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11.
We report what is believed to be the first demonstration of soft-x-ray interferometry of a plasma with a tabletop soft-x-ray laser. A Lloyd's mirror interferometer was used in combination with a very compact lambda = 46.9 nm capillary-discharge-pumped laser to map the electron density in the cathode region of a pinch plasma.  相似文献   
12.
C60 inclusion complexes in γ-cyclodextrin are studied by molecular mechanics and semi-empirical methods with the aim of comparing measured and calculated induced circular dichroism (ICD) spectra. Low energy geometries of the complexes are generated by Monte Carlo simulations, also accounting for solvation effects by an aqueous environment. The ICD spectrum of the complex is then obtained from an exciton model based on semi-empirical calculations of the transition energies and the corresponding transition moments. Highly symmetric, tightly bound complexes of two γ-cyclodextrins and buckminsterfullerene are found as the most probable structures. The main bands of the experimentally derived ICD spectrum are assigned to the excitation transitions of the chromophore and are discussed in comparison to calculations on the magnetic circular dichroism (MCD) spectrum of C60.  相似文献   
13.
The isotope shift in the proton magnetic resonance of deuteromethanes has been examined. By the use of Pople's formula for the chemical shift, it has been shown that the effect is due to vibronic coupling from the bending modes S4. The chemical shift was evaluated under the assumption that the hydrogen population is linearly dependent on the 2S character of the bonded carbon hybrid. Satisfactory agreement between theoretical and experimental results was obtained.  相似文献   
14.
We present clear experimental evidence showing that the contribution of bound electrons can dominate the index of refraction of laser-created plasmas at soft x-ray wavelengths. We report anomalous fringe shifts in soft x-ray laser interferograms of Al laser-created plasmas. The comparison of measured and simulated interferograms shows that this results from the dominant contribution of low charge ions to the index of refraction. This usually neglected bound electron contribution can affect the propagation of soft x-ray radiation in plasmas and the interferometric diagnostics of plasmas for many elements.  相似文献   
15.
We report saturated operation of an 18.9-nm laser at 5-Hz repetition rate. An amplification with a gain-length product GL of 15.5 is obtained in the 4d 1S0-4p 1P1 laser line of Ni-like Mo in plasmas heated at grazing incidence with approximately 1-J pulses of 8.1-ps duration from a tabletop laser system. Lasing is obtained over a broad range of time delays and pumping conditions. We also measure a GL of 13.5 in the 22.6-nm transition of the same ion. The results are of interest for numerous applications requiring high-repetition-rate lasers at wavelengths below 20 nm.  相似文献   
16.
Images with a spatial resolution of 120-150 nm were obtained with 46.9 nm light from a compact capillary-discharge laser by use of the combination of a Sc-Si multilayer-coated Schwarzschild condenser and a free-standing imaging zone plate. The results are relevant to the development of compact extreme-ultraviolet laser-based imaging tools for nanoscience and nanotechnology.  相似文献   
17.
We report the demonstration of an amplitude-division soft-x-ray interferometer that can be used to generate high-contrast interferograms at the wavelength of any of the saturated soft-x-ray lasers (5.6-46.9 nm) that are available at present. The interferometer, which utilizes grazing-incidence diffraction gratings as beam splitters in a modified Mach-Zehnder configuration, was used in combination with a tabletop 46.9-nm laser to probe a large-scale (~2.7-mm-long) laser-created plasma.  相似文献   
18.
Nitinol self-expanding stents are used for the endovascular management of peripheral artery diseases of the popliteal artery, which is located behind the knee joint. Unfortunately, the complex kinematics of the artery during the leg flexion leads to severe loading conditions, favouring the mechanical failure of the stent, calling for a specific biomechanical analysis. For this reason, in the present study we reconstruct by medical image analysis the patient-specific popliteal kinematics during leg flexion, which is subsequently exploited to compute the mechanical response of a stent model, virtually implanted in the artery by structural finite element analysis (FEA). The medical image analysis indicates a non-uniform configuration change of the artery during the leg flexion, leading to an increase of the vessel curvature above the knee. The computed mechanical response of the stent reflects the non-uniform configuration change of the artery as after the flexion the average stress is higher in the part of the stent located above the knee. Although the proposed analysis is limited to a case-study, it shows the capability of patient-specific FEA simulations to compute the mechanical response of a stent model subjected to the complex and severe loading conditions of the popliteal artery during leg flexion.  相似文献   
19.
We present the detailed analysis of the diffusive transport of spatially inhomogeneous fluid mixtures and the interplay between structural and dynamical properties varying on the atomic scale. The present treatment is based on different areas of liquid state theory, namely, kinetic and density functional theory and their implementation as an effective numerical method via the lattice Boltzmann approach. By combining the first two methods, it is possible to obtain a closed set of kinetic equations for the singlet phase space distribution functions of each species. The interactions among particles are considered within a self-consistent approximation and the resulting effective molecular fields are analyzed. We focus on multispecies diffusion in systems with short-range hard-core repulsion between particles of unequal sizes and weak attractive long-range interactions. As a result, the attractive part of the potential does not contribute explicitly to viscosity but to diffusivity and the thermodynamic properties. Finally, we obtain a practical scheme to solve the kinetic equations by employing a discretization procedure derived from the lattice Boltzmann approach. Within this framework, we present numerical data concerning the mutual diffusion properties both in the case of a quiescent bulk fluid and shear flow inducing Taylor dispersion.  相似文献   
20.
It is believed that the detection of gamma-ray bursts from evaporating primordial black holes is highly improbable in the near future since the expected photon flux, consisting mainly of photons with energies ≳ GeV, is too low. Contrary to this point of view, we show that a large fraction of the black hole power at the final stage of evaporation (the last 103 s) can be liberated as a burst of soft γ-ray emission of duration 10−1–103 s and luminosity 1028–1031 erg/s in the energy range 0.1–1 MeV. According to our calculations of the black hole evaporation rate (within the Standard Model of elementary particles), when the black hole temperature exceeds approximately 10 GeV, the charged particle outflow from a black hole forms a well-defined plasma and can be described in the hydrodynamic approximation. In this case more than half of the rest energy of a black hole can be converted into soft gamma-rays due to the presence of the magnetic field with energy density comparable to that of charged particles. We consider various mechanisms leading to such transformation and estimate their efficiency. It is shown that, at least, some of the gamma-ray bursts detected by BATSE can be associated with evaporating black holes. Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 41, No. 1, pp. 36–45, January, 1998.  相似文献   
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