Experimental and kinetic modeling study of tetralin: A naphtheno-aromatic fuel for gasoline,jet and diesel surrogates

Distillate fuels contain significant proportions of naphtheno-aromatic components and tetralin is a suitable surrogate component to represent this molecular moiety. The presence of aromatic and naphthyl rings makes kinetic modeling of tetralin very challenging. Primary radicals formed during the oxidation of tetralin can be aryl, benzylic or paraffinic in nature. Using available information on reaction paths and rate constants of naphthenes and alkyl-aromatics, a kinetic model of tetralin has been developed in the current study with emphasis on low-temperature chemistry and high-pressure conditions. Due to the lack of high-level quantum chemical calculations on reaction pathways of tetralin, analogous rates from ab-initio studies on benzylic and paraffinic radicals have been adopted here. Some modifications to the reaction rate rules are incorporated to account for the unique characteristics of tetralin's molecular structure. Important reaction channels have been identified using reaction path and brute force sensitivity analyses. In order to investigate the model performance at low temperatures, new experiments are carried out in a rapid compression machine on blends of tetralin and 3-methylpentane. Blending of low-reactivity tetralin with a high-reactivity alkane allowed the investigation of tetralin ignition at very low temperatures (665 – 856 K). The kinetic model developed in the current study is found to predict the current experiments and literature data adequately. The new model will aid in high-fidelity surrogate predictions at engine-relevant conditions.     

Landau quantization and spin polarization of cold magnetized quark matter

The magnetic field and density behaviors of various thermodynamic quantities of strange quark matter under compact star conditions are investigated in the framework of the thermodynamically self-consistent quasiparticle model. For individual species, a larger number density \begin{document}$ n_i $\end{document} leads to a larger magnetic field strength threshold that aligns all particles parallel or antiparallel to the magnetic field. Accordingly, in contrast to the finite baryon density effect which reduces the spin polarization of magnetized strange quark matter, the magnetic field effect leads to an enhancement of it. We also compute the sound velocity as a function of the baryon density and find the sound velocity shows an obvious oscillation with increasing density. Except for the oscillation, the sound velocity grows with increasing density, similar to the zero-magnetic field case, and approaches the conformal limit \begin{document}$ V_s^2=1/3 $\end{document} at high densities from below.     

Scaling in soft hadroproduction by positive projectiles in the range of 32–147 GeV/c

The total hadron multiplicity and the multiplicity in the three-jet events ine ⁺ e ^?-annihilation are considered. The formula for the total multiplicity (with account for the heavy quark contribution) agrees well with experiment. The value of the multiplicity for three-jet events is predicted.     

Sonochemical and sonophotocatalytic degradation of malachite green: the effect of carbon tetrachloride on reaction rates

A comparative study between the sonolytic, photocatalytic and sonophotocatalytic oxidation processes of aqueous solutions of malachite green was carried out in the presence of carbon tetrachloride, under a low power ultrasonic field (<15 W) and using titanium dioxide as a photocatalyst. The effect of a number of parameters such as ultrasonic intensity, TiO2 crystalline structure and the presence of CCl4 were studied using an inexpensive reactor. Enhanced rates of sonolytic degradation of malachite green in the presence of CCl4 were demonstrated. On the other hand, the simultaneous use of sonolysis and photocatalysis in the presence of CCl4 does not improve the degradation rate of malachite green in comparison with the one obtained using only sonolysis, but it makes possible a faster oxidative degradation of some reaction intermediaries. Finally, in air saturated solutions both processes, the sonolytic and the photocatalytic one, follow a first-order rate law.     

Switchable magnetic bottles and field gradients for particle traps

Versatile methods for the manipulation of individual quantum systems, such as confined particles, have become central elements in current developments in precision spectroscopy, frequency standards, quantum information processing, quantum simulation, and alike. For atomic and some subatomic particles, both neutral and charged, a precise control of magnetic fields is essential. In this paper, we discuss possibilities for the creation of specific magnetic field configurations which find application in these areas. In particular, we pursue the idea of a magnetic bottle which can be switched on and off by transition between the normal and the superconducting phase of a suitable material in cryogenic environments, for example, in trap experiments in moderate magnetic fields. Methods for a fine-tuning of the magnetic field and its linear and quadratic components in a trap are presented together with possible applications.     

Nonspecular total internal reflection of spatial solitons at the interface between highly birefringent media

We investigate total internal reflection of nonlocal spatial optical solitons at the interface between two differently oriented regions of a highly birefringent nematic liquid crystal. The solitons survive the interaction with an induced index mismatch and undergo nonspecular reflection, with an emerging angle differing appreciably from the incidence angle.     

Limit Cycles Bifurcating from a k-dimensional Isochronous Center Contained in ?n with k ? n

The goal of this paper is double. First, we illustrate a method for studying the bifurcation of limit cycles from the continuum periodic orbits of a k-dimensional isochronous center contained in ℝ ⁿ with n ⩾ k, when we perturb it in a class of differential systems. The method is based in the averaging theory. Second, we consider a particular polynomial differential system in the plane having a center and a non-rational first integral. Then we study the bifurcation of limit cycles from the periodic orbits of this center when we perturb it in the class of all polynomial differential systems of a given degree. As far as we know this is one of the first examples that this study can be made for a polynomial differential system having a center and a non-rational first integral. The first and third authors are partially supported by a MCYT/FEDER grant MTM2005-06098-C01, and by a CIRIT grant number 2005SGR-00550. The second author is partially supported by a FAPESP–BRAZIL grant 10246-2. The first two authors are also supported by the joint project CAPES–MECD grant HBP2003-0017.     

The Maxwell tensor for the Liénard-Wiechert field as an exact divergence

A potential for the bounded part of the Maxwell tensor associated to the Liénard-Wiechert field has been obtained by van Weert. In this paper we explicitly derive the non-local potential for the radiative part of such a tensor.