Effect of maltodextrins on the surface activity of small-molecule surfactants

We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na⁺), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed.     

A priori estimates for quasilinear degenerate parabolic equations

We prove some maximum and gradient estimates for classical solutions to a wide class of quasilinear degenerate parabolic equations, including first order ones. The proof is elementary and exploits the smallness of the domain in the time direction.

     

Internal standardization for the determination of cadmium,cobalt, chromium and manganese in saline produced water from petroleum industry by inductively coupled plasma optical emission spectrometry after cloud point extraction

In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L^− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L^− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰.     

Operator–valued Fourier multiplier theorems on Besov spaces

We investigate analytical properties of a measure geometric Laplacian which is given as the second derivative w.r.t. two atomless finite Borel measures μ and ν with compact supports supp μ ? supp ν on the real line. This class of operators includes a generalization of the well‐known Sturm‐Liouville operator as well as of the measure geometric Laplacian given by . We obtain for this differential operator under both Dirichlet and Neumann boundary conditions similar properties as known in the classical Lebesgue case for the euclidean Laplacian like Gauß‐Green‐formula, inversion formula, compactness of the resolvent and its kernel representation w.r.t. the corresponding Green function. Finally we prove nuclearity of the resolvent and give two representations of its trace.     

Vapor-liquid equilibrium data at 25°C for six binary systems containing methyl acetate or methanol,with dichloromethane,chloroform, or 1,2-trans-dichloroethylene

Isothermal vapor-liquid equilibrium (VLE) data, at 25° C were determined by a saturation method for each of the six methanol or methyl acetate binary systems with dichloromethane, chloroform, and 1,2-trans-dichloroethylene. The experimental data satisfy the Redlich-Kister consistency test, and were correlated with five Gibbs free energy models. All the binary mixtures of methanol with the chlorinated compounds exhibit strong positive deviations from ideality while the mixtures of methyl acetate with the chlorinated compounds present negative deviations from ideal behavior.Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60^th birthday, Clermont-Ferrand, France, 17–18 May 1990.     

New Ln[B6O9(OH)3] borates (Ln = Sm-Lu): Structure, properties, and structural relation to cationic Li4[B7O12]Cl conductors (Li-Boracites)

Crystals of new rare earth borates of the composition Ln[B₆O₉ (OH)₃] (Ln = Sm-Lu), sp. gr. R3c are synthesized under hydrothermal conditions. Their crystal structures are determined on single crystals with Ln = Ho, Gd without preliminary determination of their chemical formulas. The polar anionic framework of the crystals consists of BO₃ triangles and BO₄ tetrahedra and has wide channels along the threefold axis of the structure, which are similar to the channels along the a, b, and c axes in cubic Li₄[B₇O₁₂]Cl boracite with Li conductivity. Rare earth atoms are arranged in the structure over the cubic F pseudolattice, whereas the analogous positions in Li boracites are filled with Cl anions. The squared optical nonlinearity of the new crystals is comparable with the nonlinearity of quartz, whereas the electrical conductivity in borates at 300°C exceeds 10⁻⁶ S/cm. __________ Translated from Kristallografiya, Vol. 49, No. 4, 2004, pp. 681–691. Original Russian Text Copyright ? 2004 by Belokoneva, Ivanova, Stefanovich, Dimitrova, Kurazhkovskaya.     

Asymptotic stability of semigroups associated with linear weak dissipative systems with memory

We study the asymptotic behavior of the solutions of a class of linear dissipative integral differential equations. We show in the abstract setting a necessary and sufficient condition to get an exponential decay of the solution. In the case of the lack of exponential decay, we find the polynomial rate of decay of the solution. Some examples are given.     

Interpolation on spherical geodesic grids: A comparative study

Most operational models in atmospheric physics, meteorology and climatology nowadays adopt spherical geodesic grids and require “ad hoc” developed interpolation procedures. The author does a comparison between chosen representatives of linear, distance-based and cubic interpolation schemes outlining their advantages and drawbacks in this specific application field. Numerical experiments on a standard test problem, while confirming a good performance of linear and distance-based schemes in a single interpolation step, also show their minor accuracy with respect to the cubic scheme in the more realistic simulation of advection of a meteorological field.     

Harmonic and intermodulation distortion modeling in IM-DD multi-band radio over fiber links exploiting injection locked lasers

A comprehensive numerical tool has been developed for the evaluation of the performances of Radio over Fiber (RoF) links intended for wireless signal distribution.At the transmitter end an appropriate set of rate equations allows to model the optical source as a solitary laser or as an appropriately injection locked laser. The optical channel is modeled putting into account the combined effect of fiber dispersion, laser source non ideal performances (e.g. non-linear effects, frequency chirp), and quadratic detection of the receiving photodiode. The simulation model developed can be a useful tool at the design stage allowing a preliminary evaluation of the characteristics of real RoF links.     

Deformations of arithmetically Cohen-Macaulay subvarieties of pn

We show that every arithmetically Cohen-Macaulay two-codimensional subscheme ofP ⁿ can be deformed to a reduced union of two-codimensional linear subvarieties. This problem (classical for curves with the name of Zeuthen problem) was solved for curves by F.Gaeta.