热对流条件下颗粒沉降的格子Boltzmann方法模拟

采用格子Boltzmann方法模拟了在热对流条件下的颗粒沉降问题, 在研究单颗粒在等温流体、热流体和冷流体中运动的基础上, 进一步模拟了两个不同温度的颗粒在流体中的沉降.结果表明:两等温颗粒的沉降方式与雷诺数Re以及格拉晓夫数Gr密切相关, 而两不同温度的颗粒与两等温颗粒的沉降规律有显著不同.无论初始位置如何, 冷颗粒最终总位于热颗粒下方运动, Re较大时, 发生连续的拖曳、接触现象, 而Re较小时, 冷颗粒会以较大的沉降速度远离热颗粒. 关键词： 格子Boltzmann方法 颗粒沉降 热对流     

乙醇在TiO2(110)表面光催化解离的动力学和超快电子动态学 (cited: 2)

采用实时双光子光电子能谱和时间分辨双光子光电子能谱技术分别研究了乙醇在该表面光催化解离的动力学和超快电子动态学过程. 通过测量与乙醇光催化解离相关的电子激发态随时间的演化,发现这个反应满足分型动力学. 乙醇在还原性TiO₂(110)上的光催化解离比在氧化性表面快,这归结于缺陷的存在降低了反应能垒. 这样一个反应的加速过程很可能是与缺陷电子相关的. 通过干涉双脉冲相关的测量,得到了乙醇-TiO₂界面电子激发态的超快动态学. 与甲醇的情况类似,这个电子激发态的寿命为24 fs. 激发态的出现为TiO₂和它周围环境的电子转移提供了一个通道.     

离子速度成像技术研究2-溴戊烷的光解离动力学

运用离子速度成像技术研究了2-溴戊烷分子在～234 nm处的光解离动力学. 通过分析光解产物Br(²P_3/2)(简称Br)和Br(²P_1/2) (简称Br*)的速度影像,分别得到其速度分布和角度分布. Br和Br*的速度分布可以用两个高斯分布拟合,分别对应于2-溴戊烷在～234 nm处两个独立的光解离反应通道. 高能的高斯分量对应于C-Br伸缩振动模式的直接解离,低能的高斯分量对应于弯曲振动和C-Br伸缩振动耦合所导致的解离. 确定出光解离产物Br的相对量子产率为0.892,结合Br和Br*碎片的各项异性参数和溴原子的相对量子产率,讨论了³Q₀、³Q₁和¹Q₁激发态分别对产物Br和Br*的贡献. 通过对比溴代戊烷4种同分异构体光解离过程的差异,讨论了分子烷基分支化对光解机理的影响.     

下电极对ZnO薄膜电阻开关特性的影响

本文采用直流磁控溅射法在三种不同的下电极(BEs)上制备了ZnO薄膜, 获得了W/ZnO/BEs存储器结构. 研究了不同的下电极材料对器件电阻开关特性的影响. 研究结果表明, 以不同下电极所制备的器件都具有单极性电阻开关特性. 在低阻态时, ZnO薄膜的导电机理为欧姆传导, 而高阻态时薄膜的导电机理为空间电荷限制电流. 不同下电极与ZnO薄膜之间的肖特基势垒高度对电阻开关过程中的操作电压有较大的影响, 并基于导电细丝模型对不同下电极上ZnO薄膜的低阻态阻值及reset电流的变化进行了解释. 关键词： ZnO薄膜 电阻开关 下电极     

基于动态地场和元胞自动机的自行车流建模

针对现有自行车流模型对车辆间作用考虑不足的问题,在原多车道元胞自动机模型的基础上引入动态地场,在模型中纳入了排斥力,并充分考虑了前车速度对后车行驶的影响,体现了自行车的灵活性等特征,提出了换道成本的概念并建立了新的基于比较交通环境的换道规则. 数值仿真结果表明：1）该模型能更准确地描述自行车流,反映自行车流的特征,得到的数据符合实际;2）单位车道宽度的通行能力随着车道数的增加有小幅下降;3）激进的驾驶风格使得换道次数大幅增加,通行能力下降. 关键词： 自行车流 元胞自动机 动态地场 仿真     

The band gap and transmission characteristics investigation of local resonant quaternary phononic crystals with periodic coating

In this article, the investigation of the Lamb wave propagation in two-dimensional phononic crystals (PCs) composed of an array of periodic coating on a thin plate is presented. Compared with the traditional PCs usually consist of cylindrical scatters with uniform coatings in their exterior structure, the newly exterior coating structures with periodic alternant arrangement of two different materials are proposed. The band structures are calculated using finite element method. We discover that a complete band gap can be exhibited at low frequency. Furthermore, for a finite PCs plate, the computed transmission and resonance spectra shown an evident resonance nature which can be directly related to formation of the low-frequency gaps. The effects of different material parameters and arrangement mode of coating on the acoustic energy transmission and attenuation are also studied. Finally, the experimental transmission spectrum of the periodic coating PCs are also presented and compared with the numerical results. This study will provide useful support to the design of tuning band gaps and isolators in the low-frequency range.     

Early stage expansion and time-resolved spectral emission of laser-induced plasma from polymer

In the nanosecond laser ablation regime, absorption of laser energy by the plasma during its early stage expansion critically influences the properties of the plasma and thus its interaction with ambient air. These influences can significantly alter spectral emission of the plasma. For organic samples especially, recombination of the plasma with the ambient air leads to interfering emissions with respect to emissions due to native species evaporated from the sample. Distinguishing interfering emissions due to ambient air represents a critical issue for the application of laser-induced breakdown spectroscopy (LIBS) to the analysis of organic materials. In this paper, we report observations of early stage expansion and interaction with ambient air of the plasma induced on a typical organic sample (nylon) using time-resolved shadowgraph. We compare, in the nanosecond ablation regime, plasmas induced by infrared (IR) laser pulses (1064 nm) and ultraviolet (UV) laser pulses (266 nm). Nanosecond ablation is compared with femtosecond ablation where the post-ablation interaction is absent. Subsequent to the early stage expansion, we observe for each studied ablation regime, spectral emission from CN, a typical radical for organic and biological samples. Time-resolved LIBS allows identifying emissions from native molecular species and those due to recombination with ambient air through their different time evolution behaviors.     

Seasonal variability of cloud optical depth over northwestern China derived from CERES/MODIS satellite measurements

The seasonal variability of cloud optical depth over northwestern China derived from Clouds and the Earth＇s Radiant Energy System （CERES） Single Scanner Footprint （SSF） Aqua Moderate Resolution Imaging Spectroradiometer （MODIS） Edition IB data from July 2002 to June 2004 is presented. The regions of interest are those with Asia monsoon influence, the Tianshan and Qilian Mountains, and the Taklimakan Desert. The results show that the instantaneous measurements presented here are much higher than the previous results derived from International Satellite Cloud Climatology Project （ISCCP） D2 monthly mean data. Generally the measurements of cloud optical depth are the highest in summer and the lowest in winter, however, Taklimakan Desert has the lowest measurements in autumn. The regional variation is quite significant over northwestern China.     

Structural and optical investigation of nonpolar α-plane GaN grown by metalben organic chemical vapour deposition on r-plane sapphire by neutron irradiation

Nonpolar (1120) α-plane GaN films are grown by metal-organic chemical vapour deposition (MOCVD) on r-plane (1102) sapphire. The samples are irradiated with neutrons under a dose of 1 × 10¹⁵ cm^-2. The surface morphology, the crystal defects and the optical properties of the samples before and after irradiation are analysed using atomic force microscopy (AFM), high resolution X-ray diffraction (HRXRD) and photoluminescence (PL). The AFM result shows deteriorated sample surface after the irradiation. Careful fitting of the XRD rocking curve is carried out to obtain the Lorentzian weight fraction. Broadening due to Lorentzian type is more obvious in the as-grown sample compared with that of the irradiated sample, indicating that more point defects appear in the irradiated sample. The variations of line width and intensity of the PL band edge emission peak are consistent with the XRD results. The activation energy decreases from 82.5 meV to 29.9 meV after irradiation by neutron.