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841.
We describe a new and very accurate method for measuring as a function of temperature the solubility of very slightly soluble salts (≈ 10-5) in single crystals. The method is applied to the systems NaCl, Na2SO4 and KCl, K2SO4 and to the preparation of SO2-4 doped KCl single crystals. The parameters for diffusion of SO2-4 at infinite dilution into NaCl and KCl have been measured in the intrinsic range. 相似文献
842.
Kratochwil NA Malherbe P Lindemann L Ebeling M Hoener MC Mühlemann A Porter RH Stahl M Gerber PR 《Journal of chemical information and modeling》2005,45(5):1324-1336
G protein-coupled receptors (GPCRs) share a common architecture consisting of seven transmembrane (TM) domains. Various lines of evidence suggest that this fold provides a generic binding pocket within the TM region for hosting agonists, antagonists, and allosteric modulators. Here, a comprehensive and automated method allowing fast analysis and comparison of these putative binding pockets across the entire GPCR family is presented. The method relies on a robust alignment algorithm based on conservation indices, focusing on pharmacophore-like relationships between amino acids. Analysis of conservation patterns across the GPCR family and alignment to the rhodopsin X-ray structure allows the extraction of the amino acids lining the TM binding pocket in a so-called ligand binding pocket vector (LPV). In a second step, LPVs are translated to simple 3D receptor pharmacophore models, where each amino acid is represented by a single spherical pharmacophore feature and all atomic detail is omitted. Applications of the method include the assessment of selectivity issues, support of mutagenesis studies, and the derivation of rules for focused screening to identify chemical starting points in early drug discovery projects. Because of the coarseness of this 3D receptor pharmacophore model, however, meaningful scoring and ranking procedures of large sets of molecules are not justified. The LPV analysis of the trace amine-associated receptor family and its experimental validation is discussed as an example. The value of the 3D receptor model is demonstrated for a class C GPCR family, the metabotropic glutamate receptors. 相似文献
843.
We use Voiculescu’s concept of free probability to construct a completely isomorphic embedding of the operator space OH in the predual of a von Neumann algebra. We analyze the properties of this embedding and determine the operator space projection constant of OHn:
The lower estimate is a recent result of Pisier and Shlyakhtenko that improves an estimate of order 1/(1+lnn) of the author. The additional factor
indicates that the operator space OHn behaves differently than its classical counterpart
. We give an application of this formula to positive sesquilinear forms on
. This leads to logarithmic characterization of C*-algebras with the weak expectation property introduced by Lance. Mathematics Subject Classification (2000) 47L25 相似文献
844.
In this paper we extend previous results of Banach, Lamperti and Yeadon on isometries ofL
p-spaces to the non-tracial case first introduced by Haagerup. Specifically, we use operator space techniques and an extrapolation
argument to prove that every 2-isometryT:L
p(M) →L
p(N) between arbitrary noncommutativeL
p-spaces can always be written in the form
Here π is a normal *-isomorphism fromM onto the von Neumann subalgebra π(M) ofN,w is a partial isometry inN, andE is a normal conditional expectation fromN onto π(M). As a consequence of this, any 2-isometry is automatically a complete isometry and has completely contractively complemented
range.
The first and second authors were partially supported by the National Science Foundation DMS-0088928 and DMS-0140067. 相似文献
845.
Miclet E Williams Jr DC Clore GM Bryce DL Boisbouvier J Bax A 《Journal of the American Chemical Society》2004,126(34):10560-10570
A large fraction of hydrogens in proteins and nucleic acids is of the methylene type. Their detailed study, however, in terms of structure and dynamics by NMR spectroscopy is hampered by their fast relaxation properties, which give rise to low sensitivity and resolution. It is demonstrated that six different relaxation interference processes, involving 1H-13C and 1H-1H dipolar interactions and 1H and 13C chemical shift anisotropy, can be used simultaneously to mitigate these problems effectively. The approach is applicable to the majority of NMR experiments commonly used to study side chain and backbone conformation. For proteins, its efficiency is evaluated quantitatively for two samples: the third IgG-binding domain from Streptococcal Protein G and the protein calmodulin complexed with a 26-residue target peptide. Gains in both resolution and sensitivity by up to factors of 3.2 and 2.0, respectively, are observed for Gly residues at high magnetic field strengths, but even at much lower fields gains remain substantial. The resolution enhancement obtained for methylene groups makes possible a detailed analysis of spectral regions commonly considered inaccessible due to spectral crowding. For DNA, the high resolution now obtainable for C5' sites permits an H5'/H5'-based sequential NOE assignment procedure, complementary to the conventional base-H1'/H2'/H2' pathway. 相似文献
846.
We demonstrate a new class of frequency-entangled states generated via spontaneous parametric down-conversion under extended phase-matching conditions. Biphoton entanglement with coincident signal and idler frequencies is observed over a broad bandwidth in periodically poled KTiOPO4. We demonstrate high visibility in Hong-Ou-Mandel interferometric measurements under pulsed pumping without spectral filtering, which indicates excellent frequency indistinguishability between the down-converted photons. The coincident-frequency entanglement source is useful for quantum information processing and quantum measurement applications. 相似文献
847.
Marius Crainic 《Commentarii Mathematici Helvetici》2003,78(4):681-721
In the first section we discuss Morita invariance of
differentiable/algebroid cohomology.In the second section we extend the Van Est isomorphism to
groupoids. As a first application we clarify the connection
between differentiable and algebroid cohomology (proved in
degree 1, and conjectured in degree 2 by Weinstein-Xu
[50]). As a second application we extend Van Ests
argument for the integrability of Lie algebras. Applied to
Poisson manifolds, this immediately implies the integrability
criterion of Hector-Dazord [14].In the third section we describe the relevant characteristic classes of
representations, living in algebroid cohomology, as well as
their relation to the Van Est map. This extends
Evens-Lu-Weinsteins characteristic class $\theta_{L}$
[20] (hence, in particular, the modular class of Poisson
manifolds), and also the classical characteristic classes of
flat vector bundles [2, 30].In the last section we
describe applications to Poisson geometry. 相似文献
848.
We study the local operator space structure of nuclear C
*
-algebras. It is shown that a C
*
-algebra is nuclear if and only if it is an 𝒪ℒ∞,λ space for some (and actually for every) λ>6. The 𝒪ℒ∞ constant λ provides an interesting invariant
for nuclear C
*
-algebras. Indeed, if 𝒜 is a nuclear C
*
-algebra, then we have 1≤𝒪ℒ∞(𝒜)≤6, and if 𝒜 is a unital nuclear C
*
-algebra with , we show that 𝒜 must be stably finite. We also investigate the connection between the rigid 𝒪ℒ∞,1+ structure and the rigid complete order 𝒪ℒ∞,1+ structure on C
*
-algebras, where the latter structure has been studied by Blackadar and Kirchberg in their characterization of strong NF C
*
-algebras. Another main result of this paper is to show that these two local structrues are actually equivalent on unital
nuclear C
*
-algebras. We obtain this by showing that if a unital (nuclear) C
*
-algebra is a rigid 𝒪ℒ∞,1+ space, then it is inner quasi-diagonal, and thus is a strong NF algebra. It is also shown that if a unital (nuclear) C
*
-algebra is an 𝒪ℒ∞,1+ space, then it is quasi-diagonal, and thus is an NF algebra.
Received: 26 June 2001 / Revised version: 7 May 2002 / Published online: 10 February 2003
Mathematics Subject Classification (2000): 46L07, 46L05, 47L25
Junge and Ruan were partially supported by the National Science Foundation. Ozawa was supported by the Japanese Society for
Promotion of Science. 相似文献
849.
Cyclodipeptides containing L -Thr and L -His residues have been studied by 1H NMR in D2O and DMSO-d6. In the neutral form in D2O as in DMSO-d6, the folded form of the L -His residue is not unique. The diketopiperazine ring seems to be not strictly planar. 相似文献
850.
Sans résumé 相似文献