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61.
62.
Reaction of ethoxymethylene-malonitrile and ethoxymethyleneethyl cyanoacetate, resp., with 4-hydroxy-2-pyridones (1a–b) and 4-hydroxy-2-quinolones (3a–b) leads to 2,5-dioxo-5,6-dihydro-2 H-pyrano[3,2-c]pyridine-(2a–d) and 2,5-dioxo-5,6-dihydro-pyrano[3.2-c]quinoline-derivatives (4a–d), resp.2a–d and4a–d exhibit remarkable visible fluorescence. Absorption- and emmission-data in different solvents are reported. 相似文献
63.
H. Schmidt 《Fresenius' Journal of Analytical Chemistry》1954,141(3):204
Ohne ZusammenfassungVgl. diese Z. 137, 129 (1952/53); 138, 118 (1953) 相似文献
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G. Münzenberg S. Hofmann H. Folger F. P. Heßberger J. Keller K. Poppensieker B. Quint W. Reisdorf K. H. Schmidt H. J. Schött P. Armbruster M. E. Leino R. Hingmann 《Zeitschrift für Physik A Hadrons and Nuclei》1985,322(2):227-235
In irradiations of207Pb and208Pb, respectively, with54Cr theα-decay of the isotopes259106,260106, and261106 could be observed for the first time. For260106 a spontaneous fission branch of (50 ?20 +30 )% was observed. The isotopes were identified by genetic relationships of α-decay after separation in-flight with the velocity filter SHIP and implantation into a position-sensitive silicon surface-barrier detector. The measured partial fission halflife of the doubly even isotope260106 of (7.2 ?2.7 +4.8 )ms exceeds the predicted values by at least a factor of 40. This result could be explained by the high shell corrections of the ground state mass, derived from the measured α-decay energies. The experimental results show evidence for an island of purely shell stabilized nuclei in the region of deformed isotopes beyond the actinides. 相似文献
67.
A. Bähring E. Meyer I. V. Hertel H. Schmidt 《Zeitschrift für Physik A Hadrons and Nuclei》1985,320(1):141-149
Pronounced polarization effects have been observed in inelastic collisions of laser state-prepared Na*(3p,M L) with Na+ leading to Na*(3d) for the energy rangeE CM=20–45 eV. Using linearly polarized light the dependence of the inelastic process on the alignment of the electronic charge cloud of the Na*(3p) prior to the collision has been measured. In studies with left and right hand circularly polarized light the angular momentum transferred in the collision process has been determined. The results are compared with similar data for the 3p→3s deexitation process studied previously [6]. The density matrix of the Na*(3p) state has been evaluated with respect to the collisional excitation to Na*(3d). Semiclassical calculations based on the coupled channel impact parameter approximation using pseudopotentials [7] and nonadiabatic rotational coupling elements for the Na 2 * system [12] have been performed. The agreement with the experimental results is good, in particular for the higher collision energies. 相似文献
68.
Preparation of Ceramic Powders. II. Mg2TiO4, MgTiO3, and MgTi2O5 Formed by Hydrolysis of 2-Ethoxyethylates Solutions of 2-ethoxyethylates of magnesium and titanium in 2-ethoxyethanol submitted to hydrolysis, evaporation and heating of the residue up to 450°C allow to prepare Mg2TiO4, MgTiO3, and MgTi2O5 in an amorphous state with smaller than 1% of volatile components. Highly dispersed powders showing an increased sintering activity are obtained as a result of recrystallization. Mg2TiO4 is formed as inverse spinel phase in a metastable state. 相似文献
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Dihydrothiinone 9a undergoes photocycloaddition regioselectively to all three C?C bonds of penta‐1,2,4‐triene ( 10 ), the relative stabilities of the biradical intermediates determining the product distribution. In contrast, cyclohexenone 9b and dihydropyranone 9c afford more complex mixtures of bicyclo[4.2.0]octanones, which also turn out to be less stable on chromatographic workup, reflecting the higher strain due to the shorter bond lengths (C? O and C? C vs. C? S) in the six‐membered rings, respectively. 相似文献