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Luís Antônio Dantas Silva Fernanda Vieira Teixeira Raphael Caixeta Serpa Najla Locatelli Esteves Rayane Ramos dos Santos Eliana Martins Lima Marcílio Sérgio Soares da Cunha-Filho Adriano Antunes de Souza Araújo Stephânia Fleury Taveira Ricardo Neves Marreto 《Journal of Thermal Analysis and Calorimetry》2016,123(3):2337-2344
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Julia Calatayud Juan Carlos Corts Marc Jornet 《Mathematical Methods in the Applied Sciences》2019,42(18):7259-7267
In this paper, we address the problem of approximating the probability density function of the following random logistic differential equation: P′(t,ω)=A(t,ω)(1?P(t,ω))P(t,ω), t∈[t0,T], P(t0,ω)=P0(ω), where ω is any outcome in the sample space Ω. In the recent contribution [Cortés, JC, et al. Commun Nonlinear Sci Numer Simulat 2019; 72: 121–138], the authors imposed conditions on the diffusion coefficient A(t) and on the initial condition P0 to approximate the density function f1(p,t) of P(t): A(t) is expressed as a Karhunen–Loève expansion with absolutely continuous random coefficients that have certain growth and are independent of the absolutely continuous random variable P0, and the density of P0, , is Lipschitz on (0,1). In this article, we tackle the problem in a different manner, by using probability tools that allow the hypotheses to be less restrictive. We only suppose that A(t) is expanded on L2([t0,T]×Ω), so that we include other expansions such as random power series. We only require absolute continuity for P0, so that A(t) may be discrete or singular, due to a modified version of the random variable transformation technique. For , only almost everywhere continuity and boundedness on (0,1) are needed. We construct an approximating sequence of density functions in terms of expectations that tends to f1(p,t) pointwise. Numerical examples illustrate our theoretical results. 相似文献
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Rob Turner Sean Robert Wevrett Suzanne Edmunds Marc Brown Robert Atkinson Tim Shea 《Biomedical chromatography : BMC》2019,33(8)
The aim of this investigation was to develop receiver and extraction fluids, and subsequently validate an analytical method to quantify the permeation and penetration of flurbiprofen into human pharynx tissue using a Franz diffusion cell. The solubility and stability of flurbiprofen in a suitable receiver fluid, and a suitable extraction method and fluid to recover and quantitate flurbiprofen from human pharynx tissue, were investigated using high‐performance liquid chromatography (HPLC). The potential interference of human pharynx tissue in the receiver fluid was also investigated. The HPLC analytical method was successfully validated according to current guidelines. The final receiver fluid demonstrated sufficient solubility and stability, and the extraction method and fluid resulted in >95% recovery of flurbiprofen following exposure to human pharynx tissue. The lower limit of quantitation of flurbiprofen was 0.045 μg/mL in both the receiver and extraction fluids. There was no interference of the human pharynx tissue with the HPLC method. This investigation validated an analytical method for quantitating flurbiprofen, and determined a suitable receiver fluid and extraction method and fluid, which can be used to investigate the permeation and penetration of flurbiprofen through human pharynx tissue using the Franz diffusion cell method. 相似文献
166.
Molecular Size and Electronic Structure Combined Effects on the Electrogenerated Chemiluminescence of Sulfurated Pyrene‐Cored Dendrimers
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Dr. Giovanni Valenti Dr. Andrea Fiorani Dr. Simone Di Motta Dr. Giacomo Bergamini Prof. Marc Gingras Prof. Paola Ceroni Prof. Fabrizia Negri Prof. Francesco Paolucci Prof. Massimo Marcaccio 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(7):2936-2947
The electrochemistry, photophysics, and electrochemically generated chemiluminescence (ECL) of a family of polysulfurated dendrimers with a pyrene core have been thoroughly investigated and complemented by theoretical calculations. The redox and luminescence properties of dendrimers are dependent on the generation number. From low to higher generation it is both easier to reduce and oxidize them and the emission efficiency increases along the family, with respect to the polysulfurated pyrene core. The analysis of such data evidences that the formation of the singlet excited state by cation–anion annihilation is an energy‐deficient process and, thus, the ECL has been justified through the triplet–triplet annihilation pathway. The study of the dynamics of the ECL emission was achieved both experimentally and theoretically by molecular mechanics and quantum chemical calculations. It has allowed rationalization of a possible mechanism and the experimental dependence of the transient ECL on the dendrimer generation. The theoretically calculated Marcus electron‐transfer rate constant compares very well with that obtained by the finite element simulation of the whole ECL mechanism. This highlights the role played by the thioether dendrons in modulating the redox and photophysical properties, responsible for the occurrence and dynamics of the electron transfer involved in the ECL. Thus, the combination of experimental and computational results allows understanding of the dendrimer size dependence of the ECL transient signal as a result of factors affecting the annihilation electron transfer. 相似文献
167.
Dr. Marc Presset Dr. Jérôme Paul Ghania Nait Cherif Nisanthan Ratnam Nicolas Laloi Prof. Eric Léonel Dr. Corinne Gosmini Prof. Erwan Le Gall 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(17):4491-4495
The reductive Barbier coupling of aromatic halides and electrophiles has been achieved using a CoBr2/1,10-phenanthroline catalytic system and over stoichiometric amounts of zinc. The reaction displayed a broad scope of substrates, including (hetero)aryl chlorides as pro-nucleophiles and aldehydes or imines as electrophiles, leading to diarylmethanols and diarylmethylamines in moderate to excellent yields, respectively. 相似文献
168.
Laurent François Joël Dupays Dmitry Davidenko Marc Massot 《Combustion Theory and Modelling》2020,24(5):775-809
We investigate a model of solid propellant combustion involving surface pyrolysis coupled to finite activation energy gas-phase combustion. Existence and uniqueness of a travelling wave solution are established by extending dynamical system tools classically used for premixed flames, dealing with the additional difficulty arising from the surface regression and pyrolysis. An efficient shooting method allows to solve the problem in phase space without resorting to space discretisation nor fixed-point Newton iterations. The results are compared to solutions from a CFD code developed at ONERA, assessing the efficiency and potential of the method, and the impact of the modelling assumptions is evaluated through parametric studies. 相似文献
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