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51.
Laila Rubab Sumbal Afroz Sajjad Ahmad Saddam Hussain Iram Nawaz Ali Irfan Fozia Batool Katarzyna Kotwica-Mojzych Mariusz Mojzych 《Molecules (Basel, Switzerland)》2022,27(5)
Coumarin is an important six-membered aromatic heterocyclic pharmacophore, widely distributed in natural products and synthetic molecules. The versatile and unique features of coumarin nucleus, in combination with privileged sulfonamide moiety, have enhanced the broad spectrum of biological activities. The research and development of coumarin, sulfonamide-based pharmacology, and medicinal chemistry have become active topics, and attracted the attention of medicinal chemists, pharmacists, and synthetic chemists. Coumarin sulfonamide compounds and analogs as clinical drugs have been used to cure various diseases with high therapeutic potency, which have shown their enormous development value. The diversified and wide array of biological activities such as anticancer, antibacterial, anti-fungal, antioxidant and anti-viral, etc. were displayed by diversified coumarin sulfonamides. The present systematic and comprehensive review in the current developments of synthesis and the medicinal chemistry of coumarin sulfonamide-based scaffolds give a whole range of therapeutics, especially in the field of oncology and carbonic anhydrase inhibitors. In the present review, various synthetic approaches, strategies, and methodologies involving effect of catalysts, the change of substrates, and the employment of various synthetic reaction conditions to obtain high yields is cited. 相似文献
52.
The Institute for Chemical Processing of Coal in Zabrze, Poland, organized a proficiency testing round to determine the mass fraction of ash, total sulfur and total carbon and the value of gross calorific value. Forty-four participants from Polish heat and power plants, research entities and independent laboratories reported results. The performance of the participants was evaluated using z and E n scores. Over 85 % of the participants reported satisfactory results indicating the high level of proficiency of the Polish laboratories in the field. 相似文献
53.
Christian Rein Steen Nissen Mariusz Grzelakowski Morten Meldal 《Journal of polymer science. Part A, Polymer chemistry》2016,54(13):2032-2039
A facile click chemistry method of immobilizing surface‐functionalized polymer vesicles on casted polymeric PAN substrates is described. Microporous PAN membranes were subjected to hydrochloric acid hydrolysis to obtain surface carboxylates. The carboxylic groups were activated with EDC/NHS‐solution and were then reacted with propargylamine to introduce alkyne groups for CuAAC reactions. The alkyne functionality of the modified membrane surface was verified by reaction with an azide functional click dye both before and after the immobilization of azide‐functionalized ABA vesicles. The efficient postfunctionalization of the membrane with alkyne allowed quantitative coverage of the membrane surface with a polymersome monolayer, as confirmed by immobilization of polymerzomes loaded with a fluorescent dye. Polymersome monolayers immobilized on alkyne functionalized PAN‐membranes were characterized by cryo‐SEM and monolayers were confirmed by atom force microscopy. These methods opens up new avenues for preparing membrane based filtration and sensor technologies. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2032–2039 相似文献
54.
[structure: see text] Crystal engineering of an organic ladder can be achieved with a T-shaped molecule, 4,4-bis(4'-hydroxyphenyl)-1-cyclohexanol, having three hydroxyl functionalities that can form O-H...O hydrogen-bonded helices. The topology of this network structure finds a parallel in three-connected coordination polymers. 相似文献
55.
Mariusz Rabus Saharon Shelah 《Proceedings of the American Mathematical Society》1999,127(9):2573-2581
For every uncountable cardinal there is a ccc Boolean algebra whose topological density is .
56.
Let E be an elliptic curve defined over a number field K, without complex multiplication, S a finite subset of E(K) and l a rational prime being good modulus for E/K. The main result of the paper asserts that if |S|l2+l and for almost all prime ideals P of K S contains an element R satisfying R mod P = lQ with QE(K/P) then S contains an element R which satisfies R=lQ with some QE(K). It improves the result of S.Wong [6], where the above statement is proved under the stronger assumption |S|l2. Moreover we show that the bound |S|l2+l is optimal. 相似文献
57.
58.
Nishizawa M Yadav VK Skwarczynski M Takao H Imagawa H Sugihara T 《Organic letters》2003,5(10):1609-1611
[reaction: see text] Hg(OTf)(2) exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. The present procedure should involve a sequence of mercuration of a terminal alkyne, carbocyclization, hydration, and protodemercuration that regenerates the catalyst. 相似文献
59.
Jenkinson Oliver; Gonzalez Luis Felipe; Urbanski Mariusz 《Proceedings London Mathematical Society》2003,86(3):755-778
For any non-empty subset I of the natural numbers, let I denotethose numbers in the unit interval whose continued fractiondigits all lie in I. Define the corresponding transfer operator
for , where Re (rß) = I is the abscissa of convergence of the series . When acting on a certain Hilbert space HI, rß, weshow that the operator LI, rß is conjugate to an integraloperator KI, rß. If furthermore rß is real,then KI, rß is selfadjoint, so that LI, rß: HI, rß HI, rß has purely real spectrum.It is proved that LI, rß also has purely real spectrumwhen acting on various Hilbert or Banach spaces of holomorphicfunctions, on the nuclear space C [0, 1], and on the Fréchetspace C [0, 1]. The analytic properties of the map rß LI, rßare investigated. For certain alphabets I of an arithmetic nature(for example, I = primes, I = squares, I an arithmetic progression,I the set of sums of two squares it is shown that rß LI, rß admits an analytic continuation beyond thehalf-plane Re rß > I. 2000 Mathematics SubjectClassification 37D35, 37D20, 30B70. 相似文献
60.
Urszula Koss Mariusz ?ukaszewski Katarzyna Hubkowska Andrzej Czerwi��ski 《Journal of Solid State Electrochemistry》2011,15(11-12):2477-2487
Hydrogen electrosorption into Pd-rich (>80?at.% Pd in the bulk) Pd?CRh alloys has been studied in acidic solutions (0.5?M H2SO4) using cyclic voltammetry and chronoamperometry. The influence of temperature (in the range between 283 and 328?K), electrode potential and alloy bulk composition on hydrogen electrosorption properties of Pd?CRh alloys is presented. It has been found that the additive of Rh to Pd?CRh alloys increases the maximum hydrogen solubility (for Rh bulk content below 10?at.%), decreases the potential of absorbed hydrogen oxidation peak and decreases the potential of the ???????? phase transition. Increasing temperature decreases the potential of absorbed hydrogen oxidation peak, the maximum hydrogen solubility, and the potential of the ???????? phase transition. The amounts of electrosorbed hydrogen for ??- and ??-phase boundaries, i.e., ??max and ??min, have been determined from the integration of the initial parts of current?Ctime responses in hydrogen absorption and desorption processes. The H/M ratio corresponding to ??max increases with increasing Rh content, while for ??min a maximum of H/M ratio is observed for the alloys containing ca. 95% Rh. 相似文献