extend the approach of pre-averaging as a general method for the estimation of the integrated volatility in the presence of microstructure noise and are closely related to the original concept of bipower variation in the no-noise case. We show that this approach provides efficient estimators for a large class of integrated powers of volatility and prove the associated (stable) central limit theorems. In a more general Itō semimartingale framework this method can be used to define both estimators for the entire quadratic variation of the underlying process and jump-robust estimators which are consistent for various functionals of volatility. As a by-product we obtain a simple test for the presence of jumps in the underlying semimartingale. 相似文献
957.
In this paper we present a central limit theorem for general functions of the increments of Brownian semimartingales. This provides a natural extension of the results derived in [O.E. Barndorff-Nielsen, S.E. Graversen, J. Jacod, M. Podolskij, N. Shephard, A central limit theorem for realised power and bipower variations of continuous semimartingales, in: From Stochastic Analysis to Mathematical Finance, Festschrift for Albert Shiryaev, Springer, 2006], where the central limit theorem was shown for even functions. We prove an infeasible central limit theorem for general functions and state some assumptions under which a feasible version of our results can be obtained. Finally, we present some examples from the literature to which our theory can be applied. 相似文献
958.
A series of di-, tri-, and tetra-tetrazoloalkanes were synthesized from the corresponding nitrile and sodium azide. These were alkylated to give hydroxy terminated chains for possible use as high energy oligomers. 相似文献
959.
960.
The synthesis of two light-fluorous TEMPO derivatives is reported, along with their application in oxidation reactions. 相似文献