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991.
The topic of non-destructively detecting localised damage in plates is addressed in this article. Since the presence of a crack or a delamination causes a discontinuity in the mode shape first derivatives, a numerical method for detecting discontinuities in smooth piecewise functions and their derivatives, based on a polynomial-annihilation technique is presented. The method, already proposed for beam-type structures, has been extended to enable the detection and localisation of damage in plate-like structures for which only post-damage mode shapes are available. Applying finite element analysis, the mode shapes of an isotropic plate with a saw-cut and a multi-layered composite plate with a delamination have been calculated and the performance of the approach evaluated for increasing amounts of noise. Encouraging results indicate that further development of the technique for non-destructive testing of plate-like structures would be highly worthwhile. 相似文献
992.
Undoped CeO2, and single and triple doped CeO2:M (where M=Dy3+, Tb3+and Eu3+) nanophosphors were synthesized through a simple sonochemical process and characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), EDS and photoluminescence (PL) spectrophotometry. The TEM micrographs show that resultant nanoparticles have flower-like shape. The doped samples showed multicolor emission on single wavelength excitation. Energy transfer was observed from host to the dopant ions. Characteristic blue emission from Dy3+ ions, green from Tb3+ ions and red from Eu3+ ions were observed. The CIE coordinates of the triple doped Ce0.86Dy0.005Tb0.055Eu0.08O2 nanoflowers lie in the white light region of the chromaticity diagram and show promise as good phosphor materials for new lighting devices. 相似文献
993.
Joshi BN Jain AK Gupta YK Biswas DC Saxena A John BV Danu LS Vind RP Choudhury RK 《Physical review letters》2011,106(2):022501
The heavy cluster knockout reaction (16)O((12)C,2(12)C)(4)He performed for the first time, reveals the true nature of the (12)C-(12)C interaction. The observed cross section is enhanced by almost 2 orders of magnitude over the conventional zero range distorted wave impulse approximation (DWIA) predictions. An attractive (12)C-(12)C optical potential, as obtained in the folding model, does not explain the enhanced cross section in the finite range (FR) DWIA framework. The inclusion of a hard core of fairly long range ~3.65 fm explains the data. The present investigation of (16)O((12)C,2(12)C)(4)He along with the (12)C-(12)C elastic scattering also proves beyond doubt that the folding model's deep attractive heavy ion potentials are unsuitable to describe the highly overlapping heavy ions. The application of FR-DWIA opens up new avenues to use the heavy core knockout for the detailed investigation of heavy as well as Borromean halo nuclei. 相似文献
994.
Primordial non-Gaussianity is a crucial test of inflationary cosmology. We consider the impact of non-Gaussianity on the ionization power spectrum from 21 cm emission at the epoch of reionization. We focus on the power spectrum on large scales at redshifts of 7 to 8 and explore the expected constraint on the local non-Gaussianity parameter f(NL) for current and next-generation 21 cm experiments. We show that experiments such as SKA and MWA could measure f(NL) values of order 10. This can be improved by an order of magnitude with a fast-Fourier transform telescope like Omniscope. 相似文献
995.
A novel task-specific ionic liquid, 1-butyl-3-methylimidazolium p-toluenesulfinate, [bmim][p-TolSO2] has been synthesized and used as a nucleophile for the reaction with alkyl bromides and phenacyl bromides to prepare sulfones and β-ketosulfones in excellent yields (80-93%) in [bmim][BF4] ionic liquid. The isolated yields of sulfones and β-ketosulfones were higher in [bmim][BF4] than other organic solvents at room temperature. 相似文献
996.
Suresh M Mandal AK Kesharwani MK Adarsh NN Ganguly B Kanaparthi RK Samanta A Das A 《The Journal of organic chemistry》2011,76(1):138-144
A new dibenzo[24]crown-8 derivative (1) was synthesized and functionalized with aromatic moieties such as naphthalene and coumarin units. These two fluorophores are known to form an effective FRET (Forster resonance energy transfer) pair, and this formed the basis for the design of this host crown ether derivative. Results of the steady-state and time-resolved fluorescence studies confirmed the resonance energy transfer between the donor naphthalene moiety and acceptor coumarin fragment, while NMR spectra and computational studies support a folded conformation for the uncomplexed crown ether 1. This was found to form an inclusion complex, a [2]pseudorotaxane type with imidazolium ion derivatives as the guest molecules with varying alkyl chain lengths ([C(4)mim](+) or [C(10)mim](+)). The host crown ether (1) tends to adopt an open conformation on formation of the interwoven inclusion complex (1·[C(4)mim](+) or 1·[C(10)mim](+)). This change in conformation, from the folded to a open one, was predicted by computational as well as (1)H NMR studies and was confirmed by single crystal X-ray structure for one (1·[C(4)mim](+)) of the two inclusion complexes. The increase in the effective distance between the naphthalene and coumarin moieties in the open conformation of these inclusion complexes was also supported by the decrease in the effective FRET process that was operational between naphthalene and coumarin moieties in the free molecule (1). Importantly, this inclusion complex formation was found to be reversible, and in the presence of a stronger base/polar solvent, such as triethyl amine/DMSO, the deprotonation/effective solvation of the cationic imidizolium ions ([C(4)mim](+) or [C(10)mim](+)) resulted in decomplexation or dethreading with restoration of the original emission spectra for 1, which signifies the subsequent increase in the FRET process. Thus we could demonstrate that a molecular folding-unfolding type of movement in the crown ether derivative could be induced by chemical input as an imidazolium ion. 相似文献
997.
Manoj Kumar J. Udhayakumar Ashutosh Dash 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(1):53-58
Aiming the selective recovery of palladium from high level radioactive liquid waste (HLW), a chelating thiamide type sorbent,
CWP–TU, was prepared by the modification of Japanese cedar wood powder (CWP). Convection oven and microwave heating were separately
used for modification purpose and found that microwave heating is more effective over oven heating. CWP–TU was extensively
studied for the adsorption of Pd(II) from nitric acid medium. The batch test showed that nitric acid concentration of 3 M
or higher is favorable for Pd(II) loading. Consistent adsorption of Pd(II) under gamma irradiation condition demonstrated
the feasibility of using CWP–TU in real HLW. Also, Pd(II) only adsorption from simulated HLW solution verified the palladium
only selectivity of the sorbent as well as the lack of influence of coexisting metal ions on its affinity toward Pd(II). CWP–TU
holds maximum Pd(II) loading capacities of 0.98 mol/kg at 30 °C and 1.04 mol/kg under gamma irradiation. A comparative study
using some ion exchange resins revealed that the resins are either ineffective in nitrate medium or lack stability under irradiation. 相似文献
998.
Veleeparambil M. Manoj Usha K. Aravind Hari Mohan Charuvila T. Aravindakumar 《Research on Chemical Intermediates》2011,37(8):1113-1122
The decomposition studies of S-nitrosothiols (RSNO) are important due to their potential role in vivo in connection with the storage and transport of nitric
oxide (•NO) within the body. Reactions of hydroxyl radicals (•OH) with a number of RSNOs (S-nitroso derivatives of N-acetyl-dl-penicillamine, l-cysteinemethylester, N-acetylcysteamine, and dl-penicillamine) in aqueous medium at neutral and acidic pH have been reported in the present study. Radiation chemical technique
(steady state and pulse radiolysis) has been utilized for the determination of the reaction rate constants, the end product
analyses, and the transient intermediate species. The rate constants for the reaction of •OH with the selected RSNOs were determined using a competition kinetic method with 2′-deoxy-d-ribose as the competitor. All the rate constants were found to be of the order of diffusion controlled (1010 M−1 s−1). The degradation yield of RSNOs was found to be quantitative (i.e., G(–RSNO) ≈ G(•OH)) at neutral and acidic pH. The major products of decomposition were the respective disulfide (RSSR) and nitrite (NO2
−). A good material balance is also obtained between the degradation yield and the formation of the products (i.e., G(–RSNO) ≈ G(RSSR) + G(NO2
−)). The major transient intermediate was the thiyl radical (RS•). Its intermediacy was confirmed by making use of the electron transfer reaction of 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate)
(ABTS2−) to RS•, which results in the formation of ABTS•− having a transient absorption spectrum with λmax at 410 nm. Based on these results, a generalized reaction mechanism is deduced for the reaction of •OH with RSNO. 相似文献
999.
Manoj Khanal Chandana T. Jayasundara 《Particuology》2014,(5):54-59
Discrete element method (DEM) has been used to investigate the effects of particle elastic modulus and coefficient of inter-particle sliding friction on milling of mineral particles. An autogeneous mill of 600 mm diameter and 320 mm length with 14,500 particles has been selected for the simulation. Various mill performance parameters, for example, particle trajectories, collision frequency, collision energy and mill power have been evaluated to understand the effects of particle elastic modulus and inter-particle sliding friction during milling of particles. For the given model, it has been concluded that at high energy range, as the elastic modulus and particle sliding friction increase the energy dissipated among the particles increases. The collision frequency increases with the increase in elastic modulus, however, this trend is not clearly observed with increasing inter-particle sliding friction. The power draw of the mill increases with the increase in fraction of mill critical speed. 相似文献
1000.
Isatin is an essential building block in organic synthesis and shows various biological activities. The most attractive application of isatin in organic synthesis is undoubtedly in the highly reactive C-3 carbonyl group, which is a prochiral center as well. The construction of a spiroheterocyclic framework has always been a challenging endeavor for synthetic organic chemists as it frequently requires synthetic design based on specific strategies. This review gives a short summary of the advances in the use of isatin in the synthesis of various spiroheterocyclic compounds through multicomponent reactions and 1,3-dipolar cycloaddition reactions. 相似文献